鲁西隆起区晚中生代地层碎屑石榴石分析及物源区构造演化示踪

以鲁西淄博、临朐、平邑、蒙阴盆地为重点研究区,通过盆地中生界砂岩中碎屑石榴石的成分分析,探讨鲁西隆起及周边地区中生代构造演化历史。研究表明,鲁西盆地砂岩中石榴石成分在早中侏罗世和中晚侏罗世期间出现变化,暗示着物源的转变,早中侏罗世时期主要物源是鲁西隆起,中晚侏罗世时期转变为胶东地区和鲁西隆起。侏罗纪时期石榴石的物源转变显示,苏鲁苏鲁造山带可能在中晚侏罗世时期已经抬升至地表。白垩纪鲁西盆地物源主要为胶东地区,鲁西隆起的物源贡献较小,但是青山组中段和王氏组中段物源略有波动。白垩纪鲁西盆地石榴石物源显示,控制鲁西盆地沉积的主要是苏鲁造山带,古地理格架显示东高西低的特征,盆地物源的波动暗示鲁西隆起可能在早白垩世中晚期和晚白垩世中期经历过抬升。     

四川里伍黑牛洞矿床中石榴石的Sm-Nd同位素年龄及其意义

黑牛洞矿床中的石榴石有三个期次:早期的石榴石呈顺片理拉长的条带,中期的石榴石呈颗粒碎块发育,硫化物常沿早期和中期的石榴石的裂隙和颗粒边缘填充,晚期石榴石呈完整细粒变晶产出。本文测得晚期石榴石的Sm-Nd年龄为101±26M a(初始143Nd/144Nd=0.511765±0.000025),其可能代表黑牛洞矿床最后一期中高级变质作用的时代,与形成富矿体的脆韧性变形作用同期。     

Study on the purification property of pyrite and its spectra on the processing of metal-bearing wastewater

The purification property of pyrite was discussed by using in situ attenuated total reflection-Fourier transform infrared spectroscopy. Results showed that there might be dissolution–adsorption precipitation equilibrium of heavy metals on the surface of pyrite, which is dependent on the surface oxidation of pyrite and the neutralization reaction of carbonate within pyrite. If there was excessive carbonate within pyrite, the “dissolution” of metals would be less than that of the “adsorption precipitation,” making pyrite exhibit its purification property. Based on this property, pyrite was used to process simulated wastewater containing Pb²⁺, Hg²⁺, Cd²⁺, Cr(VI) and Cu²⁺. Results showed that the efficiencies of metal removal exceeded 96%. In addition, reflectance spectroscopy and absorption spectroscopy were also utilized to investigate the simulated metal-bearing wastewater treatment process. Analysis by diffused reflectance infrared Fourier transform spectroscopy confirmed that the superficial hydroxyl groups in pyrite reacted with metal ions during the wastewater treatment process. Reflectance spectroscopy in the visible region was used to characterize the variation in particle size and specific surface area of pyrite during the wastewater treatment process, which explained its increasing activity when reutilized. Further, analysis by absorption spectroscopy and X-ray photoelectron spectroscopy indicated that the process involved when using pyrite for the treatment of Cr(VI)-containing wastewater was an adsorption–precipitation process.