磁铁矿的穆斯堡尔谱研究

我们对大冶、马坑、大顶、黄沙坪、鞍山五个矿区的七个铁矿石样品中的磁铁矿作了室温~(57)Fe和~(119)Sn穆斯堡尔谱测定,并根据穆斯堡尔数据和化学分析推算出磁铁矿的非理想配比的分子结构式. 初步研究表明,不同的成矿条件和Zn、Mg等二价阳离子的类质同像替代的多少,明显地影响晶胞参数和穆斯堡尔参数.文中讨论了它们的变化规律性.     

Silicon Isotope Geochemistry of Micro—Fine Disseminated Gold Deposits in SW Guizhou and NW Guangxi,China

Quartz was studied with respect to its silicon isotopic composition and cathodoluminescence in micro-fine disseminated gold deposits in SW Guizhou and NW Guangxi.The results showed that quartz in wall rocks.ores and that in association with hydrothermal silicification are distinctive in silicon isotopes and cathodoluminescence characters.Quartz in association with primary silicification is non-luminescent while that in wall rocks and associated with secondary silicification exhibits striking luminescence.Based on the dynamic fractionation of silicon isotopes,it is suggested that the mineralization was accompanied by rapid transport of aprimary siliceous fluid along the major deep fault system into subordinate faults before ore components deposited in favorable strata via penetration and metasomatism.Therefore,a deep origin is implicit for gold deposits of this type.     

储层裂缝特征测井解释方法综述

为了更好地研究裂缝性砂砾岩储层和其它裂缝性储层裂缝的测井解释问题,综述了目前在裂缝性储层裂缝测井解释中主要采用的常规评价、人工神经网络和斯通利波３类方法在识别裂缝带和定量计算储层裂缝参数两个方面的应用原理和研究现状,并指出了今后的一些研究方向。     

Fifteen Years of Ocean Observations with China Argo

For 15 years since the beginning of China Argo project, China has deployed over 350 profiling floats in Pacific and Indian ocean, and constructed China Argo ocean observing network. Moreover, we have setup the Argo data receiving, processing and distributing system, and developed various Argo data products using Argo observations, which has promoted the progress of ocean data sharing in China. The abundant Argo data have become a main data source in oceanic and atmospheric basic researches and operational applications. A batch of important achievements in basic research and operational application have been brought, e.g. in aspects of tropical cyclone (typhoon), ocean circulation, meso-scale eddy, turbulence, heat/salt storage and transport and water mass, as well as in ocean, atmosphere/climate operational forecasting and predicting. With the extension of the international Argo program from “Core Argo” to “Global Argo”, we are faced with great challenges in the long-term maintaining and sustained developing of our Argo ocean observing network. It is suggested that we should take the opportunity to construct China regional Argo ocean observing network as soon as possible in adjacent northwestern Pacific and Indian ocean using Chinese BeiDou profiling floats, which will make us to take responsibility and obligation of a big country for addressing global climate changes and preventing natural disasters.     

论卡以头组的时代

中国科学院南京地质古生物研究所的有关人员 (1980 )曾做过大量地层古生物工作 ,证实卡以头砂页岩层或卡以头组的时代为三叠纪最早期 ,是飞仙关组底部地层的相变。“论卡以头组”一文认为该组下部的时代为二叠纪 ,上部则属三叠纪。对该文提供的地层古生物资料进行分析后 ,本文作者认为该论点缺乏证据 ,不能成立 ;将陆相的威宁哲觉剖面代替标准地点宣威羊场的过渡相剖面作为卡以头组的标准剖面 ,也是不合适的     

豫西偃龙煤田深部铝土矿地质特征及矿床成因

偃龙煤田深部铝土矿区位于豫西铝土矿成矿区嵩箕铝土矿成矿小区,是豫西铝土矿成矿区的重要组成部分。区内铝土矿赋存于上石炭统本溪组中上部,下伏具有岩溶特征的寒武—奥陶纪灰岩,沉积相为滨岸泻湖泥岩相区,属海相沉积的一水硬铝石岩溶型矿床,矿体主要填充在岩溶作用形成的负地形之中。本文系统阐述了矿区的含矿岩系、矿床地质及矿石质量特征等,研究了本区铝土矿的成矿地质条件、矿床的展布规律和富集规律,对矿床成因及控矿因素进行了分析,指出铝土矿床分布在坳陷区边部及隆起区的过渡带,铝土矿的厚度和品质与本溪组厚度有着明显的正相关关系,预测深部仍有较好的成矿远景。     

The effect of slight to minor biodegradation on C<Subscript>6</Subscript> to C<Subscript>7</Subscript> light hydrocarbons in crude oils: a case study from Dawanqi Oilfield in the Tarim Basin,NW China

Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much information regarding the genetic origin and alteration of crude oils. But secondary alterations—especially biodegradation—have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C₆–C₇ LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C₆–C₇ cycloalkanes. For branched C₆–C₇ alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C₆–C₇ LHs. There is a particular case: although 2,2,3-trimethylbutane has a relative higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2-Dimethylpentane is the most resistant to biodegradation in branched C₆–C₇ alkanes. Furthermore, the 2-methylpentane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain isomers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango’s LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the “Biodegraded” zone. When the heptane value is 0–21 and the isoheptane value is 0–2.6, the crude oil in Dawanqi Oilfield is defined as the “Biodegraded” zone.     

Spatial and seasonal distributions of soil phosphorus in a typical seasonal flooding wetland of the Yellow River Delta,China

Soil samples from 0 to 100 cm depth were collected in four sampling sites (Sites A, B, C and D) along a 250-m length of sampling zone from the Yellow River channel to a tidal creek in a seasonal flooding wetland of the Yellow River Delta of China in fall of 2007 and spring of 2008 to investigate spatial and seasonal distribution patterns of total phosphorous (TP) and available phosphorus (AP) and their influencing factors. Our results showed that TP contents in spring and AP contents in both seasons in surface soils increased with increasing distances away from the Yellow River channel. TP contents in surface soils (0–10 cm) followed the order Site A (698.6 mg/kg) > Site B (688.0 mg/kg) > Site C (638.8 mg/kg) > Site D (599.2 mg/kg) in fall, while Site C (699.6 mg/kg) > Site D (651.7 mg/kg) > Site B (593.6 mg/kg) > Site A (577.5 mg/kg) in spring. Generally, lower TP content (630.6 mg/kg) and higher AP level (6.2 mg/kg) in surface soils were observed in spring compared to fall (656.2 mg/kg for TP and 5.2 mg/kg for AP). Both TP and AP exhibited similar profile distribution patterns and decreased with depth along soil profiles with one or two accumulation peaks at the depth of 40–80 cm. Although the mean TP content in soil profiles was slightly higher in spring (635.7 mg/kg) than that in fall (628.0 mg/kg), the mean TP stock was obviously lower in spring (959.9 g/m²) with an obvious accumulation at the 60–80 cm soil depth compared to fall (1124.6 g/m²). Topsoil concentration factors also indicated that TP and AP had shallower distribution in soil profiles. Correlation analysis showed that AP had significant and positive correlation with these soil properties such as soil organic matter, salinity, total nitrogen and Al (p < 0.01), but TP was just significantly correlated with TN and Al (p < 0.05).     

羌塘盆地结构构造与油气勘探方向

羌塘盆地是我国陆域大型中生代海相沉积盆地,富含烃源岩,但结构构造非常复杂。结合野外观测及相关资料对地震反射剖面进行地质构造详细解释,良好地揭示了羌塘盆地结构和深部构造。羌塘盆地逆冲推覆构造延伸存在显著差别,北羌塘凹陷多格错仁逆冲推覆构造、阿木错逆冲推覆构造与南羌塘凹陷肖茶卡—双湖逆冲推覆构造、多玛—其香错逆冲推覆构造仅发育于盆地表层0~3km深度范围,北羌塘凹陷龙尾错逆冲推覆构造、羌中隆起北缘逆冲推覆构造、南羌塘凹陷赛布错—扎加藏布逆冲推覆构造、拉萨地块北缘色林错逆冲推覆构造系统自地表向深部延伸深度超过6km,羌塘盆地深部还发育中生界底部逆冲系和基底逆冲系,伴有不同规模的褶皱构造。逆冲推覆构造形成活动时代包括晚白垩世、古近纪早期和古近纪晚期,晚白垩世与古近纪早期逆冲推覆构造运动导致构造隆升的裂变径迹年龄分别为87±5~75±4Ma、64±5~46±4Ma。经过多期逆冲推覆构造改造和褶皱变形,羌塘盆地中生界海相沉积地层与烃源岩显著增厚,为新生代晚期二次生烃及油气成藏提供了非常有利的地质构造条件;北羌塘凹陷发育万安湖向斜、半岛湖背斜、东湖向斜、阿木错向斜,南羌塘凹陷发育宁日圈闭、鲁雄错背斜、诺尔玛错圈闭、协德圈闭、崩则错圈闭,羌中隆起下伏侏罗系和三叠系烃源岩,色林错下白垩统下伏古近纪湖相沉积,这些构造部位都是油气勘探的重要靶区。     

Natural Variability of Shear Strength in a Granite Residual Soil from Porto

The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation.