Determining groundwater degradation from irrigation in desert-marginal northern China

Groundwater degradation from irrigated agriculture is of concern in semi-arid northern China. Data-scarcity often means the causes and extent of problems are not fully understood. An irrigated area in Inner Mongolia was studied, where abstraction from an unconfined Quaternary aquifer has increased threefold over 20 years to 20 million m³/year; groundwater levels are falling at up to 0.5 m/year; and groundwater is increasingly mineralised (TDS increase from 400 to 700–1,900 mg/L), with nitrate concentrations up to 137 mg/L N. Residence-time (chlorofluorocarbons), stable-isotope and hydrogeochemical indicators helped develop a conceptual model of groundwater system evolution, demonstrating a direct relationship between modern water proportion and the degree of groundwater mineralisation, indicating that irrigation-water recycling is reducing groundwater quality. The investigations suggest that before irrigation development, active recharge to the aquifer from wadis significantly exceeded groundwater inflow from nearby mountains, previously held to be the main groundwater input. Away from active wadis, groundwater is older with a probable pre-Holocene component. Proof-of-concept groundwater modelling supports geochemical evidence, indicating the importance of wadi recharge and irrigation return flows. Engineering works protecting the irrigated area from flooding have reduced good quality recharge; active recharge is now dominated by irrigation returns, which are degrading the aquifer.     

Theoretical-Observational Comparisons and Details in the Evolution of Sakurai's Object

We create a grid of evolutionary models which include models thatexhibit born-again behavior; that is a very late helium pulse. Ourmodels include metalicities between Z = 0.001 and Z = 0.020. Massloss is varied beginning at the peak of the last thermal pulse onthe AGB. By doing this, we determine the range of helium mass atAGB departure that later produces a very late helium flash. Wepresent a direct comparison between our models, Sakurai's Object andFG Sge. Based on our comparisons, we make an observable predictionfor the future of Sakurai's Object: We expect it to increase intemperature and decrease slightly in luminosity within the next 20to 70 years and then to cool and brighten a second time with alonger time scale of roughly 200 to 500 years. It will become asFG Sge is now.     

Magnetic properties and emplacement of the Bishop tuff,California

 Anisotropy of magnetic susceptibility (AMS) and characteristic remanence were measured for 45 sites in the 0.76 Ma Bishop tuff, eastern California. Thirty-three sites were sampled in three stratigraphic sections, two in Owens gorge south of Long Valley caldera, and the third in the Adobe lobe north of Long Valley. The remaining 12 sites are widely distributed, but of limited stratigraphic extent. Weakly indurated, highly porous to dense, welded ash-flow tuffs were sampled. Saturation magnetization vs temperature experiments indicate two principal iron oxide phases: low Ti magnetites with 525–570  °C Curie temperatures, and maghemite with 610°–640  °C Curie temperatures. AF demagnetization spectra of isothermal remanent magnetizations are indicative of magnetite/maghemite predominantly in the multidomain to pseudo-single domain size ranges. Remeasurement of AMS after application of saturating direct fields indicates that randomly oriented single-domain grains are also present. The degree of anisotropy is only a few percent, typical of tuffs. The AMS ellipsoids are oblate with K_min axes normal to subhorizontal foliation and K_max axes regionally aligned with published source vents. For 12 of 16 locality means, K_max axes plunge sourceward, confirming previous observations regarding flow sense. Topographic control on flow emplacement is indicated by the distribution of tuff deposits and by flow directions inferred from K_max axes. Deposition east of the Benton range occurred by flow around the south end of the range and through two gaps (Benton notch and Chidago gap). Flow down Mammoth pass of the Sierra Nevada is also evident. At least some of the Adobe lobe in the northeast flowed around the west end of Glass mountain. Eastward flow directions in the upper Owens gorge and southeast directions in the lower Owens gorge are parallel to the present canyon, suggesting that the present drainage has been established along the pre-Bishop paleodrainage. Characteristic remanence directions from 45 sites (267 samples) yield an overall mean of D=348°, I=53° for the Bishop tuff. A correlation is found in two of the three profiles between density and remanence inclination. A mean remanence direction based on 13 localities together with data from uncompacted xenoliths and data from the ash-fall tuff at Lake Tecopa is: D=353°, I=54°, k=172, α₉₅=2.9°, N=15. Received: 11 July 1995 / Accepted: 29 February 1996     

Sediment remobilisation from decomposing cordgrass (Spartina anglica) patches on a wave‐exposed intertidal flat

