Persistence of road runoff generation in a logged catchment in Peninsular Malaysia

Measurements of saturated hydraulic conductivity (K_s) and diagnostic model simulations show that all types of logging road/trail in the 14·4 ha Bukit Tarek Experimental Catchment 3 (BTEC3) generate substantial Horton overland flow (HOF) during most storms, regardless of design and level of trafficking. Near‐surface K_s(0–0·05 m) on the main logging road, skid trails and newly constructed logging terraces was less than 1, 2 and 34 mm h^?1, respectively. Near‐surface K_s on an abandoned skid trail in an adjacent basin was higher (62 mm h^?1), owing to the development of a thin organic‐rich layer on the running surface over the past 40 years. Saturated hydraulic conductivity measured at 0·25 m below the surface of all roads was not different (all <6 mm h^?1) and corresponded to the K_s of the adjacent hillslope subsoil, as most roads were excavated into the regolith more than 0·5–1 m. After 40 years, only limited recovery in near‐surface K_s occurred on the abandoned skid trail. This road generated HOF after the storage capacity of the upper near‐surface layer was exceeded during events larger than about 20 mm. Thus, excavation into low‐K_s substrate had a greater influence on the persistence of surface runoff production than did surface compaction by machinery during construction and subsequent use during logging operations. Overland flow on BTEC3 roads was also augmented by the interception of shallow subsurface flow traveling along the soil–saprolite/bedrock interface and return flow emerging from the cutbank through shallow biogenic pipes. The most feasible strategy for reducing long‐term road‐related impacts in BTEC3 is limiting the depth of excavation and designing a more efficient road network, including minimizing the length and connectivity of roads and skid trails. Copyright © 2007 John Wiley & Sons, Ltd.     

Precipitation pattern modeling using cross-station perception: regional investigation

Establishing robust models for predicting precipitation processes can yield a significant aspect for many applications in water resource engineering and environmental prospective. In particular, understanding precipitation phenomena is crucial for managing the effects of flooding in watersheds. In this research, a regional precipitation pattern modeling was undertaken using three intelligent predictive models incorporating artificial neural network (ANN), support vector machine (SVM) and random forest (RF) methods. The modeling was carried out using monthly time scale precipitation information in a semi-arid environment located in Iraq. Twenty weather stations covering the entire region were used to construct the predictive models. At the initial stage, the region was divided into three climatic districts based on documented research. Initially, modeling was carried out for each district using historical information from regionally distributed meteorological stations for calibration. Subsequently, cross-station modeling was undertaken for each district using precipitation data from other districts. The study demonstrated that cross-station modeling was an effective means of predicting the spatial distribution of precipitation in watersheds with limited meteorological data.     

Sicilian serpentinite xenoliths containing abiotic organics with nanodiamond clusters as key model for prebiotic processes

Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Ocean entered as xenoliths in a Miocenic diatreme,hence brought to the surface,in the Hyblean Plateau(Sicily).Some xenoliths consist of strongly serpentinized ultramafic rocks bearing blebs of abiotic organic matter,where clusters of amorphous carbon nanoparticles,including nanodiamonds,are immersed.Such an occurrence conjures up established hypotheses that diamond surfaces are suitable catalytic platforms stimulating the assemblage of complex bio-organic molecules relevant to the emergence of life on Earth.The appearance of bio-organic molecules under primitive Earth conditions is one of the major unsolved questions on the origin of life.Here we report new micro-Raman spectra on blebs of abiotic organic matter from a selected xenolith.Diamond bands were related to hydrogenated nanocrystalline diamonds,with size of nearly 1-1.6 nm,formed from organics at low pressures and temperatures.In particular,diamond surfaces can give rise to crystalline interfacial water layers that may have played a fundamental role in the early biosphere evolution as a good medium for rapidly transporting positive charges in the form of hydrated protons.Nowadays,proton gradients in alkaline hydrothermal vents along oceanic ridges are generally viewed as key pre-biotic factors.In general,serpentinites span the entire geological record,including prebiotic times.These hydrous ultramafic rocks often display evidence of abiotic carbon species,both organic and inorganic,including nanodiamonds,being also capable to give rise to chemiosmotic processes and proton gradients necessary to the organisms,such as the"Last Universal Common Ancestor"(LUCA),in the prebiotic Earth.     

Recombinant workfare, across the Americas: Transnationalizing “fast” social policy

The paper presents a genealogy of the Bloomberg administration’s Opportunity NYC program, launched in 2007 as part of New York City’s explicitly experimental anti-poverty strategy. Opportunity NYC was modeled on “conditional cash transfer” programs, currently operating in more than thirty countries across the Global South, drawing direct inspiration from Mexico’s widely touted Oportunidades program. This striking case of South-North policy emulation calls attention to some distinctive features of what is characterized here as a transnationalizing “fast-policy” regime, based on technocratic forms of program evaluation and development, dense expert networks, and orchestrated communities of practice, within which a range of policy intermediaries—particularly those connected with multilateral agencies—are assuming significant new roles. What appears to be a pragmatic form of policy learning in fact operates in the context of narrow ideological parameters, within which there is a concerted technocratic “push” toward favored solutions.     

Particle tracking analysis of river–aquifer interaction via bank infiltration techniques

Induced bank infiltration (BI) is commonly implemented in other countries, but remains new and unexplored in Malaysia. Increasing river pollution could affect drinking water resources. Given the threat of pollution to raw water sources, applying induced BI to sustain water management is essential. This paper presents a case study of the BI method, which evaluates the effects of groundwater pumping and BI operation on the installation of wells as well as determines the effect of pumping rate on flow paths, travel time, the size of the pumping and capture zone delineation, and groundwater mixing in a pumping well in Jenderam Hilir, Malaysia. The proposed method performs infiltration safely and achieves the ideal pumping rate. Numerical modeling packages, MODFLOW and MODPATH (particle tracking) were used. Results indicate that the migration of river water into the aquifer is generally slow and depends on the pumping rate and distance from well to the river. Most water arrives at the well by the end of a pumping period of 1–5 days at 3,072 m³/day for test wells DW1 and DW2, and during simultaneous pumping for DW2 and PW1 for a well located 36 and 18 m, respectively, from the river. During the 9.7-day pumping period, 33 % of the water pumped from the DW1 well was river water, and 38 % from DW2 throughout 4.6 days was river water. The models provide necessary information for water operators in the design and construction of pumping and sampling schedules of BI practices.     

United Arab Emirates limestones: impact of petrography on thermal behavior

The thermal behavior of selected limestones from representative localities of the United Arab Emirates is investigated for their suitability for soft-burnt lime production. The limestone samples were collected from the Ghalilah, Musandam, Shauiba, Muthaymimah, Dammam and Asmari formations. The samples were characterized for petrography, mineral and chemical composition, together with physico-mechanical characteristics. Investigative methods included transmitted light microscopy (TLM), cathodoluminescence (CLM) and scanning electron microscopy (SEM), as well as X-ray micro-tomography (μ-CT), XRD, XRF and Archimedes method. The limestone samples were fired in an electrical muffle furnace for 0.25, 0.5, 1 and 2 hours at 800, 900, 1,000 and 1,100 °C. After firing the lime grains were tested to determine their hydration rate and microfabric. The Ghalilah and Musandam limes show the lowest and highest maximum hydration rates, respectively, due mainly to the impure nature of the former, and the smaller lime crystallites and dominance of post-calcination micro-cracks of the latter. The Dammam and Asmari limes preserve a “ghost” microfabric of the original limestone. Higher allochem contents impose lower activation energy requirements for calcination, which implies earlier calcination of the allochems. The Musandam, Shauiba and Muthaymimah limestones may be useful for the production of reactive soft-burnt lime under the applied firing conditions, however, the Dammam and Asmari limestones need more advanced calcination conditions than the applied ones. The Ghalilah limestone was found to be unsuitable for the production of lime.     

Heavy metal contamination in water and sediment of the Port Klang coastal area, Selangor, Malaysia

This investigation presents the temporal and spatial distribution of heavy metals (As, Cd, Cr, Cu, Ni, Pb, Hg, and Zn), in water and in sediments of Port Klang, Malaysia. Water and sediment samples were collected from 21 stations at 3-month intervals, and contamination factor $ (C_{\text{f}} ) $ and contamination degree $ (C_{\text{d}} ) $ were calculated to estimate the contamination status at the sampling stations. Cluster analysis was used to classify the stations based on the contamination sources. Results show that concentrations of As, Cd, Hg, and Pb in sediment and As, Cd, Hg, Pb, Cr, and Zn in water were significantly higher than the background values at which these metals are considered hazardous. The main sources of heavy metal contamination in Port Klang were industrial wastewater and port activities.     

Malaysian fisheries policy : Search for new grounds

Past fisheries development policies in Malaysia are assessed and new grounds for managing the Malaysian fisheries are explored. Some incompatibility in the goals for fishery development are discerned, especially those of increasing domestic landings through mechanization and resource conservation. Future management efforts should be based on a fuller understanding of the fishery stock and regional management of fish stocks. Aquaculture is often seen as a plausible alternative in order to augment supplies from the capture fisheries. A comprehensive multidisciplinary approach is needed to transform and commercialize traditional, experience-dependent culture systems into technology-packaged systems based on scientific methods. There is also substantial potential for the development of recreational fisheries.     

Adsorptive removal of Cu(II) and Pb(II) onto mixed-waste activated carbon: kinetic,thermodynamic, and competitive studies and application to real wastewater samples

This work aimed to investigate the adsorption characteristics, both kinetically and thermodynamically, of Cu(II) and Pb(II) removal from aqueous solutions onto mixed-waste activated carbon, as well as to study the competitive behavior found in mixed heavy metal solution systems. This study shows that activated carbon prepared from mixed waste is an effective adsorbent for the removal of Cu(II) and Pb(II) from aqueous solutions, with the aim of detoxifying industrial effluents before their safe disposal onto water surfaces. The adsorption process was characterized in terms of kinetic and thermodynamic studies. In addition, the influence of presence of Cu(II) and Pb(II) in a competitive system was investigated. The results showed that the maximum adsorption capacities were gained at a pH of 6 with a contact time of 180 min, a metal solution concentration of 300 ppm, and an adsorbent dose of 0.3 g/L. The adsorption process was found to follow a pseudo-first-order kinetic model. Thermodynamic parameters such as ΔG ^o, ΔH ^o, and ΔS ^o showed that the sorption process was spontaneous and endothermic in nature. A competitive study demonstrated the applicability of mixed-waste activated carbon to adsorb Cu(II) and Pb(II) from a solution of mixed metals. In addition, the adsorption capacity was found to be as effective as other adsorbents reported in the literature. The developed adsorptive removal procedure was applied for treatment of real wastewater samples and showed high removal efficiency.