The groundwater recharge regime of some slightly metamorphosed neoproterozoic sedimentary rocks: an application of natural environmental tracers

Isotope data of precipitation and groundwater in parts of the Voltaian Basin in Northern Ghana were used to explain the groundwater recharge regime in the area. Groundwater recharge is an important parameter in the development of a decision support system for the management and efficient utilization of groundwater resources in the area. It is therefore important to establish the processes and sources of groundwater recharge. δ¹⁸O and δ²H data for local precipitation suggest enrichment relative to the Global Meteoric Water Line (GMWL) and indicate that precipitation takes place at a relative humidity less than 100%. The groundwater data plot on an evaporation line with a slope of 5, suggesting a high degree of evaporative enrichment of the precipitation in the process of vertical infiltration and percolation through the unsaturated zone into the saturated zone. This finding is consistent with the observation of high evapotranspiration rates in the area and ties in with the fact that significant clay fraction in the unsaturated zone limits vertical percolation and thus exposes the percolating rainwater to the effects of high temperatures and low humidities resulting in high evapotranspiration rates. Groundwater recharge estimates from the chloride mass balance, CMB, method suggest recharge in the range of 1.8–32% of the annual average precipitation in the form of rainfall. The highest rates are associated with areas where open wells encourage significant amount of groundwater recharge from precipitation in the area. In the northern parts of the study area, groundwater recharge is lower than 12%. The recharge so computed through the application of the CMB methodology takes on a spatial distribution akin to the converse of the spatial pattern of both δ¹⁸O and δ²H in the area. As such, the locations of the highest recharge are associated with the most depleted values of the two isotopes. This observation is consistent with the assertion that low vertical hydraulic conductivities slow down vertical percolation of precipitation down to the groundwater water. The percolating precipitation water thus gets enriched in the heavier isotopes through high evapotranspiration rates. At the same time, the amount of water that finally reaches the water table is considerably reduced. Copyright © 2013 John Wiley & Sons, Ltd.     

Microbially influenced formation of Mg‐calcite and Ca‐dolomite in the presence of exopolymeric substances produced by sulphate‐reducing bacteria

Some species of sulphate‐reducing bacteria (SRB) are known to mediate the formation of dolomite and Mg‐calcite. However, their exact role in the mineralization process remains elusive. Here, we present the result of a laboratory experiment that was designed to test whether formation of carbonate minerals by SRB can occur in the absence of living cells, through passive mineralization of their exopolymeric substances (EPS). SRB capable of mediating dolomite were cultivated in the laboratory, allowing them to secrete EPS. Microbial activity within the cultures was subsequently inhibited with antibiotics. Only after this step, Ca²⁺ and Mg²⁺ were added to the solution and carbonate minerals could form. Mg‐calcite and disordered Ca‐dolomite precipitated in association with EPS. The mol.% of Mg²⁺ in the crystals increased with longer incubation times. This result demonstrates that organic compounds produced by SRB can mediate the formation of Ca‐Mg carbonates in the absence of an active metabolism.     

Stately home geology: Kelmscott Manor,Oxfordshire, UK

Kelmscott Manor on the banks of the Upper Thames in Oxfordshire is a place of pilgrimage for social historians and conversationalists as well as those who simply want to turn the clock back to a rural England long departed. The manor was leased to William Morris in 1871 to be his family home until long after his death in 1896—their escape from the hectic daily life in London. At that point, Morris spent the previous 10 years building up the crafts business for which he is best known, the patterned textiles and wallpaper designs and the basic wooden furniture we associate with the Arts and Crafts Movement. It can be difficult to remember that much of the respected craftwork was generated in the East End of London by gifted craftsmen.     

Oblique oceanic opening and passive margin irregularity,as inherited in the Zagros fold‐and‐thrust belt

The Zagros fold‐and‐thrust belt of SW Iran represents deformation of the former Arabian passive margin since Permian–Triassic opening of the Neo‐Tethys ocean. The Zagros belt is characterized by a present‐day structural salient‐recess setting inherited from past marginal embayment‐promontory geometry, which was involved in discontinuous ophiolite obduction and diachronous continental collision. We examine outcrop‐scale Mesozoic extensional brittle tectonics, preserved as syn‐depositional normal faults within the folded strata, in terms of stress tensor inversion. The result is then integrated with belt‐scale isopach, seismic and topographical data to delineate the geometry of a major irregularity along the passive margin originating from oblique oceanic opening. The implication of this configuration within the tectonic framework of oceanic closure is discussed.     

