QUANTITATIVE ANALYSIS OF TRACE ELEMENTS IN GEOLOGICAL MATERIALS BY LASER ABLATION ICPMS: INSTRUMENTAL OPERATING CONDITIONS AND CALIBRATION VALUES OF NIST GLASSES

A UV laser ablation microprobe coupled to an ICPMS has been used to determine trace element concentrations in solids with a spatial resolution of 50 microns and detection limits ranging from 2 μg/g for Ni to 50 ng/g for the REE, The, and U. Experiments designed to optimize laser operating conditions show that pulse rates of 4 Hz produce a steady state signal with less inter-element fractionation per unit time than higher pulse rates (10–20 Hz). Comparisons of laser microprobe analyses of garnets and pyroxenes using the NIST 610 and 612 glasses as calibration standards, with proton microprobe, solution ICPMS, INAA and XRF data show no significant matrix effects. Laser microprobe analyses of the NIST 610 and 612 glasses have a precision and accuracy of 2–5%, and error analysis shows that counting statistics and the precision on the internal standard concentration accounts for the analytical uncertainty. The NIST glasses appear to be useful calibration materials for trace element analysis of geological materials by laser microprobe.     

Generalized Expanding and Shearing Anisotropic Bianchi Type I Magnetofluid Cosmological Model in General Relativity

The behaviour of magnetic field in anisotropic Bianchi type I cosmological model for perfect fluid distribution in General Relativity, is investigated. The distribution consists of an electrically neutral perfect fluid with an infinite electrical conductivity. It is assumed that the component ¹ ₁ of shear tensor ^j _i is proportional to the expansion () which leads to A = (BC)ⁿ. The other physical and geometrical aspects of the model are also discussed, Bali (1986) obtained the cosmological model for n = 1 in presence of magnetic field. We have investigated the model for general values of n and discussed the particular case and general behaviour of the model.     

BICUBIC SPLINE INTERPOLATION: A QUANTITATIVE TEST OF ACCURACY AND EFFICIENCY*

Two different methods for the construction of an approximation to bicubic splines for interpolating irregularly spaced two-dimensional data are described. These are referred to as the least squares line (LSL) and linear segment (LINSEG) construction procedures. A quantitative test is devised for investigating the absolute accuracy and efficiency of the two spline interpolation procedures. The test involves (i) laying of artificial flight lines on the analytically known field of a model, (ii) interpolation of field values along the flight lines and their subtraction from the original field values to compute the residuals. This test is applied on fields due to four models (three prism models and one dyke model) placed at different depths below the flight lines, and for each case the error estimates (the mean error, the maximum error and the standard deviation) are tabulated. An analysis of the error estimates shows in all cases the LSL interpolation to be more accurate than the LINSEG, although the latter is about 50% faster in computer time. The relative accuracy and efficiency of the LSL interpolation is also tested against a recent method based on harmonization procedure, which shows the latter to be more precise, though much slower in speed.     

Effect of Nickel and Cadmium on Ammonium Uptake Kinetics of Free and Immobilized Cells of Anacystis nidulans

The stress effect of Ni and Cd on the ammonium uptake varied significantly (ANOVA test) in free and immobilized state of the test organism. The effect due to the interaction between different variables (cell state type, metal type and metal dose) was studied to depict the significant or non‐significant variation in the ammonium uptake by free and immobilized cells in the presence of metal ions. Ammonium uptake exhibited a competitive mode of inhibition in the presence of Ni in both free and immobilized state of the organism. However, Cd exhibited non‐competitive and competitive inhibition in free and immobilized cells, respectively. The study demonstrates that there is a considerable influence of metal ions on the ammonium uptake. Cd was found to be more toxic compared to Ni in both free and immobilized state.     

Relation between spring water radon anomalies and seismic activity in Garhwal Himalaya

The variations of spring water radon concentration and meteorological parameters were analysed in relation to the seismic activities in Garhwal Himalaya, India. The radon anomalies were classified on the basis of statistical treatment of the daily observations. The precise measurements of water discharge rate from the spring have been made along with radon measurements for earthquake precursory study. The earthquakes with epicentral distances less than 150 km were considered by an empirical relationship. Pre-, co-, and post-seismic changes in the radon concentration were taken carefully into account in the empirical relationship to establish this behaviour as a potential earthquake precursor. The empirical relationship has been validated by the radon data recorded from the spring waters. The magnitudes of the earthquakes were estimated by using the empirical relationship by introducing computed correlation coefficient of radon and meteorological parameters. The calculated magnitude of some local earthquakes matches exactly with the magnitude recorded by the laboratory seismograph. The possible mechanisms that may cause a radon anomaly are also discussed.     

Adsorption of Cadmium Ions from Aqueous Solution Using Granular Activated Carbon and Activated Clay

The present study was aimed at removing cadmium ions from aqueous solution through batch studies using adsorbents, such as, granular activated carbon (GAC) and activated clay (A‐clay). GAC was of commercial grade where as the A‐clay was prepared by acid treatment of clay with 1 mol/L of H₂SO₄. Bulk densities of A‐clay and GAC were 1132 and 599 kg/m³, respectively. The surface areas were 358 m²/g for GAC and 90 m²/g for A‐clay. The adsorption studies were carried out to optimize the process parameters, such as, pH, adsorbent dosage, and contact time. The results obtained were analyzed for kinetics and adsorption isotherm studies. The pH value was optimized at pH 6 giving maximum Cd removal of 84 and 75.2% with GAC and A‐clay, respectively. The adsorbent dosage was optimized and was found to be 5 g/L for GAC and 10 g/L for A‐clay. Batch adsorption studies were carried out with initial adsorbate (Cd) concentration of 100 mg/L and adsorbent dosage of 10 g/L at pH 6. The optimum contact time was found to be 5 h for both the adsorbents. Kinetic studies showed Cd removal a pseudo second order process. The isotherm studies revealed Langmuir isotherm to better fit the data than Freundlich isotherm.     

DIKE FORMATION WITH SUBMERGED VANE

1 INTRODUCTION Increasing capital costs, emerging environmental concerns and rising maintenance expenses of conventional river training works around the world have led to the development of submerged vanes in practice. Submerged vanes are being favoured f…