Abstract

Concerns about the potential adverse effects of Spartina invasion on New Zealand estuaries, such as habitat loss and degradation, have led to herbicide use to control its spread. An experiment was conducted in the Manukau Harbour (New Zealand) to determine sediment remobilisation rates (?E) from herbicide‐treated S. anglica patches. Paired treatment and control patches (≤25 m diam.) were monitored at two sites 500 m apart with different wave exposures. Above‐ (AGB) and below‐ground (BGB) biomass decomposition and AE were determined from repeat surveys over c. 2.5 years. Work done by waves (W), which integrates wave‐energy dissipation at the bed over time, was used as a surrogate measure of sediment transport potential. Complete AGB loss occurred in both treated patches within 3 months of initial herbicide application, whereas BGB (a matrix of roots and rhizomes) persisted much longer. An exponential decay model (r ² = 0.6) fitted to the site‐two treatment data predicted an c. 85% reduction in BGB after 5 years, whereas the BGB changes for the larger and more heterogeneous site‐one treatment were more complex. BGB was a better predictor of average bed elevation than AGB in multiple regression models and, although bed elevation decreased through time and with waves, BGB was positively related to bed elevation at both sites. AE was similar for both treatment patches (c. 0.05 and c. 0.06 m yr^‐1, P < 0.001, r² ≥ 0.97) and complete sediment loss was predicted to occur within 6–10 years. The site‐one control patch accumulated sediment (0.01 m yr^‐1 , P < 0.001, r ² = 0.81) whereas the more wave‐exposed site‐two control eroded (0.01 m yr^‐1, P = 0.0017, r ² = 0.61). The potential for adverse sediment effects resulting from Spartina control at wave‐exposed sites will be minimal if the treated areas are small relative to the size of the estuary.     

Diatom-inference models for surface-water temperature and salinity developed from a 57-lake calibration set from the Sierra Nevada, California, USA

Physical, chemical, and biological data were collected from a suite of 57 lakes that span an elevational gradient of 1360 m (2115 to 3475 m a.s.l.) in the eastern Sierra Nevada, California, USA as part of a multiproxy study aimed at developing transfer functions from which to infer past drought events. Multivariate statistical techniques, including canonical correspondence analysis (CCA), were used to determine the main environmental variables influencing diatom distributions in the study lakes. Lakewater depth, surface-water temperature, salinity, total Kjeldahl nitrogen, and total phosphorus were important variables in explaining variance in the diatom distributions. Weighted-averaging (WA) and weighted-averaging partial least squares (WA-PLS) were used to develop diatom-based surface-water temperature and salinity inference models. The two best diatom-inference models for surface-water temperature were developed using simple WA and inverse deshrinking. One model covered a larger surface-water temperature gradient (13.7 °C) and performed slightly poorer (r² = 0.72, RMSE = 1.4 °C, RMSEP_jack = 2.1 °C) than a second model, which covered a smaller gradient (9.5 °C) and performed slightly better (r² = 0.89, RMSE = 0.7 °C, RMSEP_jack = 1.5 °C). The best diatom-inference model for salinity was developed using WA-PLS with three components (r² = 0.96, RMSE = 4.06 mg L^–1, RMSEP_jack = 11.13 mg L^–1). These are presently the only diatom-based inference models for surface-water temperature and salinity developed for the southwestern United States. Application of these models to fossil-diatom assemblages preserved in Sierra Nevada lake sediments offers great potential for reconstructing a high-resolution time-series of Holocene and late Pleistocene climate and drought for California.     

A Model for Estimating Future Emissions of Sulfur Hexafluoride and Perfluorocarbons

Sulfur hexafluoride (SF₆), perfluoromethane (CF₄) and perfluoroethane (C₂F₆) are strong greenhouse gases with long (>1000 year) atmospheric residence times. We derive emission factors for the major anthropogenic sources and project future emissions for 5 regions and the world. Although firms in many industrialized countries are already limiting emissions, without further policy intervention global emissions will rise 150% (CF₄ and C₂F₆) and 210% (SF₆) between 1990 and 2050; radiative forcing will increase 0.026 W m^-2. Full application of available low-cost and costless policies in industrialized nations would cut that radiative forcing by one-quarter. Increased forcing due to these gases is small (<2%) relative to other gases but permanent on the timescale of human civilization. We also quantify plausible manipulations to governmental data that will be used to determine compliance with the 1997 Kyoto Protocol, which includes commitments for industrialized countries to regulate these and other greenhouse gases. More complete and transparent data are urgently needed. West European nations, for example, can cut their emissions of these gases by half by 2010 simply by manipulating emission factors within the current bounds of uncertainty.     

