Esterase activities in the bivalve mollusc Adamussium colbecki as a biomarker for pollution monitoring in the Antarctic marine environment

Marine environments are continuously being threatened by a large number of xenobiotics from anthropogenic sources. Even in sparsely populated and relatively pristine areas, such as Antarctica, hazardous chemicals can pose a serious environmental problem. The main aims of the present study were to (1) validate and optimize an analytical technique utilizing a microtitre-plate photometer to ascertain background levels of esterase activities in the Antarctic bivalve Adamussium colbecki, (2) carry out in situ monitoring of esterase activities to assess any potential environmental impacts of the Italian Scientific Antarctic Base "Terra Nova Bay" on the surrounding marine area. Results showed the presence of organophosphorous-sensitive cholinesterase (ChE) and carboxylesterase (CbE) activities in the gills of A. colbecki and optimal assay conditions were comparable with those found for bivalve species from temperate areas. A higher sensitivity of ChE versus acetylthiocholine activity in A. colbecki to chlorpyrifos compared to species from temperate areas may also be inferred. The in situ study indicated no differences in the environmental quality of the three study sites located around the Italian Base.     

Observed and Modelled Convective Mixing-Layer Height at Dome C,Antarctica

The mixing-layer height is estimated using measurements from a high resolution surface-layer sodar run at the French-Italian station of Concordia at Dome C, Antarctica during the summer 2011–2012. The temporal and spatial resolution of the sodar allows the monitoring of the mixing-layer evolution during the whole diurnal cycle, i.e. a very shallow nocturnal boundary layer followed by a typical daytime growth. The behaviour of the summer mixing-layer height, variable between about 10- and 300 m, is analyzed as a function of the mean and turbulent structure of the boundary layer. Focusing on convective cases only, the retrieved values are compared with those calculated using a one-dimensional prognostic equation. The role of subsidence is examined and discussed. We show that the agreement between modelled and experimental values significantly increases if the subsidence is not kept fixed during the day. A simple diagnostic equation, which depends on the time-averaged integral of the near-surface turbulent heat flux, the background static stability and the buoyancy parameter, is proposed and evaluated. The diagnostic relation performance is comparable to that of the more sophisticated prognostic model.     

Interpreting the role of proximity on Industrial District competitiveness using a complexity science-based view and Systems Dynamics simulation

The paper investigates how proximity affects Industrial District competitiveness. We adopt the complexity theory by analyzing the influence of the proximity on the Industrial District adaptive capacity. Our argument in fact is that the more adaptive the Industrial District, the more the competitive success. Based on the complexity theory, we identify the structural features that allow Industrial District adaptation and their best values. Then, by developing a computational model based on the Systems Dynamics, we conduct a simulation analysis to evaluate the influence of proximity on the values of Industrial District structural features affecting its adaptive capacity. Results show that too much proximity is detrimental for the Industrial District competitiveness.     

A review of near-surface QS estimation methods using active and passive sources

Journal of Seismology - Seismic attenuation and the associated quality factor (Q) have long been studied in various sub-disciplines of seismology, ranging from observational and engineering...     

A continuous stable isotope record from the penultimate glacial maximum to the Last Interglacial (159–121 ka) from Tana Che Urla Cave (Apuan Alps,central Italy)

Relatively few radiometrically dated records are available for the central Mediterranean spanning the marine oxygen isotope stage 6–5 (MIS 6–5) transition and the first part of the Last Interglacial. Two flowstone cores from Tana che Urla Cave (TCU, central Italy), constrained by 19 U/Th ages, preserve an interval of continuous speleothem deposition between ca. 159 and 121 ka. A multiproxy record (δ¹⁸O, δ¹³C, growth rate and petrographic changes) obtained from this flowstone preserves significant regional-scale hydrological changes through the glacial/interglacial transition and multi-centennial variability (interpreted as alternations between wetter and drier periods) within both glacial and interglacial stages. The glacial stage shows a wetter period between ca. 154 and 152 ka, while the early to middle Last Interglacial period shows several drying events at ca. 129, 126 and 122 ka, which can be placed in the wider context of climatic instability emerging from North Atlantic marine and NW European terrestrial records. The TCU record also provides important insights into the evolution of local environmental conditions (i.e. soil development) in response to regional and global-scale climate events.     

