农户行为视角下的乡村生产空间系统运行机制及重构启示

农户行为转变是乡村生产空间系统量变或从量变到质变的重要驱动力,乡村生产空间系统的运行实质上是农户行为作用的外在表现,厘清农户行为可为诠释乡村生产空间系统的运行机制提供平台。本文在剖析农户行为转变与乡村生产空间系统运行响应的理论框架基础上,从农户行为转变和乡村生产空间系统响应入手构建指标体系,建立模糊综合评价量化模型,并以重庆市江津区恒和村作为实证,诠释乡村生产空间系统运行机制。主要研究结论为：不同农户行为对乡村生产空间系统运行的影响程度各异,大体为生产大户>合作社农户>传统农户;不同农户行为对系统运行响应结果的作用差异明显,生产大户行为主要影响乡村生产空间的利用效率,合作社农户行为对提升生产空间系统经济效益作用明显,传统农户行为对生产空间系统环境改善的贡献作用最小。并从经济、社会、空间重构视角提出发展多种形式的适度规模化经营、培育新型农业经营主体和职业农民、合理引导农户技术和资本投入等建议,以实现乡村生产空间系统协调与均衡发展。     

Early middle Holocene climate oscillations recorded in the Beihuqiao Core,Yuhang, Zhejiang Province,China

A long-standing controversy exists concerning the spatial and temporal characteristics of Holocene climate change in China. Zhejiang is located in the southeast of China, where the East Asian monsoon dominates the climate and a Neolithic culture flourished. In recent years, geographers have debated the climatic conditions existing at the time of the Neolithic cultures. This study reconstructed the sedimentary environment between 11.30 and 4.17 cal ka BP based on a multi-proxy analysis of a 14.3 meter sediment core, drilled in Beihuqiao, Zhejiang Province, China. The results show: (1) The climate was getting warm between 11.50 and 8.77 cal ka BP. Grain size became finer from the bottom to the top layer, accompanied by an increase in the chemical index of alteration (CIA), Mg/Sr ratio, the percentage of clay, pollen concentrations, and a decrease in SiO₂/Al₂O₃ ratio, and the value of bases–alumina (ba), as well as other trace elements. (2) Between 8.77 and 7.99 cal ka BP, the sediment is composed of gray-yellow and gray silt. The percentage of CaO and the ratio of CaO + Na₂O + K₂O to Al₂O₃ is much higher. The pollen concentration sharply decreases. The climate was cold and dry in the early stages of this period, but became relatively warmer and wetter in the later stages. (3) The Holocene Climatic Optimum occurred at 7.99–5.68 cal ka BP. Higher contents of clay, total Fe₂O₃, Al₂O₃, CIA, the chemical proxy of alteration, pollen concentration, evergreen pollens, and high values of Mg/Sr are observed at this stage, coinciding with a lower SiO₂/Al₂O₃ value, (CaO + Na₂O + K₂O)/Al₂O₃ ratio, and an obvious reduction in silt/clay, and SiO₂ and CaO concentrations. (4) During the period 5.68–4.17 cal ka BP, the temperature in the study area declined in a stepwise fashion. The grain size became finer, and the Mg/Sr ratio decreased gradually.     

Atmospheric chemistry of hydrogen fluoride

Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence.     

热带平流层多尺度波动分离方案的研究：多站点高分辨率无线电探空联合分析

利用太平洋地区台风过境期间6个热带气象站的高分辨率无线电探空资料,结合扩展经验正交函数（EEOF）展开,对热带下平流层行星波和重力波扰动进行了分离,给出了一种热带地区提取重力波扰动的新方案。对观测数据做EEOF展开后,选择表征行星尺度波动模态的特征向量和相应权重进行气象要素场的重建。结果显示,在不同的台风过程期间,温度、纬向风和经向风的重建扰动量显示出不同的动力学偏振关系:在准两年振荡（QBO）东风位相时与赤道开尔文波的偏振关系一致,而在准两年振荡西风位相时与混合罗斯贝-重力波（MRG）的偏振关系一致。把行星尺度波动模态从原始观测中剔除,得到新的扰动廓线,对其进行重力波垂直波数谱的谱型拟合。结果发现,与以往方法提取的重力波扰动相比,新方法所得谱型参数中特征垂直波长λ*在不同时期不同站点变化很小,稳定在1.7 km左右,且低频波数段谱斜率s的数值与理论假设1十分接近。综合其研究结果可以推测,用新方法提取的热带重力波扰动更加符合当前的理论垂直波数谱模型。      

