Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

天然闪锌矿原位高温X射线衍射研究

对天然闪锌矿进行了原位高温X射线衍射实验研究,结果表明：闪锌矿受热膨胀,27～675℃温度范围内其膨胀系数为25.61×10-6℃-1;随着温度的升高,在543℃时产生中间物相Zn3O（SO4）2,并分解产生红锌矿ZnO;在797℃时中间物相完全消失,同时出现尖晶石结构的ZnFe2O4;加热至1160℃时的产物为ZnO和ZnFe2O4。实验表明,天然闪锌矿的热改性可产生一定比例的红锌矿（ZnO）,其与闪锌矿一起形成二元复合半导体。在光的激发下,该半导体体系产生的光生载流子由一种半导体注入另一种半导体,降低了光生电子-空穴对的复合几率,提高其光催化活性。本文的研究可为热改性提高天然闪锌矿光催化活性提供理论依据。     

松辽盆地西南部钱家店铀矿床物源分析及铀成矿意义

基于开鲁盆地钱家店铀矿床姚下段砂岩的碎屑组分分析、重矿物组合特征以及稀土元素分析,探讨了该砂岩型铀矿的物质来源及矿质来源。碎屑组分分析指示该地区姚下段砂岩碎屑矿物以石英为主,碱性长石次之,岩屑类型丰富且含量较高;重矿物组合特征反映出姚下段重矿物以稳定矿物钛磁铁矿、白钛石、锆石和石榴石等为主,不稳定矿物绿帘石、硬绿泥石及黑云母含量较少;稀土元素特征显示出蚀源区花岗岩与过渡带相似的REE分布模式,花岗岩的ΣREE值与过渡带的ΣREE值较接近,且均具有铕负异常。综上所述,钱家店地区姚家组下段沉积显示了多物源体系的特征,碎屑矿物以中酸性岩浆岩来源为主,变质岩来源碎屑为辅;物源主要有3大方向：西北部舍伯吐凸起物源、东部架玛吐凸起物源及南部的燕山造山带物源,物源总体以南部燕山造山带为主,同时受多方向物源的共同控制。燕山晚期中酸性富铀岩浆岩在钱家店铀矿床铀源供给方面扮演了重要的角色。     

长三角房价收入比时空演变格局及收敛性研究

房价收入比是衡量房地产健康状况和探测居民住房支付能力的重要指标。以2008—2018年长三角307个区县为研究单元,运用数值-位序法则和趋势面分析对房价收入比的总体分布特征进行探究,利用LISA时间路径分析房价收入比的时空动态性特征,并检验区域房价收入比的收敛性。结果表明： ① 长三角房价收入比总体上呈上升趋势,空间上表现为东高西低、南高北低的格局,上海、浙江、江苏和安徽依次降低。② 上海和浙江南部房价收入比的空间结构更具动态性,而江苏和安徽更加稳定;长三角房价收入比的空间演化整体上具有较强的空间锁定效应和空间整合性。③ 长三角区县房价收入比整体上不存在σ收敛,但各时间段上均存在显著的绝对β收敛,且各省份内部也均存在着俱乐部收敛现象。城市群房价收入比的变动对居民的流动有着重要的指示作用,并具有扩散效应和虹吸效应。加强城市群房地产市场一体化建设,是促进城市群区域一体化发展的有效途径。     

