GGR Critical Review of Analytical Developments in 2003

The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).     

Class distribution and locality in rural areas: an example from Gloucestershire

The analysis of rural social change has reached a point of somewhat saturated orthodoxy. Numerous studies over the last 20 years have served to reinforce a standard view that it is the ‘newcomer vs local’ conflict which lies at the heart of social and cultural changes in rural communities. Moreover, these broad categorisations have often been translated into class terms without due regard for the detailed circumstances of locality or intra-class fractions. This paper presents some evidence from an intensive study of 10 parishes in rural Gloucestershire, and seeks to provide a detailed background to the distribution of selected indicators of social change in that area. It focuses on the diversions and needs experienced by different social groups and suggests additional complexities to those recognised in traditional treatments of rural conflict.     

Scalar Fluxes Near a Tall Building in an Aligned Array of Rectangular Buildings

Scalar dispersion from ground-level sources in arrays of buildings is investigated using wind-tunnel measurements and large-eddy simulation (LES). An array of uniform-height buildings of equal dimensions and an array with an additional single tall building (wind tunnel) or a periodically repeated tall building (LES) are considered. The buildings in the array are aligned and form long streets. The sensitivity of the dispersion pattern to small changes in wind direction is demonstrated. Vertical scalar fluxes are decomposed into the advective and turbulent parts and the influences of wind direction and of the presence of the tall building on the scalar flux components are evaluated. In the uniform-height array turbulent scalar fluxes are dominant, whereas the tall building produces an increase of the magnitude of advective scalar fluxes that yields the largest component. The presence of the tall building causes either an increase or a decrease to the total vertical scalar flux depending on the position of the source with respect to the tall building. The results of the simulations can be used to develop parametrizations for street-canyon dispersion models and enhance their capabilities in areas with tall buildings.     

Atmospheric effects from post-nuclear fires

During a large nuclear war, the atmosphere would be loaded with huge quantities of pollutants, which are produced by fires in urban and industrial centers, cultivated lands, forests and grasslands. Especially detrimental are the effects of light absorbing airborne particles. An analysis of the amounts of the various types of fuels which could burn in a nuclear war indicates that more than 10¹⁴ g of black smoke could be produced by fires started by the nuclear explosions. Due to this, the penetration of sunlight to the earth's surface would be reduced greatly over extended areas of the northern hemisphere, maybe even globally. This could temporarily cause extreme darkness in large areas in midlatitudes and reduce crop growth and biospheric productivity.This situation would last for several weeks and cause very anomalous meteorological conditions. Much solar radiation would be absorbed in the atmosphere instead of at the earth's surface. The land areas and lower atmosphere would, therefore, cool and the overlying atmosphere warm, creating strong vertical thermal stability in a highly polluted atmosphere. For extended periods and in large parts of the world, weather conditions would be abnormal. The resulting cold, probably freezing, temperatures at the ground would interfere severely with crop production during the growing season and cause extreme conditions for large sections of the biosphere. The combination of lack of sunlight, frost and other adverse meteorological conditions would add enormously to the already huge problems of the survivors.     

Rates of erosion and landscape change along the Blue Ridge escarpment,southern Appalachian Mountains,estimated from in situ cosmogenic 10Be

The Blue Ridge escarpment, located within the southern Appalachian Mountains of Virginia and North Carolina, forms a distinct, steep boundary between the lower‐elevation Piedmont and higher‐elevation Blue Ridge physiographic provinces. To understand better the rate at which this landform and the adjacent landscape are changing, we measured cosmogenic beryllium‐10 (¹⁰Be) in quartz separated from sediment samples (n = 50) collected in 32 streams and from three exposed bedrock outcrops along four transects normal to the escarpment, allowing us to calculate erosion rates integrated over 10⁴–10⁵ years. These basin‐averaged erosion rates (5.4–49 m Myr^?1) are consistent with those measured elsewhere in the southern Appalachain Mountains and show a positive relationship between erosion rate and average basin slope. Erosion rates show no relationship with basin size or relative position of the Brevard fault zone, a fundamental structural element of the region. The cosmogenic isotopic data, when considered along with the distribution of average basin slopes in each physiographic province, suggest that the escarpment is eroding on average more rapidly than the Blue Ridge uplands, which are eroding more rapidly than the Piedmont lowlands. This difference in erosion rates by geomorphic setting suggests that the elevation difference between the uplands and lowlands adjacent to the escarpment is being reduced but at extremely slow rates. Copyright © 2016 John Wiley & Sons, Ltd.     

Climate change and coastal flooding in Metro Boston: impacts and adaptation strategies

Sea level rise (SLR) due to climate change will increase storm surge height along the 825 km long coastline of Metro Boston, USA. Land at risk consists of urban waterfront with piers and armoring, residential areas with and without seawalls and revetments, and undeveloped land with either rock coasts or gently sloping beachfront and low-lying coastal marshes. Risk-based analysis shows that the cumulative 100 year economic impacts on developed areas from increased storm surge flooding depend heavily upon the adaptation response, location, and estimated sea level rise. Generally it is found that it is advantageous to use expensive structural protection in areas that are highly developed and less structural approaches such as floodproofing and limiting or removing development in less developed or environmentally sensitive areas.     

Estimates of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning

In order to estimate the production of charcoal and the atmospheric emissions of trace gases volatilized by burning we have estimated the global amounts of biomass which are affected by fires. We have roughly calculated annual gross burning rates ranging between about 5 Pg and 9 Pg (1 Pg = 10¹⁵ g) of dry matter (2–4 Pg C). In comparison, about 9–17 Pg of above-ground dry matter (4–8 Pg C) is exposed to fires, indicating a worldwide average burning efficiency of about 50%. The production of dead below-ground dry matter varies between 6–9 Pg per year. We have tentatively indicated the possibility of a large production of elemental carbon (0.5–1.7 Pg C/yr) due to the incomplete combustion of biomass to charcoal. This provides a sink for atmospheric CO₂, which would have been particularly important during the past centuries. From meager statistical information and often ill-documented statements in the literature, it is extremely difficult to calculate the net carbon release rates to the atmosphere from the biomass changes which take place, especially in the tropics. All together, we calculate an overall effect lof the biosphere on the atmospheric carbon dioxide budget which may range between the possibilities of a net uptake or a net release of about 2 Pg C/yr. The release of CO₂ to the atmosphere by deforestation projects may well be balanced by reforestation and by the production of charcoal. Better information is needed, however, to make these estimates more reliable.Now at the Max-Planck-Institute for Chemistry, Mainz, FRG.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.