北京不同区域气溶胶辐射效应

采用大气辐射传输模式SES2以及2013年1月—2015年10月欧洲中期天气预报中心细网格再分析资料计算了北京地区4个观测站地面接收的短波辐射通量,分析了晴天和云天北京城郊气溶胶对总辐射的定量影响时空变化特征。结果表明:北京城区和近郊区气溶胶对总辐射的影响约为远郊区的2倍,北京南部和西部气溶胶对辐射的影响较大,晴天和云天北京城区和近郊区气溶胶对总辐射的削减值分别为146.23~180.99 W·m-2和202.11~217.02 W·m-2,晴天总辐射削减空间差异较大;秋冬季气溶胶对总辐射的影响明显大于春夏季,北京市观象台秋冬季气溶胶对总辐射的削减作用最大可达60%,较春夏季高10%~20%;北京城郊总辐射和直接辐射削减率与气溶胶光学厚度变化均呈线性关系,近地面PM_2.5浓度对辐射的影响不容忽视。     

Acidity of Aerosols during Winter Heavy Haze Events in Beijing and Gucheng,China

We investigated the acidity and concentrations of water-soluble ions in PM_2.5 aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO₄^2–, NO₃^–, and NH₄⁺ concentrations were 8.3, 12.5, and 14.1 μg m^–3, respectively, at the urban site and 14.0, 14.2, and 24.2 μg m^–3, respectively, at the rural site. The nitrogen and sulfur oxidation ratios in urban Beijing were correlated with relative humidity (with correlation coefficient r = 0.79 and 0.67, respectively) and the aerosol loadings. Based on a parameterization model, we found that the rate constant of the heterogeneous reactions for SO₂ on polluted days was about 10 times higher than that on clear days, suggesting that the heterogeneous reactions in the aerosol water played an essential role in haze events. The ISORROPIA II model was used to predict the aerosol pH, which had a mean (range) of 5.0 (4.9–5.2) and 5.3 (4.6–6.3) at the urban and rural site, respectively. Under the conditions with this predicted pH value, oxidation by dissolved NO₂ and the hydrolysis of N₂O₅ may be the major heterogeneous reactions forming SO₄^2– and NO₃^– in haze. We also analyzed the sensitivity of the aerosol pH to changes in the concentrations of SO₄^2–, NO₃^–, and NH₄⁺ under haze conditions. The aerosol pH was more sensitive to the SO₄^2– and NH₄⁺ concentrations with opposing trends, than to the NO₃^– concentrations. The sensitivity of the pH was relatively weak overall, which was attributed to the buffering effect of NH₃ partitioning.     

德州一次沙尘天气过程成因及气溶胶粒子的输送路径分析

利用NCEP 1°×1°再分析资料分析了2017年5月4日浮尘和5月5日扬沙天气的成因。结果表明：3日20时—4日08时,蒙古气旋在有利的环流背景下迅速发展,配合冷锋在内蒙古中部和东部形成大范围的强沙尘天气;4日20时—5日08时沙尘通过高空气流输送到华北地区,在自身沉降和较强下沉气流的共同作用下,迅速沉降形成华北地区大范围的浮尘天气;5日08—14时由于西北路冷空气影响,横槽转竖,冷锋加速南下,将大量沙源地的沙尘输送到德州造成扬沙天气。通过HYSPLIT模式对本次过程中气团后向轨迹的模拟,证实以上两个阶段沙尘天气过程中的输送方式及路径。通过分析影响系统、物理量和气象要素发现,蒙古国、我国内蒙古中部沙源地天气系统强度、位置的变化直接影响沙尘天气的类型,高层气流变化与沙尘天气的类型有很好的对应关系。     

