Coupling among the terrestrial sulfur,carbon and oxygen cycles: numerical modeling based on revised Phanerozoic carbon isotope record

Numerical modeling of the terrestrial oxygen budget based on the revised δ¹³C_carb record by Veizeret al. (1980) has shown that total photosynthetic oxygen has varied between ±7% and ±10% of its average reservoir size (～3.2 × 10²² g) during the last 800 myr as a result of oscillations of the sedimentary reservoir of organic carbon. Calculated curves of oxygen evolution display a distinct minimum in the Early Paleozoic framed by two maxima in the Latest Proterozoic and the Mesozoic. The sympathetic relationship observed between the curves of total oxygen evolution and respective functions for the partial reservoir of sulfate-bound oxygen suggests that the O₂ required for an additional conversion of sulfide to sulfate was most probably provided by excess burial of organic carbon, the results of the modeling thus adding credence to current interpretations proposed for the negative correlation between the secular ${}^{13}\text{C}{}^{12}\text{C}$ and ${}^{34}\text{S}{}^{32}\text{S}$ trends.     

Evidence for the 22-year-cycle in the longitudinal distribution of sunspots

It was shown in an earlier paper that preferred hemispheres of solar activity alternate with the 22-year magnetic cycle, when analyzed in the 27.0 day Bartels rotation. Using data which cover the time between 1818 and 1983 we trace back this result to 1880 (cycle 12). Before 1880 no significant correlations are found.     

Soil frost effects on soil water and runoff dynamics along a boreal transect: 2. Simulations

A physically based SVAT‐model was tested with soil and snow physical measurements, as well as runoff data from an 8600 m² catchment in northern Sweden in order to quantify the influence of soil frost on spring snowmelt runoff in a moderately sloped, boreal forest. The model was run as an array of connected profiles cascading to the brook. For three winter seasons (1995–98) it was able to predict the onset and total accumulation of the runoff with satisfactory accuracy. Surface runoff was identified as only a minor fraction of the total runoff occurring during short periods in connection with ice blocking of the water‐conducting pores. Little surface runoff, though, does not mean that soil frost is unimportant for spring runoff. Simulations without frost routines systematically underestimated the total accumulated runoff. The possibility of major frost effects appearing in response to specific combinations of weather conditions were also tested. Different scenarios of critical initial conditions for the winter, e.g. high water saturation and delayed snow accumulation leading to an increased frost penetration, were tested. These showed that under special circumstances there is potential for increased spring runoff due to soil frost. Copyright © 2001 John Wiley & Sons, Ltd.     

Geochemical and petrological characteristics of Eppawala phosphate deposits,Sri Lanka

The apatite-bearing carbonate rocks at Eppawala, Sri Lanka occur as massive, discontinuous bodies in a Precambrian, high-grade metamorphic terrain, which weather to form economically important phosphate deposits. The ore bodies at Eppawala contain =42% P ₂O ₅, and citric acid solubility of different components varies from 4 to 6%. The parent rocks are mainly made up of calcite, dolomite and apatite, with lesser amounts of ilmenite, magnetite, pyrite, forsterite, phlogopite, enstatite, magnesite, diopside, tremolite and spinel. Most of minerals show an euhedral habit, with a wide range of crystal sizes (from a few millimetres to several decimetres). The Eppawala rocks are characterised by low silica (=0.41%), high phosphorous (=10.58%) and high strontium content (2,960–6,819 ppm). Concentrations of light rare-earth elements in these rocks are comparably higher than those of marbles. The REE fractionation of these rocks is pronounced, and La/Yb ratios vary between 14 and 43. Both apatite and calcite show markedly elevated strontium levels (=0.6%). The d ¹³C _PDB and d ¹⁸O _SMOW values of the carbonates are in the range of –3.4 to –2.2 and 7.7 to 16.4‰ respectively. The euhedral habit, as well as the presence of major quantities of apatite and considerable amounts of iron-bearing minerals suggest that the ore host rock has genetic links to an igneous source rather than to an intensely metamorphosed limestone. The higher light REE contents of the rocks, compared to marbles, also argue against a metamorphic or sedimentary origin. The Sr/Mn and Ce/La ratios in the apatite are ~40 and ~2 respectively, suggesting that they were formed in a carbonatite magma. The markedly increased REE concentrations in the bulk chemistry of the rocks have been shown to be mainly controlled by the content of phosphate minerals. Compared to most carbonatites, the Eppawala rocks are generally depleted in selected trace elements, particularly Ba, Nb, Th, V, U and Zr. This depletion may be due to either a primary infertility of the parent magma with regard to such trace elements, or it is a result of fractional crystallisation during the rock formation. The stable isotope ratios do not plot within the defined "mantle carbonatite box", but still lie within the broader range of carbonatitic rocks. With these data at hand, it can be readily argued that the mode of occurrence, petrography and geochemistry of the Eppawala apatite-bearing carbonates provide conclusive evidence of their carbonatitic origin.     