赣东北地区矽卡岩典型矿物形成与演化的光谱证据:以朱溪钨多金属矿为例SCIEI北大核心CSCD

朱溪是近年来在江西塔前-赋春成矿带发现的一个世界级超大型钨铜矿床。本文采用短波红外+热红外光谱技术对矿区13个钻孔进行了光谱测量,结合岩石-矿物地球化学分析,探讨了朱溪矿床矽卡岩中典型蚀变矿物的形成与演化过程,厘定了矽卡岩形成不同阶段矿物组合的光谱特征,构建了朱溪矿床的短波红外+热红外光谱勘查模型。研究发现:(1)区内不同矿物组合形成了明显的蚀变分带,由内向外依次为绢云母(富Si)+长石(岩体顶层蚀变,多期流体叠加综合作用)→外矽卡岩:钙铝榴石+透辉石+(绢云母)→透辉石+蛇纹石+绿泥(帘)石+滑石→绢云母(富Al)+绿泥(帘)石(基底不整合面蚀变);(2)Al-OH波长的移动可指示成矿流体压力、温度及pH值的变化;(3)研究区透辉石的形成、演化与矿体之间关系密切,虽然富矿体赋存于矽卡岩形成早期的透辉石-石榴子石蚀变带,但大量矿体则赋存于矽卡岩退蚀变阶段的蛇纹石-绿泥石蚀变带;(4)矿体的形成与流体的混合作用关系极大,伊利石光谱吸收特征能够指示外部冷水(大气降水或地下水)的灌入轨迹。     

A Comparison of Nd Isotopes of Granitoids from the Central Asian Orogenic Belt and Qinling-Dabie Orogen,and Implications for Understanding of Crustal Growth from Accretion to Collision

正Orogens can generally be divided into two types:accretionary and collisional.The fundamental differences in deep-crustal compositions and architecture from accretion to collision and how to identify them is not well understood.This is one of the major aims of the IGCP 662 project (www.igcp662.org.cn).The Central Asian Orogenic Belt (CAOB) is a typical and the world's largest Phanerozoic accretionary orogenic belt and the     

山西新发现大理岩玉的宝石矿物学特征

山西北部六棱山地区新发现了一种玉石品种——大理岩玉,其主要有黄色和黄褐色两种颜色,结构较致密,透明度较好,是一种优质的饰面石材和玉雕原料。采用薄片观察、环境扫描电子显微镜、X射线粉末衍射、LA-ICP-MS和常规宝石学仪器等测试手段对该大理岩玉样品的宝石矿物学特征进行了测试与研究。结果显示,该大理岩玉为经变质作用形成的方解石大理岩,所含CaCO3的质量分数为96%～97%,推测Fe元素是该玉石的致色元素;微量的碳质和铁质粉末阻碍了柱状方解石的重结晶,形成条纹结构;方解石为不规则的多边形柱体,呈镶嵌的不规则他形变晶结构。通过分析大理岩玉的结构特征,认为平行于其层纹方向切磨,可使得其成品表面光洁度好,光泽强,不易破损。     

Results for Rarely Determined Elements in MPI-DING, USGS and NIST SRM Glasses Using Laser Ablation ICP-MS

New analytical results are reported for rarely determined elements Be, B, Ge, As, Mo, Rh, Pd, Ag, Cd, In, Sn, Sb, W, Re, Ir, Pt, Au, Tl and Bi in MPI‐DING and USGS (BCR‐2G, BHVO‐2G, BIR‐1G) silicate glasses and the NIST SRM 610‐614 synthetic soda‐lime glasses using 193 nm ArF excimer laser ablation and quadrupole ICP‐MS. The method used involved external calibration against GOR132‐G for Ir and NIST SRM 610 for other elements, internal standardisation using Ca, and ablation with a crater diameter of 160 μm and a pulsed laser repetition rate of 10 Hz. Small amounts of nitrogen (5 ml min^?1) were added to the central channel gas of the plasma to improve the limits of detection for most of these elements by a factor of 1.2–2.5 and to reduce the oxide interference level to 0.02% (ThO⁺/Th⁺). Under these conditions, the LODs for most of these rarely determined elements were within the range 0.1 to 10 ng g^?1. The operating conditions that were required to minimise ICP‐induced fractionation (U⁺/Th⁺≈ 1) in the mode without nitrogen were accompanied by a 50–60% reduction in sensitivity for elements such as Ca, Au and Pt. In contrast, ICP‐induced fractionation could be minimised (U⁺/Th⁺≈ 1) with no loss of analyte sensitivity in the nitrogen mode. Interferences of CuAr⁺, ZnAr⁺, Cd⁺, Pb²⁺ and Sn⁺ on Pd⁺, Rh⁺, Cd⁺ and In⁺ were corrected. Oxide interferences were not considered due to their lower production rate. Analytical precision, as given by one relative standard deviation (% RSD) was less than 15% for most of the elements present at concentrations greater than 0.1 μg g^?1. A significant negative correlation was found between logarithmic concentration and logarithmic RSD, with a correlation coefficient of ?0.76. This trend indicates that possible chemical heterogeneities for most of these elements are smaller than the analytical uncertainty. Our results for Be, B, Ge, Sb and W are generally in good agreement with their reference values. In contrast, other elements in many of the reference glasses have only information values, upper limits or even no values, which restrict any detailed evaluation of the accuracy of the determined values. However, concentrations from multiple isotopes of one element analysed in this study showed excellent agreement, which guarantee the quality of our data to a certain extent.     