2006—2015年山东短时强降水时空分布特征

利用山东2006—2015年5—9月123个国家级气象观测站10 a逐小时降水量资料,统计分析了山东短时强降水的时空分布特征,结果表明：1）站次时空分布不均。鲁南易出现短时强降水,2013年最多,达到了564站次,7月最多,平均207站次,多出现在傍晚前后和凌晨。2）极值时空分布差异较大。10 a单站极值大值区分布在鲁西北、鲁南和半岛东部,2009年最多,为17站,且多夜间发生;10 a中年度极值均出现在13:00—次日02:00,8月最多,为7次。3）5、6、9月局地和小范围短时强降水天气过程所占比例较大,7—8月大范围短时强降水过程明显增加。     

地形对台风“海燕”暴雨增幅作用的观测与模拟

1330号台风"海燕"过程影响海南岛的强降水落区和强降水极值点(毛感乡)均位于南部地区,利用海南省区域加密自动站、三亚多普勒雷达以及0.25°×0.25°ERA-interim再分析资料对强降水成因进行观测分析,应用WRF Ver3.1.1模式对"海燕"进行模拟试验。结果表明:(1)"海燕"从海南岛南部近海北上阶段,其外围的偏东风或偏南风与五指山、吊罗山形成向南开口的"厂"字形地形正交,加密自动站和多普勒雷达在五指山区及"厂"字形地形南侧均探测到多个β中尺度风向辐合切变线或气旋性辐合涡旋,毛感乡附近存在明显的风向辐合,地面辐合中心与小时雨量大值区基本吻合。(2)"厂"字形地形迎风坡的强迫抬升导致气流垂直速度增大,毛感乡附近存在的水平的β中尺度辐合切变和垂直的β中尺度环流,有利于边界层辐合和中高层辐散增强,降水显著增幅。(3)数值模拟的强降水落区和降水极值点与实况基本一致,极值雨量较实况偏小;地形对山区及山脉迎风(背风)坡的雨量增(减)幅作用明显;有地形时,在五指山区及"厂"字形地形南侧容易产生β中尺度风向辐合区。     

Acidity of Aerosols during Winter Heavy Haze Events in Beijing and Gucheng,China

We investigated the acidity and concentrations of water-soluble ions in PM_(2.5) aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO_4~(2–), NO_3~–, and NH_4~+ concentrations were 8.3,12.5, and 14.1 μg m~(–3), respectively, at the urban site and 14.0, 14.2, and 24.2 μg m~(–3), respectively, at the rural site.The nitrogen and sulfur oxidation ratios in urban Beijing were correlated with relative humidity(with correlation coefficient r = 0.79 and 0.67, respectively) and the aerosol loadings. Based on a parameterization model, we found that the rate constant of the heterogeneous reactions for SO_2 on polluted days was about 10 times higher than that on clear days, suggesting that the heterogeneous reactions in the aerosol water played an essential role in haze events.The ISORROPIA II model was used to predict the aerosol pH, which had a mean(range) of 5.0(4.9–5.2) and 5.3(4.6–6.3) at the urban and rural site, respectively. Under the conditions with this predicted pH value, oxidation by dissolved NO_2 and the hydrolysis of N_2O_5 may be the major heterogeneous reactions forming SO_4~(2–) and NO_3~– in haze.We also analyzed the sensitivity of the aerosol p H to changes in the concentrations of SO_4~(2–), NO_3~–, and NH_4~+ under haze conditions. The aerosol p H was more sensitive to the SO_4~(2–) and NH_4~+ concentrations with opposing trends, than to the NO_3~– concentrations. The sensitivity of the p H was relatively weak overall, which was attributed to the buffering effect of NH_3 partitioning.