山东济宁高硫煤与低硫煤煤层剖面地球化学特征研究

运用电感耦合等离子质谱（ICP-MS）、X射线荧光光谱（XRF）、离子选择电极（ISE）、显微镜光度计和煤化学等方法,对山东济宁矿区的高硫煤（太原组16号煤层）与低硫煤（山西组3上煤层）剖面的煤岩、煤质和煤地球化学特征进行研究。高硫煤中微量元素在垂向上呈现显著的变化规律：（1）Sr含量从煤层底板到顶板呈增高趋势,而Ba含量则相反;因而Sr/Ba比值从下向上呈逐渐变大趋势（0.04～47.7）;（2）Th/U比值从下向上也呈逐渐变大趋势（0.2～37.1）;（3）As含量在煤层顶板石灰岩（26.1μg/g）、透镜状黄铁矿夹层（14.7～19.3μg/g）中较高;（4）V、Cr、Co、Ni、Cu、Pb、Zn等元素在煤层底部和顶部分层中含量较高,而在煤层中部分层中含量较低;（5）Nb、Ta、Zr、Hf、Ga等元素从煤层的底部到顶部呈逐渐降低趋势;（6）煤中稀土元素总量（REE）,除透镜状黄铁矿夹层（第2、4、11分层）外,其它分层（第1、3、5、6、7、8、9、10分层）显示从上往下逐渐增高之规律性。低硫煤中微量元素的分布和垂向变化与高硫煤明显不同：As含量在14个煤分层中都较低（1.03～3.37μg/g）,Sr/Ba比值从下向上变化不大（0.4～2.2）,各个煤分层中稀土元素总量（REE）呈现随灰份含量增高而增高的变化趋势,低硫煤与高硫煤的稀土元素分布模式差别很大。上述研究结果表明济宁矿区高硫煤与低硫煤在地球化学特征上的差别,反映了上石炭统太原组与下二叠统山西组沉积环境和聚煤条件的差别,具有指相意义;太原组16号煤层中富集的硫及有害微量元素,对环境具有潜在危害。     

海洋沉积物中的钒、钼、铊、镓及其环境指示意义

研究探讨沉积物中钒、钼、铊和镓的生物地球化学行为对揭示海洋环境演变机制有重要的科学意义,基于此考虑,本文系统分析总结了近年来海洋沉积物中V、Mo、Tl和Ga的地球化学特征以及与环境关系的研究进展,以期对深入开展环境敏感微量元素的海洋生物地球化学有所裨益。结果表明,由于受人为输入的影响,近海沉积物中V、Mo、Tl和Ga含量高于远海,河口高于近海;在表层沉积物中,细颗粒沉积物中V、Mo、Tl和Ga含量高于粗颗粒中的,且其含量与物源、有机质含量等沉积环境因素密切相关;在垂直分布上,随沉积物深度的增加,V、Mo、Tl和Ga含量趋于降低,表明近几十年来,随人为影响的加剧,海洋作为地球上物质的汇获得了比以前更多的V、Mo、Tl和Ga。由此可见,在水平方向上,海洋沉积物中V、Mo、Tl和Ga的丰度可表明输入物源的特性,而在柱状样中的垂直分布,则能够表征历史年代上V、Mo、Tl和Ga沉积量的差异。由于沉积物中V、Mo、Tl和Ga的性质比较稳定,它们在一定程度上可以揭示和表征海洋环境演变的讯息,追溯海洋环境演变的历史以及预测将来的发展趋向。     

波浪及波流边界层泥沙起动规律

基于波浪边界层理论及单向流泥沙起动Shields曲线,推证出波浪泥沙起动Shields曲线;基于波流边界层理论,提出表述波流边界层动力特征的波流比因子X及非线性作用因子Y,并建立了Y与X的相关关系;在此基础之上,结合单向流及波浪泥沙起动Shields曲线,推证出波流共同作用下泥沙起动Shields曲线。结果表明:波浪泥沙起动Shields曲线在层流区与单向流光滑紊流区曲线保持一致,粗糙紊流区与单向流粗糙紊流区曲线保持一致,过渡区线型为折线,由层流区及粗糙紊流区曲线延长交汇获得;X及Y能够合理地表征波流边界层动力对比特征及非线性作用特征;波流泥沙起动Shields曲线介于波浪及单向流泥沙起动Shields曲线之间,随着波流比因子X的不同,依据非线性作用因子Y,自动在波浪及单向流泥沙起动Shields曲线之间非线性过渡。建立的波流泥沙起动Shields曲线与试验结果吻合较好,且能够概括单向流、波浪及波流等不同动力及细沙、粗沙等不同粒径的泥沙起动条件。     

