3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Some applications of paleoecology to the management of tidal marshes

The shallow-water habitat is under increasing environmental pressures from accelerated sea-level rise and continual urban sprawl and will require well-informed management decisions to maintain its health into the future. One of the keys to the effective management of the shallow-water habitat is understanding the processes responsible for its development. Paleoecology has the potential to provide much insight into the development of the system, particularly when the impacts of accelerated sea-level rise on vegetation and sedimentation dynamics in tidal marshes is being considered. For example, a paleoecological comparison of tidal salt marshes to tidal freshwater marshes shows that rates of development will dictate the system's response to accelerated sea-level rise, with tidal freshwater marshes capable of transgressing landward more rapidly than their saline counterparts. Such information implies that management of the adjacent uplands is as important to the future of the system as management of the marsh itself. Therefore, it is important to consult paleoecological research when management strategies are being considered. *** DIRECT SUPPORT *** A01BY074 00010     

Impact of quarrying gypsum in a semidesert karstic area (Sorbas,SE Spain)

The Messinian gypsum of Sorbas is intensively karstified, with hundreds of dolines and numerous, highly unusual exo- and endokarstic forms. Amongst these the tumuli are especially spectacular, as are the large caverns, adorned with numerous speleothems, some of which have not been described anywhere else in the World. The extraction of the gypsum has impacted practically all the elements of the environment (landscape, water, soil, subsoil, flora, fauna, etc.) and, in particular, all of the karstic forms. In addition to endangering the caves and the natural treasures that they contain, it affects the surface waters, markedly modifying the hydrographic network. Groundwaters, which now occur in the bottom of a quarry, are also affected.     

Recent landslide activity in Manaihan,East Belgium

Past landslides have been recognized in the Battice area in E-Belgium. In contrast to the other inactive landslides, the Manaihan landslide responded immediately to heavy rainfall events in the last two decades. This study aims to map its spatial extent and the dominant surface features; to measure surface displacement using GPS; to investigate subsurface structure with Cone penetration test (CPT) and corings; and to determine the depth of the shear surface by inclinometers. Results show a partial landslide reactivation. Surface velocities range between 20 and 40 cm/year and are strongly dependent on winter rainfall. CPT results give clear boundaries between the landslide mass and the undisturbed bedrock in the head scarp. Distinct shear surfaces have been determined with displacement rates up to 15.8 mm in 21 days. Further research should apply geophysical methods for two-dimensional information on the ground, investigate geotechnical properties of the landslide mass, model slope instability, and determine the influence of a sewage pipe crossing the central landslide mass as a potential cause for landslide activity.     

The magnetic fields and density of relativistic electrons in the nucleus of NGC 1052

We analyze observations of the compact GHZ-peaked-spectrum radio source in the nucleus of the weakly active galaxy NGC 1052, assuming that the low-frequency turnover in its spectrum is due to synchrotron self-absorption. The analysis is based on a model for an inhomogeneous source of synchrotron radiation. It is shown that the magnetic field is not uniform, but the change in the field strength from the center to the edge of the compact radio source does not exceed an order of magnitude. The maximum magnetic-field strength in the nucleus of NGC 1052 is 20 G < H _⊥ < 200 G, and the density of relativistic electrons is 0.018 cm⁻³ < n _e < 0.18 cm⁻³ on scales of 0.1 pc; everywhere in the radio source, the energy density of the magnetic field exceeds the energy density of the relativistic electrons. The physical conditions are similar to those in the nuclei of the nearby radio galaxies 3C 111 and 3C 465, and differ strongly from those in the nucleus of the radio galaxy 0108+388, which is a compact GHz-peaked-spectrum source (these three galaxies were studied by the authors earlier using the same method).     

Catagenesis of organic matter at the top and base of the Jurassic complex in the West Siberian megabasin

Thermal maturation for the top and base of the Jurassic in the West Siberian megabasin was modeled on the basis of the vitrinite reflectance (R_vt⁰) data using mathematical modeling and computer simulations. The values of thermal maturation are found to vary within substages PC₃-MC₃² for the top (or being equivalent to PC₃-MC₁² on the periphery and southern part of the basin, or to MC₂-MC₃² in the north) and PC₃-AC₃ for the base of the Jurassic (or being equivalent to PC₃-MC₂ on the periphery and southern part of the basin or MC₃¹-AC₃ in the north). Thermal maturity levels of the Jurassic in West Siberia are controlled by depths of burial and peak temperatures which the source rocks were subjected to during this period. The situation is further complicated by high heat flows superimposed on the regional background, which are observed in deep fault zones and in the proximity of numerous igneous bodies.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

Late Ordovician stratigraphy northwest of the Sugarloaf,mid-Wales — a discussion

Several modifications are proposed to the Ordovician stratigraphy recently proposed by Mackie and Smallwood (1987), based in particular on the recognition of a major Mynydd Trawsnant anticline on the northwest flank of the Tywi structure and on field relationships indicating the Foel Formation directly to overlay the Caradoc black shale succession and directly to underlay the Craig Las Formation. The Clyn Glas Formation is suggested to have accumulated at a slope base rather than a shelf–slope break.     

Predictive Capabilities of Avalanche Models for Solar Flares

We assess the predictive capabilities of various classes of avalanche models for solar flares. We demonstrate that avalanche models cannot generally be used to predict specific events because of their high sensitivity to the embedded stochastic process. We show that deterministically driven models can nevertheless alleviate this caveat and be efficiently used for predictions of large events. Our results suggest a new approach for predictions of large (typically X-class) solar flares based on simple and computationally inexpensive avalanche models.