Tectonic settings and magma associations

The largest volumes of peralkaline silicic rocks are found in areas of epeirogenic uplift and rift formation on the continents, but they may also form in several other tectonic settings, such as the oceanic islands, during the later stages of orogenic cycles, as isolated occurrences in active mobile belts, and in areas of extensional tectonics at or near continental plate margins. Their emplacement is effected during periods of dominantly tensional stresses. The peralkaline silicic rocks are typically members of the transitional, mildly aikaline basalt-trachyte association. Associated salic rocks are commonly feld-spathoidal and/or anorthite-normative, as well as peralkaline. Two main types of association are distinguished: firstly, provinces where the peralkaline rocks are mainly of comenditic type, where the salic rocks are in relatively low abundance compared to basic, and where the intermediate (Daly) composition gap is not present; secondly, provinces of pantelleritic or mixed pantelleritic-comenditic volcanism, where the basic : acid volume relationships are reversed and where the Daly gap is usually markedly developed.     

Quasi-biennial variations in the winter-time circulation of high latitudes

Summary In the years between 1952 and 1962 a quasi-biennial modulation became apparent in the total ozone values measured over Arosa, Switzerland, during spring. The stratospheric vortex behavior in the northern hemisphere during March of the years 1958 to 1964 also showed a biennial variation. This has led to speculations that the quasi-biennial forcing of the tropical stratosphere may extend its influence to the stratosphere and troposphere of high latitudes. It is shown in this paper that the stratosphere and troposphere of high latitudes in the northern hemisphere, indeed, are coupled by a feedback mechanism. The forcing from tropical latitudes, however, seems to be minimal.

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Die quasi-biennale Veränderlichkeit der Zirkulation in hohen Breiten während des Winters

Zusammenfassung Während der Jahre 1952 bis 1962 wurde in den über Arosa, Schweiz, im Frühling gemessenen Gesamtozonwerten eine quasi-biennale Modulierung entdeckt. Das Verhalten des stratosphärischen Polarwirbels im März der Jahre 1958 bis 1964 zeigte ebenfalls eine zweijährliche Veränderlichkeit. Dies verleitete zur Schlußfolgerung, daß die quasi-biennale Einwirkung der tropischen Stratosphäre sich bis in die Stratosphäre und die Troposphäre hoher Breiten erstreckt. In der vorlegenden Studie wird gezeigt, daß die Stratosphäre und Troposphäre der Nordhalbkugel in hohen Breiten tatsächlich durch einen Rückkoppelungs-Mechanismus verbunden sind. Der Einfluß tropischer Breiten auf die Zirkulationsmodulierung scheint jedoch gering zu sein.

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With 14 Figures     

Identifying trends in groundwater quality using residence time indicators: an example from the Permian aquifer of Dumfries, Scotland

The Permian sandstone and breccia aquifer of Dumfries has an important role in supplying water to the principal town in southwest Scotland. The area comprises mainly pastoral farmland with some industry and fish farming. Ongoing development of the aquifer has revealed the existence of complex groundwater flow through fractures and increasing nitrate concentrations. To further investigate these issues, the age and quality of groundwater throughout the aquifer has now been assessed using standard hydrogeochemical techniques together with CFCs and SF₆ as residence time indicators. The aquifer consists of sandstone- and breccia-dominated units: the Locharbriggs Sandstone in the east and the Doweel Breccia in the west. Groundwater throughout the aquifer is of Ca–Mg–HCO₃ type and moderately mineralised; pH is near neutral. The observed groundwater chemistry is the product of maritime rainfall modified by the dissolution of carbonate material in the breccia, sandstone and surficial deposits. CFC and SF₆ concentrations are interpreted on the basis of mixing between older (>50 years) and recent (1990s) components. Although there is generally a higher proportion of older water within the Locharbriggs Sandstone compared to the Doweel Breccia, stable isotope evidence suggests that the older water component in the interbedded sandstones of the breccia is of much greater antiquity, possibly containing an element of palaeowater. Concentrations of nitrate across the aquifer can be directly related to the amount of recent recharge. Modern groundwater contains approximately 9 mg l^–1 NO₃-N and pre-1950s groundwater has approximately 2 mg l^–1 NO₃-N. Nitrate concentrations measured at individual boreholes are explained by the relative proportions of modern and pre-1950s groundwater. If current practices continue, the concentrations of nitrate measured across the Dumfries Basin will rise as the proportion of pre-1950s groundwater diminishes.