白钨矿的原位高压X射线衍射研究

使用金刚石对顶砧高压装置(DAC)和同步辐射光源,对天然白钨矿进行了原位高压能量色散X射线衍射(EDXD)研究,实验最高压力为16.0 GPa.在实验压力范围内观察到了一次白钨矿结构→钨锰铁矿结构的可逆相变:压力小于5.3 GPa时为白钨矿结构(I4_1/a),在5.3～12.3 GPa压力区间内为白钨矿结构与钨锰铁矿结构(P2/c)并存,大于12.3 GPa时完全相变为钨锰铁矿结构.从键长、配位数和配位多面体角度对白钨矿→钨锰铁矿结构的相变机制进行了解释.     

阿尔泰造山带花岗岩时空演变、构造环境及地壳生长意义——以中国阿尔泰为例

阿尔泰造山带横跨中、俄、哈、蒙四国边界,是中亚造山带主要组成部分,发育大量的花岗岩等侵入体。本文研究总结这些岩体的时空演变、成因类型和构造环境,并探讨其增生造山和地壳生长意义。依据锆石年龄,这些岩体可大致分为早中古生代的470～440Ma(中晚奥陶世)和425～360Ma(晚志留世—晚泥盆世)、晚古生代的355～318Ma(早石炭世)和290～270Ma(早二叠世)以及早中生代245～190Ma(中晚三叠世—早侏罗世)3个阶段5个期次,其中425～360Ma花岗岩可进一步细分为425～390Ma和380～360Ma两个峰期。早中古生代(470～360Ma)花岗岩体分布广泛,主要为钙碱性I型,多具不同程度变形,其中470～440Ma岩体变形极强(片麻岩体)。它们为同造山俯冲增生产物,形成于活动陆缘俯冲(470～440Ma)、继续俯冲弧后盆地伸展(420～390Ma)到聚合碰撞(380～360Ma)的过程中。早石炭世岩体发育于造山带南部,为不变形圆形状或不规则状,具典型碱性花岗岩特征,为晚(后)造山产物。早二叠世岩体主要发育于阿尔泰造山带南部,少量分布于造山带内部,多为圆形,不变形,少量变形岩体集中在额尔齐斯构造带内,成因类型以I、A型为特点,伴生有大量基性岩脉(体),显示为后造山底侵伸展环境。早中生代岩体为不变形圆形或不规则状,具有高分异I型和S型花岗岩特征,伴有稀有金属矿产,具有板内环境特点。花岗岩体同位素填图显示,阿尔泰中部块体岩体具有较低的εNd(t)值和老的Nd同位素模式年龄(1～1.3Ga),暗示存在古老地壳基底;由北向南εNd(t)值增高,模式年龄变年轻,显示陆壳向南生长,其中水平和垂向生长率分别为18%～28%和7%～8%。中生代时期阿尔泰造山带保留水平增生结构,没有发生大规模构造块体垂向叠覆。阿尔泰造山带经历了古陆缘构造演化,奥陶纪—志留纪陆缘俯冲,泥盆纪陆弧及陆缘边缘裂解、弧后盆地形成,晚泥盆世最终洋盆闭合及早石炭世各块体拼合的演化过程。该研究表明增生造山带中同样存在构造演化的阶段性;中亚增生造山作用不仅具有弧前增生,而且还存在陆缘裂解再拼合作用。