Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.     

Role of the global oceans and land–atmosphere interaction on summertime interdecadal variability over northern Argentina

This study uses experiments with an atmospheric general circulation model (AGCM) to address the role of the oceans and the effect of land–atmosphere coupling on the predictability of summertime rainfall over northern Argentina focusing on interdecadal time scales during 1901–2006. Ensembles of experiments where the AGCM is forced with historical sea surface temperature (SST) in the global, Pacific and tropical-North Atlantic domains are used. The role of land–atmosphere interaction is assessed comparing the output of simulations with active and climatological soil moisture. A maximum covariance analysis between precipitation and SST reveals the impact of the Pacific Decadal Oscillation, the Atlantic Multidecadal Oscillation and the equatorial–tropical South Atlantic on rainfall over northern Argentina. Model simulations further show that while the dominant influence comes from the Pacific basin, the Atlantic influence can explain a large transition from dry to wet decades over northern Argentina during the beginning of the 1970s. Analysis of anomalies before and after the transition reveals an upper level anticyclonic circulation off the Patagonian coast with barotropic structure. This circulation enhances the moisture transport and convergence in northern Argentina and, together with enhanced evaporation, increased the rainfall after 1970. The SST pattern is dominated by cold conditions in the equatorial Atlantic and warm eastern Pacific and South Atlantic. We also found that land–atmosphere interaction leads to a representation of the long term rainfall evolution over northern Argentina that is closer to the observed one. Moreover, it leads to a smaller dispersion among ensemble members, thus resulting in a larger signal-to-noise ratio.     

Waveshapes of continuing currents and properties of M-components in natural positive cloud-to-ground lightning

This work analyses the waveshapes of continuing currents and parameters of M-components in positive cloud-to-ground (CG) flashes through high-speed GPS synchronized videos. The dataset is composed of only long continuing currents (with duration longer than 40 ms) and was selected from more than 800 flashes recorded in São José dos Campos (45.864°W, 23.215°S) and Uruguaiana (29.806°W, 57.005°S) in Southeast and South of Brazil, respectively, during 2003 to 2007 summers. The videos are compared with data obtained by the Brazilian Lightning Location System (BrasilDAT) in order to determine the polarity of each flash and select only positive cases. There are only two studies of waveshapes of continuing currents in the literature. One is based on direct current measurements of triggered lightning, in which four different types of waveshapes were observed; and the other is based on measurements of luminosity variations in high-speed videos of CG negative lightning, in which besides the four types above mentioned two additional types were observed. The present work is an extension of the latter, using the same method but now applied to obtain the waveshapes of positive CG lightning. As far as the authors know, this is the first report on M-components in positive continuing currents. We also have used the luminosity-versus-time graphs to observe their occurrence and measure some parameters (duration, elapsed time and time between two successive M-components), whose statistics are presented and compared in detail to the data for negative flashes. We have plotted a histogram of the M-components elapsed time over the total duration of the continuing current for positive flashes, which presented an exponential decay (correlation coefficient: 0.83), similar to what has been observed for negative flashes.     

Heavy Metal Accumulation in the Lichen Evernia prunastri Transplanted at Urban, Rural and Industrial Sites in Central Italy

The lichen Evernia prunastri has been employed for biomonitoring the atmospheric deposition of heavy metals at urban, rural and industrial sites in Central Italy. Lichen samples have been collected in a control site 1500 m a. s. l. (Parco Nazionale dAbruzzo, Central Italy) and subsequently transplanted at urban site (Cassino city center), at rural location 7 km away from Cassino (S. Elia Fiumerapido) and at industrial location (Piedimonte S. Germano) surrounding an automobile factory. Once defined the surface of impact relevant to this work, the lichen samples were transplanted at the four cardinal points of each site. Studies of bioaccumulation of Pb, Cd, Cr, Cu and Zn in lichen samples were performed five times at regular intervals between November 2000–December 2001. Microwave digestion of the samples and graphite furnace atomic absorption spectrometry were employed for the heavy metal determinations. Suitable certified reference materials (CRM) were used for validation of the analytical methodology. Results showed the ability of Evernia prunastri to accumulate the heavy metals under study. As expected, the area chosen as control site showed significantly (Friedman test, cluster analysis) lower impact in comparison to the other sites and the rural site showed smaller impact than the urban and the industrial sites.     

The Continuum Voronoi Block Model for simulation of fracture process in hard rocks

In this paper, a numerical model is presented to represent the fracture process in hard rocks based on a pseudo-discontinuum method called the Continuum Voronoi Block Model (CVBM). To validate this tool, numerical models for one Brazilian test, one unconfined compression test, and multiple triaxial compression tests with different confining stress were calibrated to match laboratory test results for Creighton granite. The model proved robust and matched the following macro-properties: crack initiation (CI) stress, (CD) stress, peak strength, tensile strength, Young's Modulus, and Poisson's ratio. The calibrated model served as a basis for a sensitivity study to analyze how micro-properties influence the rock's macroscopic responses. From the sensitivity study, a calibration methodology was proposed, which shall facilitate the use of the CVBM in future works.