高温铀物种形成(Speciation)的热力学数据

本文依据C.M.Criss和J.W.Cobble的“离子熵对应原理”,对1978年D.Langmuir给出的铀物种形成常温热力学数据进行了高温值的处理,得出了一套较全面而系统的高温热力学参数,以供参考使用。     

全国最大之一的供热厂工程的设计和服务介绍

介绍一些新技术，新经验，新设备在大型供热厂工程设计中的应用，由于此类工程与一般工程不同，具有当年设计，当年施工，当年投产的特性，故设计配合施工服务显得尤为重要，本文对服务中及时妥善处置相关问题的工作方法和体会也进行了介绍，这对于今天快节奏设计，工程总承包和改企建制，无疑都有一定的帮助和启示。     

关于推行岩土工程专业体制的思考与实例

岩土工程专业体制的核心内涵,是强调岩土工程勘查,设计,施工,监测,监理５个环节的整体和统一性。岩土工程师,不仅要为建设工程设计提供地质资料,而且还要积极参与或争取主持整个岩土工程项目的设计与施工,本文以实例阐明了其可能性与必要性。     

三山岛金矿F3断裂带的水文地质工程地质特征及灾害防治

本文对三山岛金矿F3断裂带的构造、岩性和水动力学特征进行了研究,对矿坑开挖中的突水和坑道碎屑流的成因做了探讨,并在水文地质结构、水化学、水同位素及水文地热学的综合研究基础上,对未来的二期井下工程开挖中可能出现的工程地质问题进行了预测,提出了防治方案。     

上扬子区(四川盆地)寒武系的含盐性与地质背景

据记载,分布于上扬子区寒武系的石膏岩仅有零星资料。如今,大量蒸发岩如溶蚀角砾岩、硬石膏、石盐岩及富钾卤水等已被发现。沉积相经历了从盆地相、台地相到蒸发岩相的演化过程。在中、下寒武统中找到海退沉积序列。古构造-古地理背景是蒸发岩沉积的重要控矿条件之一。周边板块运动及塑性基底的褶皱,导致台缘隆起及台内坳陷的形成。岩相古地理图展示从碳酸盐、硫酸盐到氯化物盐类的"泪滴式"沉积相带。蒸发岩沉积于台缘隆起及礁生长进入堰塞潟湖至盐湖阶段。在稳定坳陷区沉积盆地中蒸发岩系发育;石盐岩较厚,其溴氯比值为0.2-0.4;古气候炎热、干燥;在蒸发岩体周围有沉积(封层)水及溶滤水,其含钾(K+)量为0.10-4.76g/L;水文地球化学比值(如钾氯比值、钾盐比值及钾溴比值等)指示含钾异常;盐湖浓缩卤水达到氯化物盐类沉积阶段及相应的构造封闭程度;含盐地质标志广泛分布等等。鉴于上述,估计该区可能具备钾盐成矿条件。然而目的层埋藏太深,因此笔者建议,应在浅埋部位进行有效的成矿预测,为普查指出远景区。     

The history of water salinity in the Pearl River estuary,China, during the Late Quaternary

This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.     

CMIP5模式对中国近海海表温度的模拟及预估

基于观测和再分析资料;利用多种指标和方法评估了国际耦合模式比较计划（CMIP5）中21个模式对中国近海海温的月、季节和年际变化模拟能力。多模式集合能够再现气候平均意义下近海海温的空间分布特征;但量值上存在一定的低估。在渤海和黄海;集合平均与观测差别比较明显。在年际尺度上;与观测数据对比;模式模拟海温与Niño3指数相关性较小。中国近海海表面温度在1960-2002年有明显的升高趋势;从2003年开始增温趋缓。评估结果表明;ACCESS1.0、BCC-CSM1.1、HadGEM2-ES、IPSL-CM5A-MR、CMCC-CM、FGOALS-g2、CNRM-CM5-2、INMCM4八个模式对中国近海海温的变化有较好的模拟能力。利用ACCESS1.0、INMCM4、BCC-CSM1.1、IPSL-CM5A-MR、CMCC-CM这5个模式结果对中国近海海温未来的变化进行了预估。在RCP4.5、RCP8.5情景下;未来近100年中国近海海温有明显升高趋势;最优模式多模式集合平均增温分别可达到1.5℃、3.3℃;净热通量变化和平流变化共同促进了东海升温。     

空心块体水沙动力及泥沙淤积特性研究

空心块体具有良好的阻水和促淤功能,近年来被广泛用于生态修复工程。本文结合水槽试验及Flow-3D数值模拟,分析了开敞型和半封闭型空心块体的阻水效应和泥沙淤积特性。结果表明：空心块体的开孔率对内部水流流速、紊动强度起主导作用,开孔率较小的半开敞型空心块体减速、制紊效果更强;开敞型和半封闭型空心块体近底层悬沙浓度分别增大56%和75%,两者均有利于促进泥沙在块体内部淤积,近底层水流紊动越强,泥沙淤积形态差异越大;空心块体所营造的低流速、泥沙微淤、内外连通的水沙环境是大型底栖生物的生境需求,半封闭型空心块体内部的低紊动水流结构更有利于大型底栖生物的栖息、繁衍。     

The Remediation of Perchloroethylene Contaminated Groundwater by Nanoscale Iron Reactive Barrier Integrated with Surfactant and Electrokinetics

In this study, nanoscale zero-valent iron (NZVI) particles were synthesized and utilized to integrate with surfactant and electrokinetics for the remediation of perchloroethylene (PCE). The average particle diameter and specific surface area of the lab-synthesized iron particles were 109.3 nm and 129.7 m² g^–1, respectively. Experiments were performed in a glass sandbox to simulate the transport and degradation of PCE in the aquifer. The results of the transport tests revealed that the PCE concentrations at the bottom layer was higher than those at the mid and upper layers, and that the surfactant Tween 80 showed its conspicuous mobilization for PCE in the aquifer. As the results of the degradation tests showed, NZVI activity could be promoted by electrokinetics that enhanced the remediation performance of PCE contaminated groundwater by the NZVI reactive barrier. Chlorinated byproducts were not detected during the degradation tests, that is, PCE was completely dechlorinated by NZVI in the reactive barrier. The information collected from this study will be useful for further application of the NZVI reactive barrier system to remediate the aquifers contaminated by the chlorinated solvents.     

Study of zooplankton ecology in Zhejiang coastal upwelling system-Zooplankton biomass and abundance of major groups

The studied area is a shallow water area that belongs to the East China Sea continent shelf. The distribution of zooplankton biomass is higher inshore than offshore. The maximum abundance is in the inshore edge of the centre of upwelling, which is the superposed area of the salinity front and temperature front, due to the fact that the mixture of three different waters has brought about a concentration of nutrients. The herbivorous Euphausia, Copepoda and Tunicata are the major groups of the abundant area. Tunicata possess the possibility to compete against other kinds of herbivorous zooplankton. This means that there is negative correlation between the distribution of Tunicata and that of Copepoda and Euphausia. The positions of maximum areas of zooplankton biomass, phytoplankton individual and the concentration of phosphates and chlorophyll-a overlap one another. In the centre of upwelling, zooplankton can not adapt itself to the environment of lower temperature and less oxygen even with rich nutrient