Extraterrestrial amino acids identified in metal‐rich CH and CB carbonaceous chondrites from Antarctica

Carbonaceous chondrites contain numerous indigenous organic compounds and could have been an important source of prebiotic compounds required for the origin of life on Earth or elsewhere. Extraterrestrial amino acids have been reported in five of the eight groups of carbonaceous chondrites and are most abundant in CI, CM, and CR chondrites but are also present in the more thermally altered CV and CO chondrites. We report the abundance, distribution, and enantiomeric and isotopic compositions of simple primary amino acids in six metal‐rich CH and CB carbonaceous chondrites that have not previously been investigated for amino acids: Allan Hills (ALH) 85085 (CH3), Pecora Escarpment (PCA) 91467 (CH3), Patuxent Range (PAT) 91546 (CH3), MacAlpine Hills (MAC) 02675 (CBb), Miller Range (MIL) 05082 (CB), and Miller Range (MIL) 07411 (CB). Amino acid abundances and carbon isotopic values were obtained by using both liquid chromatography time‐of‐flight mass spectrometry and fluorescence, and gas chromatography isotope ratio mass spectrometry. The δ¹³C/¹²C ratios of multiple amino acids fall outside of the terrestrial range and support their extraterrestrial origin. Extracts of CH chondrites were found to be particularly rich in amino acids (13–16 parts per million, ppm) while CB chondrite extracts had much lower abundances (0.2–2 ppm). The amino acid distributions of the CH and CB chondrites were distinct from the distributions observed in type 2 and 3 CM and CR chondrites and contained elevated levels of β‐, γ‐, and δ‐amino acids compared to the corresponding α‐amino acids, providing evidence that multiple amino acid formation mechanisms were important in CH and CB chondrites.     

The dynamic strength of an ordinary chondrite

Abstract– Dynamic and quasistatic unconfined compression experiments were performed on samples of the L5 ordinary chondrite MacAlpine Hills (MAC) 88118. The dynamic compressive strength measurements are the first of its kind for a stony meteorite, and indicate that the material tested here exhibits significant increase in compressive strength with increasing strain rate. This increase in compressive strength is larger than the increases typically observed in terrestrial rock specimens compressed over a similar range of strain rates. The details of the failure process are investigated by recording images of the experiments in real time. Specifically, the crack growth speeds in the dynamic compression experiments are measured from ultrahigh‐speed images. These speeds are significantly lower than the speeds observed in terrestrial analogs that are typically used in numerical investigations of large‐scale impacts. The implications of these measurements of strength and failure process are explored in the contexts of atmospheric disruption of meteors and impact cratering/disruption of asteroids.     

Modeling the integrated roles of insurance and retrofit in managing natural disaster risk: a multi-stakeholder perspective

This paper introduces a new modeling framework to understand and improve regional natural disaster risk management in the USA, including the interactions among key stakeholders and between the two important risk management mechanisms of insurance and retrofit. The framework includes a stochastic programming optimization to represent insurer decisions, which interacts with a utility-based model of individual homeowners’ decisions to insure and/or retrofit. Reinsurer and government roles are represented as inputs, and the decision models are integrated with a detailed regional catastrophe loss estimation model. This modeling framework is applied to a full-scale, realistic case study for hurricane risk to residential buildings in Eastern North Carolina. Several alternative system configurations are considered that affect the incentives for adoption of alternative risk management methods. They include providing a government subsidy for insured homeowners to encourage retrofit, providing both a government subsidy and insurance rebate to reduce retrofit costs, and mandating insurance purchase with a cap on insurance premiums. For each configuration, outcomes are presented from the perspectives of all key stakeholders—primary insurer, homeowners (insured and uninsured, in high- and low-risk areas), reinsurers, and the government. Results suggest that it is possible to design policies in which all stakeholders can be better off simultaneously. Retrofit incentives for insured homeowners can be effective in linking and strengthening the benefits of retrofit and insurance. Mandatory insurance coupled with capped profit loading factors and possibly retrofit rebates from the insurer to the homeowner can also reduce overall system risk.     