Some Statistics of the Temperature Structure Parameter in the Convective Boundary Layer Observed by Sodar

The characteristics of the temporal and height variations of the temperature structure parameter $C_\mathrm{T}^{2}$ in strongly convective situations derived from the sodar echo-signal intensity measurements were analyzed for the first 100 m. It was corroborated that the probability density function (pdf) of the logarithm of $C_\mathrm{T}^{2}$ in the lower convective boundary layer is markedly non-Gaussian, whereas turbulence theory predicts it to be normal. It was also corroborated that the sum of two weighted Gaussians, which characterize the statistics of $C_\mathrm{T}^{2}$ within convective plumes and in their environment and the probability of plume occurrence, well approximates the observed pdfs. It was shown that the height behaviour of the arithmetic mean of $ C_\mathrm{T}^{2}$ (both total and within plumes) follows well a power law $C_\mathrm{T}^{2} (z) \sim z^{-q}$ with the exponent $q$ close to the theoretically predicted value of 4/3. But for the geometrical means of $C_\mathrm{T}^{2}$ (both total and within the plumes), $q$ is close to 1. The difference between arithmetically and geometrically averaged $C_\mathrm{T}^{2}$ profiles was analyzed. The vertical profiles of the standard deviation, skewness and kurtosis of $\hbox {ln}C_\mathrm{T}^{2}$ pdfs were analyzed to show their steady behaviour with height. The standard deviations of the logarithm of $C_\mathrm{T}^{2}$ within the plumes and between them are similar and are 1.5 times less than the total standard deviation. The estimate of the variability index $F_\mathrm{T}$ and its height behaviour were obtained, which can be useful to validate some theoretical and modelling predictions. The vertical profiles of the skewness and kurtosis show the negative asymmetry of pdfs and their flatness, respectively. The spectra of variations in $\hbox {ln}C_\mathrm{T}^{2}$ are shown to be satisfactorily fitted by the power law $f^{-\gamma } $ in the frequency range 0.02 and 0.2 Hz, with the average exponent $\approx $ 1.27  $\pm $  0.22.     

Monitoring a Marine Coastal Area: Use of Mytilus galloprovincialis and Mullus barbatus as Bioindicators

Abstract. Samples of Mytilus galloprovincialis and Mullus barbatus were collected in eight coastal sites along the South Adriatic and Ionic coasts of Italy in spring 2000 for a survey of coastal pollution in the Mediterranean basin. Specimens were analysed using an integrated approach based on residue analysis of common aquatic pollutants like organochlorines such as hexachlorobenzene (HCB), DDTs and polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), heavy metals and nonylphenols (NPnE) and biomarker responses such as acetylcholinesterase (AChE) activity, and the two specific P450 activities benzo(a)pyrene monooxygenase (BPMO) and 7-ethoxyre-sorufin-(9-deethylase (EROD). Biological and morphological parameters like somatic liver index (SLI), gonadosomatic index (GSI) and gonadal and gamete histology (eggs and sperms) were also evaluated in red mullet samples. A contamination gradient in which several hot spots occur were revealed in this study. The hot spots account for high levels of organochlorines in both species near incinerators and of PAHs in harbour areas. Levels of both NPnE and AChE activity were highest in two protected marine areas and were within detectable limits in others. This finding was confirmed by P450 activities, in which maximum levels were detected in harbours and protected marine areas. No morphological alterations of male and female gonads were observed on the histological level.     

Spatial variability of Posidonia oceanica (L.) Delile epiphytes around the mainland and the islands of Sicily (Mediterranean Sea)

This paper investigates patterns of variability in epiphytes of Posidonia oceanica leaves at various spatial scales around Sicily, including geographical differences among the Mediterranean basins, differences between the small islands and mainland, and the variability among and within replicated meadows in each of the previous conditions. Data on percentage cover of the most common epiphytic organisms were analysed by univariate techniques. Encrusting red algae, encrusting brown algae, filamentous algae, encrusting bryozoans, erect bryozoans, hydroids and Foraminifera were the most abundant taxa. Significant differences in the abundance of taxa were detected among geographical regions, while no significant differences were found between the islands and mainland. At smaller scales, variability was concentrated mostly among leaves 100s of centimetres apart and among meadows a few kilometres apart. These results suggest that both geographical and local processes are important in structuring the epiphytes of P. oceanica leaves in this area of the Mediterranean.     

The growth of “black crusts” on calcareous building stones in Palermo (Sicily): a first appraisal of anthropogenic and natural sulphur sources

Chemical, mineralogical and isotopic composition (³⁴S/³²S) analyses were carried out on “black crusts” developed on the old buildings of Palermo (Sicily) with the aim to distinguish between natural and anthropogenic sulphur sources. Furthermore individual samples of total suspended particulate (TSP) were collected and analysed in order to estimate the influence of air pollution on the decay process of calcareous stones in a typical southern Mediterranean coastal environment. SEM/EDS analysis, X-ray diffractometry, IR spectroscopy and liquid chromatography led to the compositional characterization of “black crusts” and airborne particulate matter in the city. Sulphur isotopic compositions of gypsum-bearing crusts showed a prevailing contribution of anthropogenic sources (vehicle exhaust and other combustion processes). Natural sulphur and/or sulphate sources (biogenic and/or sea-spray) were shown to play a secondary role. These data can be considered a starting point for the determination of the rate of growth of “black crusts” in a coastal Mediterranean urban environment like Palermo. In the future, they might be useful to local authorities for planning more efficient maintenance action in order to slow as much as possible the rate of decay of the monumental heritage of the city.