Erodibility of low‐compaction steep‐sloped reclaimed surface mine lands in the southern Appalachian region,USA

The use of loose spoils on steep slopes for surface coal mining reclamation sites has been promoted by the US Department of Interior, Office of Surface Mining for the establishment of native forest, as prescribed by the Forest Reclamation Approach (FRA). Although low‐compaction spoils improve tree survival and growth, erodibility on steep slopes was suspected to increase. This study quantified a combined K_C factor (combining the effects of the soil erodibility K factor and cover management C) for low compaction, steep‐sloped (>20°) reclaimed mine lands in the Appalachian region, USA. The combined K_C factor was used because standard Unit Plot conditions required to separate these factors, per Revised Universal Soil Loss Equation (RUSLE) experimental protocols, were not followed explicitly. Three active coal mining sites in the Appalachian region of East Tennessee, each containing four replicate field plots, were monitored for rainfall and sediment yields during a 14‐month period beginning June 2009. Average cumulative erosivity for the study sites during the monitoring period was measured as 5248.9 MJ·mm·ha^?1·h^?1. The K_C ranged between 0.001 and 0.05 t·ha·h·ha^?1·MJ^?1·mm^?1, with the highest values occurring immediately following reclamation site construction as rills developed (June – August 2009). The K_C for two study sites with about an 18–20 mm spoil D₈₄ were above 0.01 t·ha·h·ha^?1·MJ^?1·mm^?1 during rill development, and below 0.003 t·ha·h·ha^?1·MJ^?1·mm^?1 after August 2009 for the post‐rill development period. The K_C values for one site with a 40 mm spoil D₈₄ were never above 0.008 t·ha·h·ha^?1·MJ^?1·mm^?1 and also on average were lower, being more similar to the other two sites after the rill development period. Based on an initial K_C factor (K_e) measured during the first few storm events, the average C factor (C_e) was estimated as 0.58 for the rill development period and 0.13 for the post‐rill development period. It appears that larger size fractions of spoils influence K_C and C_e factors on low‐compaction steep slopes reclamation sites. Copyright © 2013 John Wiley & Sons, Ltd.     

The Late Cretaceous Klepa basalts in Macedonia (FYROM)—Constraints on the final stage of Tethys closure in the Balkans

The waning stage(s) of the Tethyan ocean(s) in the Balkans are not well understood. Controversy centres on the origin and life‐span of the Cretaceous Sava Zone, which is allegedly a remnant of the last oceanic domain in the Balkan Peninsula, defining the youngest suture between Eurasia‐ and Adria‐derived plates. In order to investigate to what extent Late‐Cretaceous volcanism within the Sava Zone is consistent with this model we present new age data together with trace‐element and Sr–Nd–Pb isotope data for the Klepa basaltic lavas from the central Balkan Peninsula. Our new geochemical data show marked differences between the Cretaceous Klepa basalts (Sava Zone) and the rocks of other volcanic sequences from the Jurassic ophiolites of the Balkans. The Klepa basalts mostly have Sr–Nd–Pb isotopic and trace‐element signatures that resemble enriched within‐plate basalts substantially different from Jurassic ophiolite basalts with MORB, BAB and IAV affinities. Trace‐element modelling of the Klepa rocks indicates 2%–20% polybaric melting of a relatively homogeneously metasomatised mantle source that ranges in composition from garnet lherzolite to ilmenite+apatite bearing spinel–amphibole lherzolite. Thus, the residual mineralogy is characteristic of a continental rather than oceanic lithospheric mantle source, suggesting an intracontinental within‐plate origin for the Klepa basalts. Two alternative geodynamic models are internally consistent with our new findings: (1) if the Sava Zone represents remnants of the youngest Neotethyan Ocean, magmatism along this zone would be situated within the forearc region and triggered by ridge subduction; (2) if the Sava Zone delimits a diffuse tectonic boundary between Adria and Europe which had already collided in the Late Jurassic, the Klepa basalts together with a number of other magmatic centres represent volcanism related to transtensional tectonics.     

Estimating Pile Set-up Using 24-h Restrike Resistance and Computed Static Capacity for PPC Piles Driven in Soft Lousiana Coastal Deposits

In this paper, the CPT-based predicted ultimate pile resistances (R_p) were compared with the measured pile resistances (R_m) at different elapsed time for the piles driven into saturated soft clays where piles displayed significant set-up effect. The measured pile resistances were based on 115 restrike records collected from 95 production piles, and 74 records of 9 tested piles. The predicted ultimate pile resistances were calculated from the LCPC, the Schmertmann, and the de Ruiter–Beringen methods, respectively. With the significant pile set-up effect taken into account, the relationship between measured resistances and predicted capacities at different times after pile installation were investigated. The ratios of the measured pile resistances to the predicted capacities scattered in a large spectrum. The ratios fluctuated and stayed within a range of 0.6–1.6 for different CPT methods since end of initial driving until more than 2 months after pile installation. Plots of the ratios versus the predicted pile capacities using different CPT methods have revealed that the ratio (R_m/R_p) presented a strong dependence on the predicted capacities. Great research efforts have been devoted to the analyses of the ratios of the 24-h measured resistance to the predicted capacity based on different CPT methods, in an attempt to find a feasible empirical correlation. It is found that a simple linear relationship exists between the quad root of the ratio and the predicted capacity. The developed empirical equations will give pile foundation engineers an insight into the ultimate resistances of driven piles demonstrating significant pile set-up effects. Pile set-up makes pile resistances grow with time, and it might be one of the reasons that cause the frequently reported large discrepancy between calculated static capacity and measured resistance at a certain time after pile installation.