石英单晶无衍射样品板的研制

本文介绍了由作者首创、以石英单晶片制成的一种用于粉晶X射线衍射仪上薄膜样品的底托——单晶无衍射样品板。与常规的玻璃板或者多孔素瓷板及银滤膜等样品底托相比,后二者因系结晶物质,会产生自身的衍射峰;玻璃板则在2?15—37°(Cu靶)间有一个宽大的衍射晕,这些都影响样品衍射花样的准确测定。以平行于石英(11.21)面网切割制成的单晶片,在所测定的2?3一135°范围内不存在任何衍射峰,背景值分布十分平稳,且明显低于玻璃样品板。使用这种新型的单晶无衍射样品板,将有助于提高粉晶X射线衍射仪测定的精确度。     

Effect of compressive strength on the performance of the NEMO-LIM model in Arctic Sea ice simulation

Satellite records show that the extent and thickness of sea ice in the Arctic Ocean have significantly decreased since the early 1970s. The prediction of sea ice is highly important, but accurate simulation of sea ice variations remains highly challenging. For improving model performance, sensitivity experiments were conducted using the coupled ocean and sea ice model (NEMO-LIM), and the simulation results were compared against satellite observations. Moreover, the contribution ratios of dynamic and thermodynamic processes to sea ice variations were analyzed. The results show that the performance of the model in reconstructing the spatial distribution of Arctic sea ice is highly sensitive to ice strength decay constant (C^rhg). By reducing the C^rhg constant, the sea ice compressive strength increases, leading to improved simulated sea ice states. The contribution of thermodynamic processes to sea ice melting was reduced due to less deformation and fracture of sea ice with increased compressive strength. Meanwhile, dynamic processes constrained more sea ice to the central Arctic Ocean and contributed to the increases in ice concentration, reducing the simulation bias in the central Arctic Ocean in summer. The root mean square error (RMSE) between modeled and the CryoSat-2/SMOS satellite observed ice thickness was reduced in the compressive strength-enhanced model solution. The ice thickness, especially of multiyear thick ice, was also reduced and matched with the satellite observation better in the freezing season. These provide an essential foundation on exploring the response of the marine ecosystem and biogeochemical cycling to sea ice changes.

     

基于模态逼近的EOF重构算法重建公元1250年以来北半球地表气温空间格局

随着气候场重建数据在揭示气候动力机制以及与数值模式模拟相结合等方面的应用, 它在气候变化研究领域中的实用性和重要性已得到广泛认可。因此, 关于空间格局重建方法的研究也就显得尤为重要。本文提出了一种新的气候场重建方法, 即模态逼近的经验正交函数分解方法。该方法利用代用资料与器测资料不同空间模态之间的协调性, 采用模态逐次逼近, 从而实现对过去无器测资料覆盖的气候场的重建。基于该方法, 本文利用549个树轮序列重建了北半球(22.5°N以北)公元1250年以来的地表气温空间场。为验证该方法的有效性, 设计了多组验证试验, 结果均表明该重建方法能够较好的再现器测数据的年代际尺度变率特征。最终重建结果表明, 与已有研究结果相比, 该方法重建出的北半球小冰期(1400~1700年)平均气候状态的空间格局特征与基于多组气候模式集合平均在该时段的模拟结果更为接近。另外, 为体现重建结果对外强迫的响应特征, 本文比较了在不同强度(强、中等、弱)典型火山年的空间格局差异, 发现高纬度地区对火山外强迫相比于中低纬地区更加敏感, 这与已有的基于数值模式模拟研究的结论基本一致。综合以上讨论, 证明了该方法在气候场重建方面的有效性和应用潜力。     

