Interelement relationships and age-related variation of trace element concentrations in liver of striped dolphins (Stenella coeruleoalba) from Japanese coastal waters

Concentrations of 19 trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Tl, Hg, and Pb) were determined in the liver of the striped dolphins (Stenella coeruleoalba) collected around Japan during 1977-1982 to examine the sex difference, age dependence, and interrelationships among trace elements. Tissue distribution of trace elements was also investigated in one adult and one fetus specimens. Generally, concentrations of Se, Sr, Ag, Cd, Cs, Ba, Hg, and Pb were higher in the tissues of adult than those of fetus, whereas the opposite trend was observed for Cr and Tl. There were no significant sex differences in the trace element levels in the liver. Significant positive correlations between age (0-26.5 years) and hepatic concentrations were found for Ag, Se, Hg, V, Fe, Pb, and Sr, suggesting their age-dependent accumulation in the liver. In contrast, hepatic concentrations of Mn and Zn decreased with age. Significant positive relationships were observed between Se, and Hg, Ag, V, Fe, and Sr in the liver.     

Interelement relationships and age-related variation of trace element concentrations in liver of striped dolphins (Stenella coeruleoalba) from Japanese coastal waters

Concentrations of 19 trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Tl, Hg, and Pb) were determined in the liver of the striped dolphins (Stenella coeruleoalba) collected around Japan during 1977–1982 to examine the sex difference, age dependence, and interrelationships among trace elements. Tissue distribution of trace elements was also investigated in one adult and one fetus specimens. Generally, concentrations of Se, Sr, Ag, Cd, Cs, Ba, Hg, and Pb were higher in the tissues of adult than those of fetus, whereas the opposite trend was observed for Cr and Tl. There were no significant sex differences in the trace element levels in the liver. Significant positive correlations between age (0–26.5 years) and hepatic concentrations were found for Ag, Se, Hg, V, Fe, Pb, and Sr, suggesting their age-dependent accumulation in the liver. In contrast, hepatic concentrations of Mn and Zn decreased with age. Significant positive relationships were observed between Se, and Hg, Ag, V, Fe, and Sr in the liver.     

Comparison of AGASA data with CORSIKA simulation

An interpretation of Akeno giant air shower array (AGASA) data by comparing the experimental results with the simulated ones by cosmic ray simulation for KASCADE (CORSIKA) has been made. General features of the electromagnetic component and low energy muons observed by AGASA can be well reproduced by CORSIKA. The form of the lateral distribution of charged particles agrees well with the experimental one between a few hundred metres and 2000 m from the core, irrespective of the hadronic interaction model studied and the primary composition (proton or iron). It does not depend on the primary energy between 10^17.5 and 10²⁰ eV as the experiment shows. If we evaluate the particle density measured by scintillators of 5 cm thickness at 600 m from the core S₀(600), suffix 0 denotes the vertically incident shower) by taking into account the similar conditions as in the experiment, the conversion relation from S₀(600) to the primary energy is expressed as E (eV)=2.15×10¹⁷S₀(600)^1.015 within 10% uncertainty among the models and composition used, which suggests the present AGASA conversion factor is the lower limit. Although the form of the muon lateral distribution fits well to the experiment within 1000 m from the core, the absolute values change with hadronic interaction model and primary composition. The slope of the ρ_μ(600) (muon density above 1 GeV at 600 m from the core) vs. S₀(600) relation in experiment is flatter than that in simulation of any hadronic model and primary composition. As the experimental slope is constant from 10¹⁵ to 10¹⁹ eV, we need to study this relation in a wide primary energy range to infer the rate of change of chemical composition with energy.     

Study on the Historical Distribution of Metals in Aquatic Sediments

In this study, the historical distribution of metals, phosphorous, and sulfur at four different depths in the sediments of different lakes formed in the course of an urban river (in Londrina, Parana State, Brazil) were determined. The transport of metals along the course of the river was observed mainly for Mn, Cr, and Zn. High concentrations of Pb in the Capivara Bay and Cr in the river were attributed to contamination from a battery plant and a tannery, respectively. The concentrations of heavy metals in the deepest layers of the sediments remain high several years after deposition.     