关于积云增雨和实施方案的探讨

在综合雷雨云式的积云降水特点和归纳观测及理论结果的基础上,用数值模拟研究了阵雨形成机制,发现雷雨云式的积云结构类似于雹云,也存在着水平风“零域”和成雨“穴道”,大粒子群向这里集中并累积,然后再下泻成阵雨。据此提出了积云人工增雨的动力学根据和设计实施方案的要领,并给出了积云人工增雨作业部位、时机的概念模型。     

Low temperature stress on the hematological parameters and <Emphasis Type="Italic">HSP</Emphasis> gene expression in the turbot <Emphasis Type="Italic">Scophthalmus maximus</Emphasis>

To study the effect of low temperature stress on hematological parameters and HSP gene expression in the turbot (Scophthalmus maximus), water temperature was lowered rapidly from 18 to 1°C. During the cooling process, three individuals were removed from culture tanks at 18, 13, 8, 5, 3, and 1°C. Blood samples and tissues were taken from each individual, hematological indices and HSP gene expression in tissues were measured. The red blood cell count, white blood cell count, and hemoglobin concentration decreased significantly (P < 0.05) as temperature decreased. Enzyme activities of plasma alanine transaminase and creatine kinase increased as temperature decreased, whereas aspartic transaminase and γ-glutamyl transpeptidase activities displayed no obvious changes above 1°C and lactate dehydrogenase activity increased first and then decreased. Blood urea nitrogen and uric acid levels were highest at 8°C, and creatinine concentration was highest at 3°C. The concentrations of plasma cortisol, cholesterol, and triglyceride all increased significantly (P < 0.05) as temperature decreased. The serum glucose concentration increased first and then decreased to the initial level. The HSP70 mRNA expression showed various patterns in different tissues, whereas HSP90 mRNA expression showed the same tendency in all tissues. Overall, these results indicate that temperature decreases in the range of 8 to 5°C may induce a stress response in S. maximus and that temperature should be kept above 8°C in the aquaculture setting to avoid damage to the fish.     

基于磷脂脂肪酸的热带西太平洋沉积物生源要素矿化过程探析

甄别生源要素参与的海洋沉积物矿化过程对探析生源要素的生物地球化学循环有重要的作用,矿化作用包括有氧呼吸、硝酸盐还原、铁锰异化还原及硫酸盐还原等多个过程,但如何区分这些过程一直是海洋沉积物矿化研究的难点。本研究采用气相色谱-质谱(GC-MS)联用对热带西太平洋沉积物中的磷脂脂肪酸(phospholipid fatty acid, PLFA)的组成进行了解析,并分析不同矿化过程中的主要PLFA种类及其影响因素,探究PLFA对沉积物矿化的指示作用。结果表明,PLFA总量在有氧呼吸过程中最高,而在硝酸盐还原过程中最低;且14:0、i14:0、i15:0和i19:0是有氧呼吸过程中微生物PLFA的主要组成,当其含量明显降低时可以指示沉积物矿化从有氧呼吸转变为硝酸盐还原;而10:0、17:0、20:0和22:0含量之和显著增加时则指示了硫酸盐还原过程的发生。在热带西太平洋沉积物中,总有机碳(TOC)和总有机氮(TON)含量以及间隙水NO₃-N含量是PLFA含量的重要影响因素,PLFA总量随着TOC和TON含量的减少而减少,并且TOC和TON的降解能够促进PLFA降解的发生,对PLFA组成有更直接的影响。     

CO2 flux and seasonal variability in the turbidity maximum zone and surrounding area in the Changjiang River estuary

