宁东煤田横城矿区太原组煤中关键金属的物质来源和富集机理

对宁东煤田横城矿区太原组9号煤层进行了矿物学和地球化学研究,以便查明煤中关键金属的分布、赋存和富集特征,并评价其综合利用前景。研究结果表明：① 横城矿区9号煤以高的镜质组含量、特低—低灰分产率和中—高硫含量为特征。② 煤中矿物主要由高岭石组成,以细胞充填状、透镜状和薄层状等形式存在。煤层底板中矿物主要由石英、高岭石和白云母组成,其主要为碎屑成因。③ 煤层中常量元素主要由SiO2和Al2O3组成,煤中Li、Zr、Nb、Hf、Pb和Th的含量达到轻度富集—富集程度,其中Li、Pb和Th主要赋存于高岭石,Zr和Hf赋存于锆石,Nb赋存于高岭石和锐钛矿。矿区9号煤层形成于受海水影响的潮坪 潟湖环境,煤层下部形成于铁源供给不足的低位沼泽环境,煤层上部形成于铁源严重不足的高位沼泽环境,故下部煤层中硫以黄铁矿硫为主而上部以有机硫为主。煤中碎屑物质主要来源于阴山古陆和阿拉善地块,阴山古陆主要提供了元古宙的陆源碎屑物质,阿拉善地块主要供给了早石炭世的碎屑物质,此外也有少量的火山灰和奥陶系灰岩风化残积物进入到含煤盆地。煤中的Li、Zr、Nb等关键金属的富集主要受控于长英质的碱性—过碱性物质输入量的多少,同时水/岩作用过程也导致了关键金属的活化、迁移和重新分配。煤灰中Li2O含量超过其边界品位,REO、Ga、Zr和REY接近相应边界品位,故可考虑Li Ga Zr REY等的综合开发利用。     

浙东南玉苍山-彭溪碱长花岗岩锆石U-Pb年龄学、岩石地球化学特征及其成因类型

玉苍山-彭溪岩体位于东部沿海花岗岩带北端,受古太平洋板块俯冲制约。笔者等以该岩体碱长花岗岩为研究对象,开展锆石U-Pb测年,获得其加权平均年龄为96.50±1.81Ma和98.27±0.39 Ma,表明该岩体为晚白垩世岩浆活动的产物。该岩体主要矿物组成为钾长石（60%～70%）、石英（25%～35%）,少量斜长石（＜5%）、黑云母（＜2%）等,呈中细粒花岗结构。该岩体地球化学特征上呈现高硅、富碱、低铝,镁、钙、磷、钛、铁等元素含量极低,Rb、K等大离子亲石元素和Th、U、Zr、Hf等高场强元素富集,亲铁元素Co、Ni、Cr、V等含量较低;K/Rb值低,Rb/Sr、Rb/B值高;稀土元素总量高,且轻稀土元素富集程度远大于重稀土元素,同时具有明显的铕负异常,分异指数高;反映了该岩体具有强烈的壳源特征,且形成时岩浆演化分异程度高,存在斜长石、磷灰石等矿物的分离结晶,属于过铝质高钾钙碱性花岗岩系列。认为该岩体属于A型花岗岩,为晚白垩世时期板内伸展构造环境下软流圈地幔上涌、部分地壳参与熔融形成的。     

云南牟定安益铂钯钛磁铁矿床铂族矿物特征及成因初探

云南牟定安益矿床为一处铂族金属与钛磁铁矿共同产出的大型钛磁铁矿铂族金属矿床。目前对该矿床中铂族元素的赋存状态研究甚少。结合野外宏观地质特征和室内岩矿鉴定,笔者利用TIMA和LA-ICP-MS-Mapping分析方法,对安益矿床中铂族金属矿物学特征进行研究,发现安益矿床中的铂族元素（PGEs）主要以独立矿物的形式存在。铂族矿物（PGMs）多为铂和钯的砷化物、碲化物,如砷铂矿、砷钯矿、黄碲钯矿、碲钯矿等;主要分布于硅酸盐矿物中,其次为硫化物边缘,部分分布于磁铁矿边缘;铂族矿物成因主要有岩浆成因和热液成因2种。岩浆作用形成的铂族矿物分布于硅酸盐矿物中或硫化物边缘,硅酸盐中的铂族矿物是早期PGE与半金属元素形成的纳米团簇颗粒随岩浆演化形成矿物颗粒,被结晶的硅酸盐矿物包裹;分布于硫化物边缘的铂族矿物是残余熔浆结晶的结果。热液作用将PGE以类质同象的形式富集于钛磁铁矿单辉岩的部分矿物中,如热液蚀变较强烈的黄铜矿中含有较高的Rh,这也与铂族矿物集中分布在钛磁铁矿单辉岩中一致。     

