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141.
Marc Walther Lars Bilke Jens-Olaf Delfs Thomas Graf Jens Grundmann Olaf Kolditz Rudolf Liedl 《Environmental Earth Sciences》2014,72(10):3827-3837
This paper evaluates the remediation potential of a salinized coastal aquifer by utilizing a scenario simulation. Therefore, the numerical model OpenGeoSys is first validated against analytical and experimental data to represent transient groundwater level development and variable density saline intrusion. Afterwards, a regional scale model with a three-dimensional, heterogeneous hydrogeology is calibrated for a transient state and used to simulate a best-case scenario. Water balances are evaluated in both the transient calibration and scenario run. Visualization techniques help to assess the complex model output providing valuable insight in the occurring density-driven flow processes. Furthermore, modeling and visualization results give information on the time scale for remediation activities and, due to limitations in data quality and quantity reveal potential for model improvement. 相似文献
142.
143.
Barbara Funk Rudolf Dvorak Richard Schwarz 《Celestial Mechanics and Dynamical Astronomy》2013,117(1):41-58
In this investigation we treat a special configuration of two celestial bodies in 1:1 mean motion resonance namely the so-called exchange orbits. There exist—at least—theoretically—two different types: the exchange-a orbits and the exchange-e orbits. The first one is the following: two celestial bodies are in orbit around a central body with almost the same semi-major axes on circular orbits. Because of the relatively small differences in semi-major axes they meet from time to time and exchange their semi-major axes. The inner one then moves outside the other planet and vice versa. The second configuration one is the following: two planets are moving on nearly the same orbit with respect to the semi-major axes, one on a circular orbit and the other one on an eccentric one. During their dynamical evolution they change the characteristics of the orbit, the circular one becomes an elliptic one whereas the elliptic one changes its shape to a circle. This ‘game’ repeats periodically. In this new study we extend the numerical computations for both of these exchange orbits to the three dimensional case and in another extension treat also the problem when these orbits are perturbed from a fourth body. Our results in form of graphs show quite well that for a large variety of initial conditions both configurations are stable and stay in these exchange orbits. 相似文献
144.
Yuanming Pan Mao Mao Zucheng Li Sanda M. Botis Rudolf I. Mashkovtsev Anton Shatskiy 《Physics and Chemistry of Minerals》2012,39(8):627-637
Single-crystal electron paramagnetic resonance spectra of electron-irradiated stishovite, measured at temperatures from 3.5 to 294?K, reveal three S?=?1/2 radiation-induced defects: an aluminum-associated oxygen hole center and two nd 1 centers (Ti3+ and W5+). The aluminum-associated oxygen hole center, characterized by an orthorhombic site symmetry, coaxial matrices of the electronic Zeeman g, nuclear hyperfine A(27Al) and nuclear quadrupole P(27Al), and the orientation of the g-minimum axis along an O–O direction and those of the unique A(27Al) and P(27Al) axes perpendicular to the O–O direction, is an Al–O2 3? center, with the unpaired electron equally distributed on two equatorial oxygen atoms of a substitutional Al3+ ion at the octahedral Si site. Fully optimized Al-doped structure, theoretical 27Al nuclear hyperfine and quadrupole coupling constants and directions, and 3D spin densities from periodic hybrid density functional theory calculations provide further support for this structural model. Spin Hamiltonian parameters of the Ti3+ and W5+ centers, which are confirmed by their diagnostic 47Ti, 49Ti and 183W hyperfine structures, arise from electron trapping on substitutional Ti4+ and W6+ ions at the octahedral Si site. 相似文献
145.
146.
Weibiao HSU Aicheng ZHANG Rainer BARTOSCHEWITZ Yunbin GUAN Takayuki USHIKUBO Urs KRÄHENBÜHL Rainer NIEDERGESAESS Rudolf PEPELNIK Ulrich REUS Thomas KURTZ Paul KURTZ 《Meteoritics & planetary science》2008,43(8):1363-1381
Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al2O3 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon. 相似文献
147.