The turbidity maximum zone(TMZ) is one of the most important regions in an estuary.However,the high concentration of suspended material makes it difficult to measure the partial pressure of CO_2(pCO_2) in these regions.Therefore,very little data is available on the pCO_2 levels in TMZs.To relatively accurately evaluate the CO_2 flux in an example estuary,we studied the TMZ and surrounding area in the Changjiang(Yangtze) River estuary.From seasonal cruises during February,August,November 2010,and May 2012,the pCO_2 in the TMZ and surrounding area was calculated from pH and total alkalinity(TA)measured in situ,from which the CO_2 flux was calculated.Overall,the TMZ and surrounding area acted as a source of atmosphere CO_2 in February and November,and as a sink in May and August.The average FCO_2was-9,-16,5,and 5 mmol/(m~2·d) in May,August,November,and February,respectively.The TMZ's role as a source or sink of atmosphere CO_2 was quite different to the outer estuary.In the TMZ and surrounding area,suspended matter,phytoplankton,and pH were the main factors controlling the FCO_2,but here the influence of temperature,salinity,and total alkalinity on the FCO_2 was weak.Organic carbon decomposition in suspended matter was the main reason for the region acting as a CO_2 source in winter,and phytoplankton production was the main reason the region was a CO_2 sink in summer.     

试样厚度对室内测定黄土湿陷性指标的影响

湿陷性是黄土的特殊工程性质,为研究试样厚度对室内测定黄土湿陷性指标的影响,对西安某地深1~20 m内不同深度采取的黄土,利用常规高压固结仪及改造的固结仪,进行了厚度分别为2 cm与8 cm试样的湿陷试验。对比分析各深度土层2 cm试样和8 cm试样的室内湿陷试验的结果,表明：土层湿陷性较弱或压力较小时,不同厚度试样所得的湿陷系数相差不大;土层湿陷性较强时,随着压力的增大,两者的差异越来越大,同一压力下8 cm试样所得的湿陷系数大于2 cm试样所得的值。黄土的湿陷性越强,试样厚度对试验所得湿陷性指标（湿陷系数、自重湿陷系数、湿陷起始压力）的影响越大,此结论为室内湿陷试验适当调整试样厚度提供了依据。     

华北联网后天津遥测地震台网监测能力和定位精度分析

本文通过天津遥测地震台网在华北遥测地震台网联网后的监控能力的计算和对1992年1—10月地震观测报告的分析处理,得到了一些主要结果。首先,台网的控制能力为:以天津市为中心,半经30km范围内,震级下限为M_L2.0,天津地区及邻区20km内震级下限为M_L2.5。其次,台网的定位精度百分比为:震中误差小于15km的占88％,震中误差15—30km的占8％,震中误差30km的占4％,若以全国地震月报目录定的震中位置为准,天津定的震中位置与其误差小于15km的占81.4％。同时我们还对不同震级,不同震中距(以天津市为中心)的地震的定位精度进行了统计,统计结果为距天津200km范围内的地震,震中误差在15km以内的占91.4％,而距离天津300km以上的地震,震中误差大于30km的占70％。这表明天津台网对远距离地震定位精度较差,这是因为对远距离的地震,天津台网的子台全集中在震中的一侧所致。     

Geochemical Characteristics of Particulate Organic Carbon in the Kocebu Seamount Waters of the Western Pacific Ocean in Spring 2018

The study of the geochemical characteristics of the POC in the seamount area will be of great significance for further understanding the material cycle process in the seamount ecosystem. Based on a comprehensive survey of the Kocebu seamount in the Western Pacific Ocean in March, 2018, the distribution, source and composition of Particulate Organic Carbon (POC) in the seawater of the Kocebu seamount area were discussed. The results showed that the concentration of POC in the Kocebu seamount area gradually decreased with the increasing water depth, and slightly rose in the water layers near the bottom of the seamount. The average concentration of POC in each water mass was sorted from high to low in the order of North Pacific Tropic Water, North Pacific Intermediate Water and Deep Water (DW), and the concentration of POC at stations near the seamount summit was lower than that far from the seamount in the DW. There was upwelling at the water layers of 750~1 500 m above the seamount summit, causing the uplift of the 12.50 μg/L POC isoline in this region, however, no “seamount effect” was formed. The POC was mainly imported from the sea with an average POC/PON of 3.75. At the water layers of 0~300 m, only the POC/chlorophyll a (Chl a) at deep chlorophyll maximum layer was less than 200, indicating that the POC in this region was mainly in a form of life, while at the water layer of 300 m, the POC/Chl a increased sharply, indicating that the non-living POC contributed the most to the total POC.