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101.
OH-bearing planar defects in olivine produced by the breakdown of Ti-rich humite minerals from Dabie Shan (China) 总被引:2,自引:0,他引:2
Jörg Hermann John D. Fitz Gerald Nadia Malaspina Andrew J. Berry Marco Scambelluri 《Contributions to Mineralogy and Petrology》2007,153(4):417-428
The partial breakdown of Ti-chondrodite and Ti-clinohumite during exhumation from ultra-high pressure to amphibolite facies
conditions in garnet-pyroxenites from Dabie Shan (China) produces coronas of olivine coexisting with ilmenite blebs. Fourier
transform infrared (FTIR) spectra of this newly formed olivine exhibit absorption bands in the hydroxyl-stretching region.
Two intense peaks were observed at 3,564 and 3,394 cm−1, identical in energy to peaks in Ti-clinohumite. Transmission electron microscopy (TEM) of the same olivine domains revealed
the presence of a complex (001) planar intergrowth. These interlayers have a 1.35 nm repeat distance, which is characteristic
of clinohumite. Such interlayers are also enriched in Ti with respect to the adjacent olivine as shown by energy dispersive
spectrometry. The combined evidence from FTIR spectroscopy and TEM indicates that OH is incorporated along Ti-clinohumite
planar defects. This study provides evidence that the nominally anhydrous phase olivine may contain OH as a humite-type defect
beyond the breakdown of the hydrous humite minerals and confirms earlier suggestions that Ti plays a key role in OH incorporation
in mantle olivine. We suggest that olivine containing Ti-clinohumite defects is an important phase for water transport in
subduction zones and for the storage of water in cold subcontinental mantle. However, these defects are unlikely to be stable
in hotter parts of the oceanic mantle such as where basaltic magmas are generated. 相似文献
102.
Spatial distribution and temporal trends of persistent organochlorine pollutants in sediments from Lake Maryut, Alexandria, Egypt 总被引:2,自引:0,他引:2
Organochlorine compounds (OCs) in surface and core sediments collected from Lake Maryut, Egypt, were examined to elucidate their distribution, ecological risk and historical trend. To our knowledge, this is the first study on residue levels of OCs in sediments from Lake Maryut. Concentrations of PCBs and DDTs were higher than other OCs, ranging from 3.06 to 388 and from 0.07 to 106 ng/g dry wt., respectively. The highest concentrations of OCs were found at stations near the discharge point of sewage and close to industrial areas. The distribution of DDT and its metabolites suggest no recent inputs into the lake environment. Contamination levels of sedimentary PCBs and DDTs, can be categorized moderate to high compared to other urbanized regions worldwide. Temporal trends in OCs levels were influenced by input pathways at two sites. Evaluation of ecotoxicological risks suggests that adverse biological effects are expected mainly in the main basin area. 相似文献