Compound‐specific carbon isotope compositions of aldehydes and ketones in the Murchison meteorite

Compound‐specific carbon isotope analysis (δ¹³C) of meteoritic organic compounds can be used to elucidate the abiotic chemical reactions involved in their synthesis. The soluble organic content of the Murchison carbonaceous chondrite has been extensively investigated over the years, with a focus on the origins of amino acids and the potential role of Strecker‐cyanohydrin synthesis in the early solar system. Previous δ¹³C investigations have targeted α‐amino acid and α‐hydroxy acid Strecker products and reactant HCN; however, δ¹³C values for meteoritic aldehydes and ketones (Strecker precursors) have not yet been reported. As such, the distribution of aldehydes and ketones in the cosmos and their role in prebiotic reactions have not been fully investigated. Here, we have applied an optimized O‐(2,3,4,5,6‐pentafluorobenzyl)hydroxylamine (PFBHA) derivatization procedure to the extraction, identification, and δ¹³C analysis of carbonyl compounds in the Murchison meteorite. A suite of aldehydes and ketones, dominated by acetaldehyde, propionaldehyde, and acetone, were detected in the sample. δ¹³C values, ranging from ?10.0‰ to +66.4‰, were more ¹³C‐depleted than would be expected for aldehydes and ketones derived from the interstellar medium, based on interstellar ¹²C/¹³C ratios. These relatively ¹³C‐depleted values suggest that chemical processes taking place in asteroid parent bodies (e.g., oxidation of the IOM) may provide a secondary source of aldehydes and ketones in the solar system. Comparisons between δ¹³C compositions of meteoritic aldehydes and ketones and other organic compound classes were used to evaluate potential structural relationships and associated reactions, including Strecker synthesis and alteration‐driven chemical pathways.     

Amino acid analyses of R and CK chondrites

Exogenous delivery of amino acids and other organic molecules to planetary surfaces may have played an important role in the origins of life on Earth and other solar system bodies. Previous studies have revealed the presence of indigenous amino acids in a wide range of carbon‐rich meteorites, with the abundances and structural distributions differing significantly depending on parent body mineralogy and alteration conditions. Here we report on the amino acid abundances of seven type 3–6 CK chondrites and two Rumuruti (R) chondrites. Amino acid measurements were made on hot water extracts from these meteorites by ultrahigh‐performance liquid chromatography with fluorescence detection and time‐of‐flight mass spectrometry. Of the nine meteorites analyzed, four were depleted in amino acids, and one had experienced significant amino acid contamination by terrestrial biology. The remaining four, comprised of two R and two CK chondrites, contained low levels of amino acids that were predominantly the straight chain, amino‐terminal (n‐ω‐amino) acids β‐alanine, and γ‐amino‐n‐butyric acid. This amino acid distribution is similar to what we reported previously for thermally altered ureilites and CV and CO chondrites, and these n‐ω‐amino acids appear to be indigenous to the meteorites and not the result of terrestrial contamination. The amino acids may have been formed by Fischer–Tropsch‐type reactions, although this hypothesis needs further testing.     

Evaluation of swimmer-based rip current escape strategies

Rip currents are the primary hazard on surf beaches, and early studies described them as fast, shore-normal flows that extended seaward of the surf zone. Based on this traditional view, commonly promoted safety advice was to escape a rip current by swimming parallel to the beach. However, recent studies have shown dominant rip current re-circulation within the surf zone and have endorsed floating as an appropriate escape strategy. Here, a first quantitative assessment of the efficacy of various rip current escape strategies, with a focus on the underlying physical processes, is presented. A field study was conducted at Shelly Beach, NSW, Australia, measuring three rip currents (two open beaches, one topographic) over 3 days in varying wave conditions. Floating was found to be a longer duration, more variable escape strategy ( $ \overline{t} $  = 3.8 min, σ = 2.4 min), than swimming parallel ( $ \overline{t} $  = 2.2 min, σ = 1.0 min). Neither of the scenarios is 100 % foolproof, and both fail in some scenarios, making simplified safety recommendations difficult. Swim parallel failures are related to swimming against the alongshore current of the rip circulation. Float failures related to surf zone exits, with the highest exit rate occurring in the topographic rip. Float failures also occurred due to multiple re-circulations without the person attaining safe footing on the bar. The variable spatial and temporal behaviour of rip currents suggests that a single escape strategy safety message is inappropriate. Instead, a combined approach and scenario-specific safety advice should be considered by beach safety practitioners to promote to the public.     

Teaching Orientalism in Introductory Human Geography

This article explores efforts to bring postcolonial theory into the undergraduate human geography classroom. Through a case study of teaching Edward Said's Orientalism in introductory human geography, we discuss the relevance of postcolonial theory to critical pedagogy in geography. We lay out how instructors can teach Orientalism in introductory courses, what happens when they do so, and where efforts to use postcolonial theory to help students analyze the “colonial present” can be improved. We suggest that postcolonial theory is particularly well suited pedagogically to show students the mechanisms and uneven power relations producing and sustaining past and present geographies of difference.