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Resumen El acuífero de areniscas y brechas Pérmicas de Dumfries desempeña un papel importante en el abastecimiento a la ciudad principal del Sudoeste de Escocia. El área comprende sobretodo tierras de pastoreo y granjas, junto con algunas industrias y piscifactorías. El desarrollo iniciado en el acuífero ha revelado la existencia de un complicado flujo subterráneo a través de las fracturas y de un aumento progresivo en la concentración de nitrato. Con el fin de profundizar en el conocimiento de estos temas, se ha determinado la edad y calidad de las aguas subterráneas en todo el acuífero por medio de técnicas hidrogeoquímicas estándar y de indicadores del tiempo de residencia como los clorofluorcarbonados (CFCs) y el fluoruro de azufre (SF₆). El acuífero está formado por las areniscas de Locharbriggs, al Este, y las brechas de Doweel, hacia el Oeste. Las aguas subterráneas son de tipo bicarbonatadas cálcico-magnésicas y presentan una mineralización moderada, mientras que el pH es prácticamente neutro. La química de las aguas subterráneas es el resultado del aerosol marino modificado por la disolución de materiales carbonatados en las brechas, areniscas y depósitos superficiales. Las concentraciones de CFCs y SF₆ se interpretan a partir de una mezcla de aguas entre una componente antigua (más de 50 años) y una reciente (de la década de 1990). Aunque en general se da una mayor proporción de aguas antiguas en las areniscas de Locharbriggs que en las Brechas de Doweel, los isótopos estables sugieren que la componente de aguas antiguas en las intercalaciones de areniscas que aparecen en la formación de brechas es mucho más antigua, y que, posiblemente, se trate de paleoaguas. Las concentraciones de nitrato en el acuífero pueden ser relacionadas directamente con la aportación de recarga reciente. Las aguas subterráneas modernas contienen aproximadamente 9 mg l^–1 de nitrato, mientras que las aguas subterráneas anteriores a 1950 tienen unos 2 mg l^–1. Se puede explicar las concentraciones de nitrato en pozos individuales por las proporciones relativas de aguas subterráneas modernas y anteriores a 1950. Si las prácticas actuales continúan, se producirá un aumento de las concentraciones de nitrato en la cuenca de Dumfries debido a la disminución de la proporción de aguas antiguas.

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Résumé L'aquifère des grès et brèches du Permien de Dumfries joue un rôle important dans l'alimentation en eau de la principale ville du sud-ouest de l'Écosse. La région est principalement soumise à de l'élevage pastoral avec quelques industries et des piscicultures. La progression de l'exploitation de cet aquifère a révélé l'existence d'un écoulement souterrain complexe en fractures et des concentrations en nitrate croissantes. Dans le but d'étudier ces deux points plus en détail, l'âge et la qualité de l'eau souterraine dans tout l'aquifère ont été évalués en utilisant des techniques hydrogéochimiques conventionnelles avec les CFC et SF₆ comme marqueurs du temps de séjour. L'aquifère est constitué par des unités dominées par des brèches et des grès: les grès de Locharbriggs à l'est et les brèches de Doweel à l'ouest. L'eau souterraine dans tout l'aquifère a un faciès bicarbonaté calcique et magnésien et est moyennement minéralisée; le pH est proche de la neutralité. Le chimisme observé de l'eau souterraine résulte des apports marins par la pluie modifiés par la dissolution du matériau carbonaté des brèches, des grès et des formations superficielles. Les concentrations en CFC et SF₆ sont interprétées sur la base d'un mélange entre des composantes ancienne (>50 ans) et récente (années 1990). Bien qu'il y ait en général une plus forte proportion d'eau ancienne dans les grès de Locharbriggs que dans la brèche de Doweel, les isotopes stables suggèrent que la composante d'eau ancienne dans les grès interstratifiés des brèches est beaucoup plus ancienne, contenant probablement un élément d'eau fossile. Les concentrations en nitrate dans l'aquifère peuvent être directement reliées au taux de recharge récente. L'eau souterraine moderne contient approximativement 9 mg l^–1 en NO₃-N et l'eau souterraine d'avant 1950 environ 2 mg l^–1 en NO₃-N. Les concentrations en nitrate mesurées dans des forages individuels sont expliquées par des proportions relatives d'eaux souterraines moderne et antérieure à 1950. Si les pratiques actuelles continuent, les concentrations en nitrate mesurées dans le bassin de Dumfries augmenteront alors que la part de l'eau souterraine d'avant 1950 diminuera.

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