A proxy record of winter temperatures since 1836 from ice freeze-up/breakup in lake N?sij?rvi, Finland

One obstacle on the way to a comprehensive spatial reconstruction of regional temperature changes over the past centuries is the sparseness of long winter temperature records. This paper reconstructs a proxy record of April and November–December temperatures in south-central Finland for the interval from 1836 to 1872 from breakup and freeze-up dates and ice-cover duration of a lake. Emphasis is on detecting the suitable winter months and quantifying the calibrations with measured temperatures (1873–2002). The calibration slope for the breakup date (0.158°C/day) is larger than for freeze-up date (0.119°C/day) or duration (0.090°C/day). A comparison with results from other proxy records shows that the slope may depend also on the geographical site. Trend analyses of the full temperature records (1836–2002) indicate the existence of minor change-points at around 1867 (April temperature) and 1874 (November–December temperature), with warming rates thereafter of 1.67°C per century (April) and 1.16°C per century (November–December). Spectral analyses reveal peaks in the band between 2 and 5?year period, which may point to influences of the North Atlantic Oscillation, and less power in the decadal band (up to 42?year period).     

Solar protons on closed magnetospheric field lines after an interplanetary flux decrease

Particle measurements from the low altitude polar-orbiting satellite GRS-A/Azur and from Explorer 41 in the magnetosheath during a time period after the sudden commencement at 14:30 UT on 8 March 1970, have been used in order to study the access mode of solar particles into the closed field line region of the magnetosphere. A particle decrease in the magnetosheath and over the central polar cap but not in the stable trapping region indicates that solar particles are temporarily trapped and can complete several drifts around the Earth. A single loss cone distribution ～2° inside of the stable trapping region cannot be explained by strong pitch angle scattering but is probably due to non-adiabatic particle motion.     

Assimilation of Earth rotation parameters into a global ocean model: length of day excitation

Changes in the oceanic current system and in the oceanic mass distribution alter, together with other processes, the state of the Earth’s rotation. This state is characterized by the length of day (LOD) and the tilt of the pole-to-pole axis. The aim of our study was to derive the respective governing physical mechanisms in the ocean. Therefore, Earth rotation observations were assimilated into a global circulation model of the ocean. Although assimilation is a well-established tool in climate science, the assimilation of Earth rotation observations into a global ocean model was done here for the first time. Prior to the assimilation, the Earth rotation observations were projected onto the angular momentum of the ocean. Non-oceanic contributions were removed. The result of the subsequent assimilation procedure is a time varying ocean model state that reproduces the projected Earth rotation observations well. This solution was studied to understand the oceanic generation of Earth rotation deviations and to identify governing physical mechanisms. This paper focuses on LOD anomalies although polar motion was assimilated simultaneously. Our results indicate that changes in the oceanic LOD excitation are mostly attributed to changes in total ocean mass. Changes in the spatial distribution of ocean mass turned out to have a minor contribution to the LOD deviations. The same applies to changes in the current system.