Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.     

Solar and stellar chromospheric contrast

Positions of active regions estimated from observations of the whole solar disk in Caii K _iv during the period 1977–1989 at the Coimbra Astronomical Observatory are compared with the time-dependent latitudinal distribution of background solar magnetic fields and with the latitudinal shifts of boundaries of their polarities. We confirm that the sunspot groups are located near the zonal boundaries between the opposite polarities of the solar background magnetic field during different phases of the two recent consecutive cycles of activity. We demonstrate a probable connection between the increased number of groups and the commencement of poleward migration of zonal boundaries in both hemispheres. But the influence of the dominant convective rolls seems to he still unclear. A new problem of interrelation between the zonal and sector boundaries has also appeared.     

MaxEnt power spectrum estimation using the Fourier transform for irregularly sampled data applied to a record of stellar luminosity

The principle of maximum entropy is applied to the spectral analysis of a data signal with general variance matrix and containing gaps in the record. The role of the entropic regularizer is to prevent one from overestimating structure in the spectrum when faced with imperfect data. Several arguments are presented suggesting that the arbitrary prefactor should not be introduced to the entropy term. The introduction of that factor is not required when a continuous Poisson distribution is used for the amplitude coefficients. We compare the formalism for when the variance of the data is known explicitly to that for when the variance is known only to lie in some finite range. The result of including the entropic measure factor is to suggest a spectrum consistent with the variance of the data which has less structure than that given by the forward transform. An application of the methodology to example data is demonstrated.     

A Comparison of the 10.7-cm Radio Flux Values and the International Sunspot Numbers for Solar Activity Cycles 19, 20, and 21

A nonlinear analysis of the daily 10.7-cm radio flux values for each of Solar Cycles 19, 20, and 21 is used to determine if the results match those of the International Sunspot Numbers for each of these cycles. Fractals and chaos are described and a brief review of utilizing fractals and chaos is given. The origin of the 10.7-cm radio flux is discussed and a short review of recent work discussing its measurement and its relation to the international sunspot number and other proxies for solar activity cycles given. The parameters used to describe chaos for the 10.7-cm radio flux are discussed. The length of the data sets for either statistical analysis or nonlinear analysis of the 10.7-cm radio flux values is considered. These results indicate that the 10.7-cm radio flux values appear to be stochastic for Cycle 19 and chaotic for Cycles 20 and 21. The International Sunspot Numbers show similar behavior for these three cycles. A day-by-day comparison of the dimensionless 10.7-cm radio flux values and the dimensionless International Sunspot Numbers differences shows a linear trend. The results remain consistent in that the 10.7-cm radio flux values indicate, as did the International Sunspot Numbers, that there is a transition from stochastic behavior for Cycle 19 to chaotic behavior in Cycles 20 and 21. The day-by-day comparison of the 10.7-cm radio flux values and the International Sunspot Numbers emphasizes that the 10.7?cm radio flux values are responding to the magnetic field associated with the sunspots.     

Bounce Rock—A shergottite‐like basalt encountered at Meridiani Planum,Mars

Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.     

Effects of hopper dredging and sediment dispersion,chesapeake bay

Hopper dredging operations release suspended sediment into the environment by agitation of the bed and by discharge of overflow slurries. Monitoring of turbidity and suspended sediment concentrations in central Chesapeake Bay revealed two plumes: (1) an upper plume produced by overflow discharge and (2) a near-bottom plume produced by draghead agitation and rapid settling from the upper plume. The upper plume dispersed over 5.7 km² extending 5,200 meters form the discharge point. Redeposited sediment accumulated on channel flanks covering an area of 6.4 km² and reached a thickness of 19 cm. Altogether dredging redistributed into the environment an estimated 100,000 tons of sediment or 12 percent of the total material removed.Near-field concentrations of suspended sediment, less than 300 m from the dredge, reach 840 to 7,200 mg/L or 50 to 400 times the normal background level. Far-field concentrations (>300 m) are enriched 5 to 8 times background concentrations and persist 34 to 50 percent of the time during a dredging cycle (1.5 to 2.0 h). The overflow discharge plume evolves through three dispersion phases: (1) convective descent, (2) dynamic collapse, and (3) long-term passive diffusion (Clark and others 1971). The bulk of the material descends rapidly to the bottom during the convective descent phase, whereas the cloud that remains in suspension is dispersed partly by internal waves. Although suspended sediment concentrations in the water column exceed certain water quality standards, benthic communities survived the perturbation with little effect.     

The Uncertainty in the True End Point of a Fossil's Stratigraphic Range When Stratigraphic Sections Are Sampled Discretely

Stratigraphic sections are often sampled at well-defined discrete points. Because of the incompleteness of the fossil record, a particular species may not be observed even when it is extant at a sampling point. We introduce a model and Bayesian analysis for estimating the true time of disappearance of a lineage from a section in the face of the possibility that failure to find the species beyond its observed stratigraphic range may represent false negatives. We incorporate proper prior information, including an estimated longevity of the species and the probability that it will be observed if extant. Our analysis produces a posterior density for the true extinction time of the species. Summaries of this probability distribution provide a point estimate of the extinction time, a standard deviation for the uncertainty in the estimate, and confidence intervals for the time of extinction. We apply our model to stratigraphic ranges of benthic foraminifera collected from the early Late Cretaceous (Cenomanian and Turonian) from Eastbourne, England.