Diamond potential versus oxygen regime of carbonatites

Physicochemical conditions of graphite and diamond formation in the carbonate-rich melts were estimated. A large body of analytical data was obtained for compositions of coexisting minerals in the studied objects (Chernigovka Massif, Ukraine, and Chagatai carbonatite complex, Uzbekistan). The carbon isotopic composition of the coexisting carbonates and graphite from these carbonatites was analyzed. New thermodynamic methods were proposed to estimate the oxygen potential in graphite- and diamond-bearing carbonatites. Oxygen fugacity in the graphite-bearing carbonatites is slightly below the quartz-fayalite-magnetite buffer. It was proved that diamond is generated in the course of reduction of carbonate components arriving from plume material into the lower subcontinental lithosphere rather than owing to partial oxidation of methane fluids. As follows from the study of olivine and nominally anhydrous minerals in kimberlites, the limited role of methane in deep mantle is determined by low water activity. Methane is generated in mantle under special conditions such as extremely low oxygen fugacity (for instance, at the base of continental lithosphere) and elevated water activity. These conditions may occur during crystallization differentiation in deep-level chambers of kimberlite and proto-kimberlite magmas.     

Age of nephrite-bearing dikes of the Uzunkyr Belt (South Urals): Local U-Pb isotope analysis of zircon and Sr-Nd isotope data of rock-forming minerals

Through local U-Pb isotope analysis of zircon and Sir-Need data on rock-forming minerals, the age of nephrite-bearing monzonite-diorite dikes of the Uzunkyr Belt has been determined. The derived datings coincide with known geological events that took place in the Phanerozoic on the territory of the South Urals. Xenogenic zircons prove the participation of the Upper Ordovician units in the tectonic structure of the studied area. Devonian zircons are associated with assimilation of subvolcanic rocks which are middle and basic in composition and whose formation time correlates with the appearance of the subduction zone with the Magnitogorsk island arc above it. Early Carboniferous datings indicate the relationship between dike formation and formation of the continental arc-shaped structure to which the Syrostan massif (monzodiorite-granite formation) belongs. The age range of the Uzunkyr nephrite-bearing dikes coincides with that of intrusives (350–336 Ma) of the Magnitogorsk Belt, where formation of gabbro series was also changed by formation of subalkali and alkali igneous rocks. According to the analogous data on zircon datings from metamorphic rocks of the Il’menogorskii Complex, the given territory later evolved as a whole.     

Non-LTE analysis of the formation of EuII lines in the atmospheres of solar-type stars

A method to analyze the statistical equilibrium of the EuII ion based on a 36-level model atom has been developed. The formation of EuII lines without assuming local thermodynamic equilibrium (LTE) is considered for T _eff=5500–7000 K, logg=4.0, and metallicities [A] from 0 to ?1.5. Non-LTE effects in the level populations are primarily due to radiative pumping of excited states from the ground and low-lying levels, which leads to over-population of upper relative to lower levels. As a result, the studied λ4129 and λ6645 Å lines are weaker than in the LTE case. However, due to the small energy differences between even low-lying EuII levels, collisional coupling is strong, and deviations from LTE in EuII lines are modest: for the Sun, non-LTE corrections to the abundance are only 0.04 dex. The non-LTE effects grow with an increase in the effective temperature and with a decrease in the metallicity, so that non-LTE abundance corrections can reach 0.12 dex for T _eff=5500K, logg=4.0, [A]=?1.5 and 0.1 dex for T _eff=7000K, logg=4.0, [A]=0. The effect of inaccuracy in the atomic parameters for EuII on the non-LTE calculations is examined. Analysis of the profiles of the solar EuII λ4129 and λ6645 Å lines is used to empirically refine estimates of the efficiency of collisional processes in forbidden transitions in establishing the distribution of EuII ions over excited states.     

Synchronous Transformations of Mineral and Organic Constituents of Sedimentary Rocks in Geological Structure with an Initial Extension and Subsequent Compression Tectonic Regime

Sedimentary rocks of the section in the Red River fold zone of northern Viet Nam are considered. It is shown that secondary mineral parageneses formed in two stages. The first stage (35–17 Ma ago) corresponded to the period of structure extension and sediment subsidence to a depth of about 6 km. This period and subsequent 10 Ma were marked by the formation of a usual dia- and catagenetic zoning of metasedimentary rocks. The second stage (5–7 Ma ago) corresponded to processes of compression that were responsible for the deformation of rocks into gentle folds and 1.5 to 2.2 times contraction of the section thickness in different places. The sequential–mineralogical zoning was disturbed at this stage. Smectites and mixed-layer minerals were replaced by chlorites and hydromicas. Organic material also responded to compression simultaneously with inorganic components. The bituminous component was released from humic matter and rocks became enriched in hydrocarbons.     

Infrared and Raman spectroscopy studies of the α–β phase transition in cristobalite

Infrared and Raman spectra of cristobalite are presented as a function of temperature through the phase transition. The modes are assigned and the assignments compared to those of earlier workers. The compatibility of modes at the G-point of the a-phase with the X and G-points of the ß-phase is given. In the transition region of ca. 500–550 K, smooth changes in intensity, frequency and linewidths are seen in many modes, indicative of coexistence of a- and ß-forms.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Vendian and Permian–Triassic Plagiogranite Magmatism of the Ust-Belaya Mountains,West Koryak Fold System,Northeastern Russia

Geotectonics - Vendian and Permian–Triassic plagiogranite magmatism is distinguished for the Ust-Belsky and Algansky terranes of West Koryak fold system. The U‒Pb zircon ages from...     

Age and origin of rocks of the Daldyn Group of the Anabar Shield: Evidence from U-Pb zircon dating,Sm-Nd and Lu-Hf isotope systematics

The Hf-Nd isotope systematics was used to determine the genesis of zircons from granulites of the Daldyn Group of the Anabar Shield. Obtained age of magmatic crystallization for biotite–hypersthene crystalline schists and garnet amphibolites agree with position of zircons within terrestrial array. Magmatic genesis of plagiogranite neosome under granulite conditions was established for leucocratic plagiogneisses.