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991.
Single-crystal and powder electron paramagnetic resonance (EPR) spectroscopic studies of natural amethyst quartz, before and
after isochronal annealing between 573 and 1,173 K, have been made from 90 to 294 K. Single-crystal EPR spectra confirm the
presence of two substitutional Fe3+ centers. Powder EPR spectra are characterized by two broad resonance signals at g = ~10.8 and 4.0 and a sharp signal at g = 2.002. The sharp signal is readily attributed to the well-established oxygen vacancy electron center E
1′. However, the two broad signals do not correspond to any known Fe3+ centers in the quartz lattice, but are most likely attributable to Fe3+ clusters on surfaces. The absolute numbers of spins of the Fe3+ species at g = ~10.8 have been calculated from powder EPR spectra measured at temperatures from 90 to 294 K. These results have been used
to extract thermodynamic potentials, including Gibbs energy of activation ΔG, activation energy E
a, entropy of activation ΔS and enthalpy of activation ΔH for the Fe3+ species in amethyst. In addition, magnetic susceptibilities (χ) have been calculated from EPR data at different temperatures. A linear relationship between magnetic susceptibility and
temperature is consistent with the Curie–Weiss law. Knowledge about the stability and properties of Fe3+ species on the surfaces of quartz is important to better understanding of the reactivity, bioavailability and heath effects
of iron in silica particles. 相似文献
992.
The representation of the surface of a rock fracture and a numerical method to simulate fluid flow in single fractures are the keys to understanding the hydraulic behaviour of rock fractures. In this paper, a cellular automaton (CA) approach is used to generate the single fracture structure, which is assumed to be composed of contacts and voids. We develop a CA evolution rule to produce a contact area, and randomly model a single rock fracture with different contact ratios to reflect natural fracture properties such as dead voids, islands and tortuous flow path. Then, based on the localisation theory of a CA, a numerical method to simulate fluid flow in single fractures with contacts is developed. In this method, the fracture is discretised into a system composed of cell elements. Different apertures, i.e., zero for contacts and non-zero for voids, are assigned to each cell element. Therefore, the contribution of the cell elements in a contact on a cell’s transmissivity can be ignored completely. The local transmissivity is assumed to conform to the cubic law. The fluid flow in a fracture with different contact situations is then modelled using the method established in this paper. The fluid flow path, flow velocity and fluid head distributions as well as the channel flow in the fracture are well-modelled. The flow behaviour of the fracture strongly depends on the effective fluid flow path. 相似文献
993.
994.
湖北江陵凹陷深层高温富钾卤水特征及其成因探讨 总被引:4,自引:0,他引:4
江汉盆地江陵凹陷深处赋存高温富钾卤水,含卤地层主要是古新统沙市组。富钾卤水的分布受持续的继承性沉降中心(洼陷)、沙市组含盐系、石盐-硫酸盐沉积相的控制,聚集在砂岩、玄武岩、辉绿岩和白云岩等孔隙-裂隙内,裂隙的发育又与局部构造(背斜、盐构造等)枢纽部共轭裂隙带有关。古新世,盐湖已经蒸发浓缩到钙芒硝-石盐阶段,可能短暂达到硫酸镁盐和硫酸钾镁盐阶段。以后,原生的晶间卤水在成岩后期受到玄武岩侵入和高温流体影响,发生变质作用、去镁和去硫酸根作用,同时带入丰富的钾、铷、铯等元素,最后形成了高温富钾卤水。这种成矿过程可称为地下热事件激发成矿机制,值得进一步探讨。 相似文献
995.
996.
To understand the electrical structure of the Sulu(苏鲁) terrane,we analyzed the resis-tivity logs of the Chinese Continental Scientific Drilling main hole(CCSD-MH) and obtained the statis-tical characteristics of the resistivity log of ultrahigh-pressure(UHP) metamorphic rocks.To check the logs' quality,we compared the resistivity log data with the core test data.The two datasets show a good coherence.On the whole,the resistivity of the UHP metamorphic rocks from the CCSD-MH is very high(mostly higher than 1... 相似文献
997.
Many tropical cnidarians, including anemones and corals, contain symbiotic dinoflagellates known as zooxanthellae. Photosynthesis by symbiotic dinoflagellates benefits the animal host and the proficiency of host metabolism also plays an important role in the nutrient status of the photosynthetic dinoflagellates. We aimed to determine the responses of symbiotic dinoflagellates to host starvation. The ultrastructure and some physiological indicators of symbiotic dinoflagellates (Symbiodinium sp., zooxanthellae) were examined in starved sea anemones (Stichodactyla mertensii; 3‐, 45‐ and 280‐day starvation). The cell size of zooxanthellae was not affected by starving the host; however, the ultrastructure and other physiological indicators of the zooxanthellae were affected. The photochemical efficiency of symbiotic dinoflagellates from anemones after 280 days of starvation was significantly (P < 0.01) higher than that of symbiotic dinoflagellates from anemones after 3‐ and 45‐day starvation. The number of symbiotic dinoflagellates from anemones decreased with increasing starvation duration. Generally, the chlorophyll a and c content of symbiotic dinoflagellates decreased significantly with longer anemone starvation. The tentacles of 3‐day starved anemones contained the most zooxanthellae, some of which were dividing and still enclosed within one periplast, and some had split entirely within one host vacuole. Moreover, each cell from 3‐day starved anemone contained up to five or six more mitochondria than those from 45‐ to 280‐day starved anemones. More lipid granules appeared in the zooxanthellae from 45‐ to 280‐day starved anemones. Pyrenoids, lobed accumulation bodies and calcium oxalate crystals existed in the symbiotic dinoflagellates from anemones at different starvation stages, which suggested that their existence had no correlation with host starvation. These findings contribute to an improved mechanistic understanding of the symbiotic relationship between zooxanthellae and anemones. 相似文献
998.
A gene(NANOC-D6D) encoding a desaturase that removes two hydrogen atoms from fatty acids at delta 6 position was isolated from a cDNA library of Nannochloropsis oculata(Droop) D.J.Hibberd(Eustigmatophyceae).The unicellular marine microalga N.oculata synthesizes rich long chain polyunsaturated fatty acids(LCPUFAs),including eicosapentaenoic acid(20:5n-3,EPA).The deduced protein contains 474 amino acids that fold into 4 trans-membrane domains.The neighbor-joining phylogenetic tree indicates that NANOC-D6D is ... 相似文献
999.
充电开关组件是发射机回扫充电电路关键组件,通过充电变压器完成对人工线的充电,它直接决定了人工线高压的稳定性和准确性,是影响发射机输出功率大小和稳定的关键因素之一。根据改进后开关组件线路图,总结出充电开关组件主通道、充电控制信号、故障监控信号流程和与此相关的故障树图。在此基础上,依据实际测试的发射机充电开关组件关键点波形或电平,研究出规范化的充电开关组件芯片级故障诊断流程,列举了依据充电开关组件芯片级故障诊断流程,解决了充电开关组件主通道充电赋能驱动电路芯片损坏导致无充电脉冲信号,引起无人工线高压和发射机输出功率故障,以及修复充电控制电路的充电电流传感器故障导致人工线电压过高,发射机束流报警。充电开关组件故障维修效果表明:充电开关组件芯片级故障诊断流程可以快速定位充电开关组件故障点到芯片,方法简洁,操作规范,雷达技术保障人员容易掌握,能满足国家级、省级雷达测试维修平台和雷达站器件(芯片)级维修需求,为发射机人工智能故障诊断提供借鉴,可有效缩短雷达故障维修时间,提高雷达业务运行可用性指标。 相似文献
1000.