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71.
Md. S. Rahman K. V. Sathasivam 《International Journal of Environmental Science and Technology》2016,13(8):1973-1988
Biosorption is a promising technology for the removal of heavy metals from industrial wastes and effluents. In the present study, biosorption of Pb2+, Cu2+, Fe2+ and Zn2+ onto the dried biomass of Eucheuma denticulatum (Rhodophyte) was investigated as a function of solution pH, contact time, temperature and initial metal ion concentration. The experimental data were evaluated by Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherm models. The sorption isotherm data followed Langmuir and Freundlich models, and the maximum Langmuir monolayer biosorption capacity was found as 81.97, 66.23, 51.02 and 43.48 mg g?1 for Pb2+, Cu2+, Fe2+ and Zn2+, respectively. The sorption kinetic data followed pseudo-second-order and intraparticle diffusion models. Thermodynamic study revealed feasible, spontaneous and endothermic nature of the sorption process. Fourier transform infrared analysis showed the presence of amine, aliphatic, carboxylate, carboxyl, sulfonate and ether groups in the cell wall matrix involved in metal biosorption process. A total of nine error functions were applied in order to evaluate the best-fitting models. We strongly suggest the analysis of error functions for evaluating the fitness of the isotherm and kinetic models. The present work shows that E. denticulatum can be a promising low-cost biosorbent for removal of the experimental heavy metals from aqueous solutions. Further study is warranted to evaluate its potential for the removal of heavy metals from the real environment. 相似文献
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A quality study of the drained water from Maddhapara Granite Mine underground tunnel was undertaken to study their hydrochemical variations and suitability for various uses employing chemical analysis, basic statistics, correlation matrix (r), cluster analysis, principal component/factor analyses, and ANOVA as the multivariate statistical methods. The results of chemical analysis of water show the modest variation in their ionic assemblage among different sampling points of the tunnel where Ca–HCO3 type of hydrochemical facies is principally dominated. The correlation matrix shows a very strong to very weak positive, even negative, correlation relationship, suggesting the influence of different processes such as geochemical, biochemical processes, and multiple anthropogenic sources on controlling the hydrochemical evolution and variations of water in the mine area. Cluster analysis confirms that cluster 1 contains 68.75% of total samples, whereas cluster 2 contains 31.25%. On the whole, the dominated chemical ions of first cluster groups are Ca and HCO3, suggesting a natural process similar to dissolution of carbonate minerals. The second cluster group consisted of Cl? and SO4 2? ions representing natural and anthropogenic hydrochemical process. The results of PCA/FA analysis illustrate that different processes are involved in controlling the chemical composition of groundwater in the mine area. The factor 1 loadings showed that pH, EC, TDS, Na, Mg, chloride, and sulfate which have high loading in this factor are expected to come from carbonate dissolution to oxidation conditions. One-way ANOVA describes the significance of dependent variables with respect to independent variables. ANOVA gives us the idea that EC, K+, Fetotal, SO 4 2 , As, and Pb are the most important factors in controlling spatial differences in water quality in this tunnel. But different results have been encountered for different independent variables which might be due to dissimilar sources of water. From the qualitative analysis, it is clear that water quality is not very favorable for aquatic creatures as well as for drinking purposes. The water can be used for irrigation purposes without any doubt as SAR and RSC analysis provides good results. Moreover, the results of this research confirmed that the application of multivariate statistical analysis methods is apposite to inferring complex water quality data sets with its possible pollution sources. At the end, this research recommends (1) as water becomes more and more important, water treatment plants should be built before the water being used; (2) a detailed water step utilization plan should be set beforehand to guarantee tunnel water being used effectively; and (3) after the water being used for agriculture, elements in crops should be monitored continuously to ensure that ions and compounds that come from the tunnel water are lower than guideline values for human beings health. 相似文献
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Spatial variability of soil erodibility and its correlation with soil properties in semi-arid mountainous watershed,Saudi Arabia 总被引:2,自引:0,他引:2
Soil erodibility values are best estimated from long-term direct measurements on runoff-plots; however, in lack of field tests, these values can be estimated using relationships based on physico-chemical soil properties. The study objective was to assess the erodibility and its correlation with soil properties. The average erodibility value was estimated 0.043 t ha h ha?1 MJ?1 mm?1. The areas with heavy textured soil and low organic matter content had the lowest values of erodibility. The erodibility decreases as the sand content increases, whereas silt showed a positive correlation. The erodibility factors and its relation to soil properties were evaluated using multiple regression analysis. Results revealed that sand and organic matter content of soil combinedly explained 78% of variation. Altitudinal increases also seem to affect the soil texture. This study has demonstrated that soil properties and erodibility values can be used as assistance for soil conservation practices and modelling of landscape processes. 相似文献
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Abstract Modelling and prediction of hydrological processes (e.g. rainfall–runoff) can be influenced by discontinuities in observed data, and one particular case may arise when the time scale (i.e. resolution) is coarse (e.g. monthly). This study investigates the application of catastrophe theory to examine its suitability to identify possible discontinuities in the rainfall–runoff process. A stochastic cusp catastrophe model is used to study possible discontinuities in the monthly rainfall–runoff process at the Aji River basin in Azerbaijan, Iran. Monthly-averaged rainfall and flow data observed over a period of 20 years (1981–2000) are analysed using the Cuspfit program. In this model, rainfall serves as a control variable and runoff as a behavioural variable. The performance of this model is evaluated using four measures: correlation coefficient, log-likelihood, Akaike information criterion (AIC) and Bayesian information criterion (BIC). The results indicate the presence of discontinuities in the rainfall–runoff process, with a significant sudden jump in flow (cusp signal) when rainfall reaches a threshold value. The performance of the model is also found to be better than that of linear and logistic models. The present results, though preliminary, are promising in the sense that catastrophe theory can play a possible role in the study of hydrological systems and processes, especially when the data are noisy. Citation Ghorbani, M. A., Khatibi, R., Sivakumar, B. & Cobb, L. (2010) Study of discontinuities in hydrological data using catastrophe theory. Hydrol. Sci. J. 55(7), 1137–1151. 相似文献
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Natural Hazards - An understanding on different aspects of droughts is crucial for effective water resources management. Australia has experienced notable droughts in recent years. The present... 相似文献
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Natural Hazards - This study investigates rainfall and drought characteristics in southeastern Australia (New South Wales and Victoria) using data from 45 rainfall stations. Four homogeneity tests... 相似文献