Numerical Simulation of Rainfall-induced Xianchi Reservoir Landslide in Yunyang, Chongqing, China

A calamitous landslide happened at 22:00 on September 1, 2014 in the Yunyang area of Chongqing City, southwest China, enforcing the evacuation of 508 people and damaging 23 buildings. The landslide volume comprised 1.44 million m3 of material in the source area and 0.4 million m3 of shoveled material. The debris flow runout extended 400 m vertically and 1600 m horizontally. The Xianchi reservoir landslide event has been investigated as follows: (1) samples collected from the main body of landslide were carried out using GCTS ring shear apparatus; (2) the parameters of shear and pore water pressure have been measured; and (3) the post-failure characteristics of landslide have been analyzed using the numerical simulation method. The excess pore-water pressure and erosion in the motion path are considered to be the key reasons for the long-runout motion and the scale-up of landslides, such as that at Xianchi, were caused by the heavy rainfall. The aim of this paper is to acquired numerical parameters and the basic resistance model, which is beneficial to improve simulation accuracy for hazard assessment for similar to potentially dangerous hillslopes in China and elsewhere.     

Geochemical and Isotopic Techniques Constraints on the Origin, Evolution, and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan, SE China

Geothermal resources are increasingly gaining attention as a competitive, clean energy source to address the energy crisis and mitigate climate change. The Wugongshan area, situated in the southeast coast geothermal belt of China, is a typical geothermal anomaly and contains abundant medium- and low-temperature geothermal resources. This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region, encompassing the recharge origin, water–rock interaction mechanisms, and residence time. The results show that the geothermal water in the western region of Wugongshan is weakly alkaline, with low enthalpy and mineralization levels. The hydrochemistry of geothermal waters is dominated by Na-HCO3 and Na-SO4, while the hydrochemistry types of cold springs are all Na-HCO3. The hydrochemistry types of surface waters and rain waters are Na-HCO3 or Ca-HCO3. The δD and δ18O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m. Molar ratios of major solutes and isotopic compositions of 87Sr/86Sr underscore the significant role of silicate weathering, dissolution, and cation exchange in controlling geothermal water chemistry. Additionally, geothermal waters experienced varying degrees of mixing with cold water during their ascent. The δ13C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic. The δ34S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock. Age dating using 3H and 14C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.     

Geochronology and Petrogenesis of Late Carboniferous to Early Permian Basalts in the Central Lhasa Subterrane, Southern Tibet: Implications for the Evolution of the Sumdo Paleo-Tethys Ocean

Basalts from the Late Carboniferous to Early Permian are extensively developed in the central Lhasa subterrane, southern Tibet. Studying the petrogenesis of these rocks may have implications for the late Paleozoic arc magmatism along the central Lhasa subterrane uncovering more of the evolution of the Sumdo Paleo-Tethys Ocean and its dynamic mechanism. Basalt samples from the Luobadui Formation in the Leqingla area, NW of Linzhou City in the central Lhasa subterrane, southern Tibet exhibit arc-like geochemical signatures in a subduction-zone tectonic setting characterized by high Al2O3 and low TiO2 contents, fractionated REE patterns with low Nb/La ratios and high LREE concentrations, and negative HFSE anomalies. Based on their higher Th/Ce, Nb/Zr, and lower Ba/Th, Pb/Nd ratios, slightly negative to positive εNd(t) values, and the relatively high Sr-Pb isotopic compositions, these samples were probably derived from partial melting of a depleted mantle source of garnet + spinel lherzolite, metasomatized by subducted sediments around 297 Ma. Modeling of the trace elements indicates that these basalts experienced fractional crystallization of olivine, clinopyroxene and minor plagioclase during magma ascent and eruption. It is proposed that these Late Carboniferous–Early Permian basalts are associated with the northward subduction of the Sumdo Paleo-Tethys Ocean seafloor along the southern margin of the central Lhasa subterrane.     