We extend our two previous studies on the existence of stable orbits in the Solar System by examining the domain between Jupiter and Saturn. We place (1) a massless object, (2) a Moon-mass object, (3) a Mars-mass object, (4) an Earth-mass object, and (5) a Uranus-mass object in the said region. Note that these objects are considered separately in the framework of our simulations. Our goal is to explore the orbital stability of those objects. We employ the Lie-integration method, which is fast and well established, allowing us to solve the respective differential equations for the -body system. Hence, we consider the celestial bodies spanning from Jupiter to Neptune, including the aforementioned test object, the main focus for our model simulations. The integrations indicate that in some models the test objects placed in the region between Jupiter and Saturn reside in that region for more than 600 Myr. Between 5 and 10 au, mean-motion resonances (MMRs) take place acting upon the test objects akin to simulations of Paper I and II. Our models indicate relatively small differences for the long-term stability of the five test objects notwithstanding their vastly different masses. Generally, it is found that between and 7.13 au the orbits become unstable mostly within 5 million years and further out, that is, up to au, the duration of stability lengthens to up to hundreds of millions of years. 相似文献
148.
Bulk geochemical parameters and organic matter biomarkers in a short, high resolution gravity core (Lake Valencia, Venezuela) were examined to reconstruct anthropogenic impacts on the lake’s conditions. During the period of ca. 1840–1990, sedimentary organic matter was characterized by high contents of total organic C (TOC) and total N (TN), low TOC/TN values as well as relatively enriched δ13C and δ15N signals, suggesting a primary autochthonous (algae and macrophytes) organic matter origin. The occurrence of large amounts of C23 and C25 relative to C29 and C31n-alkanes indicated substantial inputs from submerged/floating macrophytes. The variations of C32 15-keto-ol, tetrahymanol, diploptene, C32 bishomohopanol, 2-methylhopane, dinosterol and isoarborinol concentrations over the investigated period record changes in the planktonic community structure, including Botryococcus braunii, bacteriavore ciliates, cyanobacteria, Eustigmatophytes and dinoflagellates. A principal shift occurred in the 1910s when cyanobacteria and dinoflagellates became more abundant at the expense and decline of B. braunii and Eustigmatophytes, likely related to increasing anthropogenic activity around the lake. A second shift (less obvious) occurred in the 1960s when cyanobacteria became the sole predominant planktonic class, coinciding with further deterioration of lake conditions. 相似文献
149.
Anja Stojanovic Daniel Kogelnig Dieter Mader Rudolf Krachler 《Chemie der Erde / Geochemistry》2009,69(3):223-234
General geochemical parameters of water, superficial sediments, and suspended particulate matter (SPM) were determined from small shallow saline lakes (soda ponds) as well as from lake Neusiedlersee in eastern Austria. Additionally, instrumental neutron activation analysis (INAA) was used to determine the distribution of major, rare earth and other trace elements in superficial sediments and SPM. Chemical results show remarkable differences in salinity and ionic strength between the investigated ponds. Anthropogenic effects, such as drawdown of ground water level and a loss of lake water due to drainage, are clearly reflected in obtained chemical and geological data. Due to a strong dependence of the complexation and scavenging behavior of the rare earth elements (REE) on ionic strength, a significant difference between REE concentrations in soda ponds with different anthropogenic impact was found. The content and composition of authigenic evaporitic minerals in superficial sediments and SPM clearly differ with a fluctuating water level and salt concentration. Furthermore, we determined the distribution of major and trace elements in superficial sediments of a nearby fluvial system. Our results show a clear correlation between REE superficial sediment concentrations in anthropogenically degraded soda ponds and fluvial system. Therefore, we assume that REE concentrations of sediments and SPM are suitable for the study of geochemical changes of inland saline lakes due to anthropogenic impacts on water balance. 相似文献
150.