Fischer图解及其在旋回层序研究中的应用──以北京西山张夏组为例

Ｆｉｓｃｈｅｒ图解（又称为容纳空间图解）为人们研究沉积旋回在空间上的叠置规律、相对海平面变化、层序级次的划分以及地层层序对比等提供了一种客观实用的方法。本文较详细地讨论了该图解的绘制方法及应注意的问题。运用该图解，将北京西山下苇甸剖面张夏组划分为１个大的三级旋回层序和４个四级旋回层序，根据图解反映的相对海平面变化讨论了旋回层序与构造运动间的关系，提出华北板块晚寒武世之前的＂翘翘板运动＂应始于中寒武世张夏期之早期到中期。     

南京玄武湖水底交通隧道工程与环境效应分析

南京玄武湖隧道,既在城市中心,又在水下,是脆弱环境下典型的地质工程。影响水下隧道施工的不权有环境工程地质条件,还有城市环境约束因素;另外,隧道施工会对城市环境产生不良影响。作者对上述问题作了具体分析,并用系统工程的思想对隧道出口及施工方案的选择进行了初步评价。     

Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.     

塔里木盆地古近纪岩相古地理

古近纪是塔里木盆地由海向陆转化的时期。当时该区的海侵来自研究区西侧的古地中海分支,物源则主要是盆地北部的南天山以及南部的昆仑山,沉积中心在库车坳陷西部以及塔西南坳陷带的西部。古新世-始新世早期（库姆格列木群沉积期）在盆地北部库车坳陷发育砾岩、砂岩、碳酸盐岩及膏盐岩,沉积环境有滨岸、漏湖、潮坪及扇三角洲等,塔西南坳陷以碳酸盐岩和膏岩为特征,从东到西发育开阔台地、近岸局限台地、蒸发盐台地、辫状河三角洲环境等,二者之间即在塔北隆起及北部坳陷带位置为宽阔的古隆起区。始新世晚期-渐新世（苏维依组沉积期）整个盆地以滨浅湖为主,发育粉砂岩与泥岩互层沉积,塔西南坳陷虽然仍发育多个海相层,但海水的影响明显比始新世早期弱,当时主要古地理单元有海湾渴湖、滨浅湖、扇三角洲和辫状河三角洲。总体上,塔里木盆地在古近纪经历了早期以扇三角洲为主的浅水环境到晚期的滨浅湖及海湾溻湖环境,古近纪研究区的古气候以热带-亚热带的干旱气候为主。     

RFI Test Observations at a Candidate Ska Site in China

Radio frequency interference (RFI) test observations were carried out at one of the candidate Square Kilometre Array (SKA) sites in Guizhou province, following the “RFI Measurement Protocol for Candidate SKA Sites” (hereafter RFI protocol). All data (raw and calibrated) are preserved in some suitable format, such as that set by the international RFI working group of the Site Evaluation and Selection Committee (SESC). An RFI test in December 2003 was performed according to Mode 1 of the RFI Protocol, in order to identify technical difficulties which might arise during a co-ordinated RFI measurement campaign over a period of 1 year. In this paper we describe the current equipment, observational technique and data presentation. The preliminary results demonstrate that the RFI situation at Dawodang depression in Guizhou province makes it quite a promising location for the proposed SKA. Furthermore, the first session of the RFI monitoring program, which was made in May 2004, showed that a complete RFI measurement including both modes 1 and 2 of the RFI Protocol would take about 2 weeks. The possible ways to minimize some limitations of the current equipment are also discussed, which will enable us to meet the RFI protocol.     

结合第8届国际探空仪系统比对试验探讨国产气球施放高度

根据阳江探空站高空气象探测用750g气象气球施放的实际高度的现状,结合中国大探中心组织国产GPS探空仪在阳江用国产2000g气象气球比对试验时施放的高度以及广东阳江第8届国际探空仪系统比对期间施放的实际高度,探讨雨天和高空相对湿度较大的气象条件下对国产气象气球施放高度的影响。结果显示,雨天或高空相对湿度较大时,对国产现有的气象气球施放的高度存在较大的影响。研究表明,解决了国产气象气球的球皮防雨、防潮问题,很大程度上解决了国产气象气球施放高度不稳定的难题。     

Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.