东昆仑二叠系格曲组火山岩年代学、地球化学特征及其构造意义

东昆仑古特提斯造山带经历了从洋壳俯冲到陆-陆碰撞及后碰撞伸展的造山过程,但对古特提斯洋闭合时间一直存在争议,争论的焦点集中在晚二叠世格曲组沉积盆地原型及中上二叠统之间不整合关系代表的构造事件。本文对东昆仑红石山地区格曲组火山岩开展了锆石U-Pb年代学与岩石地球化学研究,结果表明,岩石富集Rb、Th、Ba等大离子亲石元素(LILE)而亏损Nb、Ta、Ti、P等高场强元素(HFSE),具有大陆岩浆弧的地球化学特征。火山岩具有高Ba/Th比值(53.6)、Th/Ce比值(0.23)、Nb/Ta比值(18.35)及低Dy/Yb比值(1.42),表明晚二叠世火山岩由枕状玄武岩和洋底沉积物等洋壳物质俯冲至60 km左右深度时熔融所形成。锆石U-Pb定年表明,格曲组下部碎屑岩段流纹质凝灰岩和英安质沉凝灰岩206Pb/238U加权平均年龄分别为(257.5±2.5)Ma和(256.2±4.8)Ma,上部灰岩段粗安质晶屑凝灰岩206Pb/238U加权平均年龄为(251.8±2.3) Ma。结合区域上已报道的格曲组及花岗岩研究成果,认为古特提斯洋在晚二叠世开始向北俯冲消减,沉积于弧前盆地的格曲组为古特提斯...     

雄安至北京大兴国际机场快线起步区地下段结构抗浮设防水位取值研究

抗浮设防水位直接影响到地下结构的安全与建设费用,在地下结构建设中至关重要,因此,科学合理地确定地下结构的抗浮设防水位具有巨大的社会意义和经济价值。本文以“雄安新区至北京大大兴国际机场快线地下工程段”为研究对象,系统分析了研究区水文地质条件以及地下水位年内年际动态变化规律,利用数值模拟法和类比预测法确定了地下结构抗浮设防水位标高建议值。结果表明,该场地区域浅层地下水水位埋深一般为5.0～20.0m,地下水水位标高一般为–10.0～1.0m。近五年场地浅层地下水水位标高一般为–5～–10 m,埋深一般为3.0～15.0 m,地下水位逐年升高,回升速率约1.0 m/a。地下结构抗浮设防水位标高取值建议取使用期抗浮设防水位采用数值模拟法预测结果。该成果服务了“雄安新区至北京大兴国际机场快线(R1线)”项目场地抗浮设计,为雄安新区重大工程建设项目的抗浮安全设计提供了示范。     

辽东湾红沿河附近海域2017—2018年冬季气温-水温-冰情关系研究

辽东湾是我国冰情最严重海域,每年冬季都会受到海冰的显著影响,冰情预测评估可为辽东湾涉海活动提供防冰抗冰的技术依据。建立气温-水温-冰情的相关性,结合便于获取的现场高精度连续气象数据和高精度冰情预测模型,可实现局地小尺度的冰情快速预测评估。基于2017—2018年冬季辽东湾东岸红沿河附近海域实测气象-水温-冰情同步观测数据,结合辽东湾大尺度整体冰情（浮冰面积）,推演局地气温、水温与不同尺度冰情评价参数（浮冰范围与冰厚）的相关关系,提出基于不同气温区间的气温变化规律的冰底热通量选取方法,进而建立适用于辽东湾的气温-水温-冰情评估方法。相关性分析结果显示：观测点气温与水温存在明显相关性;浮冰范围与气象数据存在明显相关性,临界温度为 -5 ℃的累计负气温能很好拟合本年度盛冰期浮冰范围。基于HIGHTSI进行数值模拟后发现：水温与块体积法计算冰底热通量时,冰水间的热传递系数取2.2×10^-5是可行的;水温对冰情的影响表现在海冰冰厚最大值与冰期长短。为弥补辽东湾其他海域因缺少实测海水温度观测数据欠缺、冰底热通量选取不准选取导致的冰情模拟预测评估困难的问题,本文依据水温与气温的相关性,将水温随气温变化划分为结冰区（气温小于-10 ℃时水温维持冰点附近）、过渡区（气温为-10~-5 ℃时水温处于-1.4~-0.4 ℃）、融冰区（气温高于-5 ℃时水温随气温的增大逐渐增大）,进而提出适用于辽东湾所有海域的冰底热通量计算方法和冰情评估方法。     

基于波导结构的紧凑型电介质加载双极化天线研究

本文提出了一款基于波导结构的紧凑型电介质加载双极化天线.通过采用在传统波导内加载电介质材料的方法,可以有效减小波导尺寸,从而达到天线小型化的目的.针对波导结构口径天线高后瓣辐射的问题,本文提出了一种在波导金属壁上添加矩形槽孔的方法,该方法的原理不同于扼流环结构.相比之下,矩形槽孔具有结构简单、尺寸小、加工方便等优点.通过电磁场全波仿真分析,可以发现所提出的天线具有阻抗带宽宽（大于40%）、增益高（8.6±0.6 dBi）、辐射性能稳定等优点,有很大的潜力,可以应用在如卫星通信等X波段的各种应用场景中.