Quantitative approach for damage detection of reinforced concrete frames

The objective of this paper is to provide an analytical basis for the quantitative evaluation of damage to a reinforced concrete structure based on the vibration data obtained by using the damage detection technique. A partial reinforced concrete system of a weak beam/strong column moment frame is chosen as an example. A pushover analysis is carried out in order to numerically examine both the story shear-relative displacement characteristics and the associated damage level. In the analysis, a two dimensional nonlinear finite element analysis is employed considering several constitutive models. As a result, the degradation of the stiffness at the damaged story is characterized in association with the story relative displacement. It is also pointed out that the rotation angle of the column-base is highly correlated with the story relative displacement. Based on the analytical findings, quantitative approaches for a structural health monitoring system are suggested considering both the current sensor technologies and those available in the future. Supported by: Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Scientific Research (Base Research (c) (1), Research No. 14550555)     

Trace element accumulation in fishes collected from coastal waters of the Caspian Sea

Concentrations of 13 trace elements (V, Mn, Cr, Co, Cu, Zn, Se, Mo, Ag, Cd, Hg, Tl and Pb) were determined in muscle of bony fishes collected from coastal areas of the Caspian Sea (Kazakhstan, Azerbaijan, Turkmenistan and Iran). In all the fishes, Zn concentration was highest, followed by Cu, Se, Mn and Co, while levels of toxic elements (Ag, Cd, Cd, Tl and Pb) were relatively low. Concentrations of several elements were significantly varied between the species in each sampling area. For most of the trace elements examined, the concentrations decreased significantly with body weight of fishes. In contrast, a positive correlation with body weight was found for Co, Se and Pb concentrations in one fish species, and Hg in 2 fish species. Geographical difference in the concentrations of trace elements was examined using the Caspian roach collected from five stations of Iranian coastal waters. The concentrations of Co, Mo, Ag, Cd and Tl were higher in fishes from western stations than those from eastern stations, whereas the opposite trend was observed for Hg, indicating that local sources of trace metal pollution may be present in the Iranian coastal areas of the Caspian Sea. Levels of trace elements in Caspian fishes were relatively low in comparison to those of other regions, but Zn and Hg levels in some specimens exceeded the guideline values for food.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

Total and subcellular distribution of trace elements in the liver of a mother-fetus pair of Dall's porpoises (Phocoenoides dalli)

Total and subcellular hepatic Zn, Cu, Se, Mn, V, Hg, Cd, and Ag were determined in a mother-fetus pair of Dall's porpoises (Phocoenoides dalli). Except for higher fetal Cu concentration, all maternal elements were higher. Elements existed mostly in the cytosol of both animals except in the case of maternal Ag in the microsome and fetal Cu and Ag in the nuclei and mitochondria. In the maternal cytosol, Zn, Mn, Hg, and Ag were present in the high-molecular-weight substances (HMW); Se and V were present in the low-molecular-weight substances (LMW); Cu and Cd were mostly sequestered by metallothionein (MT). In the fetal cytosol, Zn, Se, Mn, Hg, Cd, and Ag were present in the HMW and V in the LMW, while Cu and Ag were mostly associated with MT. MT isoforms were characterized using the HPLC/ICP-MS. Two and four obvious peaks appeared in the maternal and fetal MT fractions, respectively. The highest elemental ion intensities were at a retention time of 7.8 min for the mother, and for the fetus the peak elemental ion intensities occurred at a retention time of 4.3 min, suggesting that different MT isoforms may be involved in elemental accumulation in maternal and fetal hepatocytosols.     

Stress drops, wave spectra and recurrence intervals of great earthquakes — implications of the Etorofu earthquake of 1958 November 6

Summary . The great Etorofu earthquake of 1958 November 6 is characterized by a relatively small aftershock area (70 × 150 km²) and an extremely large felt area. The felt area is more extensive than those of any other large earthquakes which have occurred in the southern Kurile to northern Japan arc since the beginning of this century. The mechanism is a pure thrust fault typical of most great earthquakes in island arcs. A body wave magnitude of m _b = 8.2 is obtained at periods around 6 s using more than 40 observations, although an m _b value of only 7.6–7.7 would be expected empirically from the observed surface wave magnitude of M _s= 8.1–8.2. Both an unusually large felt area and a high m _b indicate a dominance of high-frequency components in the seismic waves. A seismic moment of M _o= 4.4 × 10²⁸ dyne cm is determined from long-period surface waves from which a high stress drop of Δσ = 78 bar is obtained using a relatively small aftershock area. Historic data indicate an anomalously long time interval between the 1958 event and any earlier great earthquake from the same source region. The observed high stress drop can be interpreted as a consequence of this long intervening period through which strain built up. The dominance of the high-frequency seismic waves can then be interpreted as a result of this high stress drop. Stress drops, seismic wave spectra and recurrence intervals of great earthquakes are in this way closely related to each other. The 1958 event may represent a high strength extreme of stochastic fluctuation of fracture strength relevant to great earthquakes.