The carbon isotopic ratio of atmospheric carbon dioxide at Tsukuba,Japan

To find out the secular and seasonal trends of the ¹³C value and CO₂ concentration in the surface air and the determination of the ¹³C in the atmospheric CO₂ collected at Tsukuba Science City was carried out during the period from July 1981 to October 1983. The monthly average of the ¹³C value of CO₂ in the surface air collected at 1400 LMT ranged from -7.52 to \s-8.45 with an average of -7.96±0.25 and the CO₂ concentration in the air varied from 334.5 l 1^-1 to 359 l 1^-1 with an average of 347.2±6.3 l 1^-1. The ¹³C value is high in summer and low in winter and is negatively correlated with the CO₂ concentration. In general, the relationship between the ¹³C and the CO₂ concentration is explainable by a simple mixing model of two different constant carbon isotopic species but the relationship does not always follow the model. The correlation between the ¹³C value and the CO₂ concentration is low during the plant growth season and high at other times. The observed negative deviation of the ¹³C value from the simple mixing model in the plant growth season is partly due to the isotopic fractionation process which takes place in the land biota.     

Hindcast/forecast of ENSO events based upon the redistribution of observed and model dynamic height in the Western Tropical Pacific, 1964–1986

Anomalous sea level, anomalous observed dynamic height (0/400 db) and anomalous model dynamic height are examined at the locations of 13 island sea level stations in the tropical Pacific for each bimonth of the four year period 1979 to 1982. Starting in 1981, the anomalous dynamic height data show off-equatorial Rossby waves propagated toward the W boundary of the Pacific basin. At the W boundary, the model Rossby wave activity was found to have excited coastally trapped Kelvin-Munk waves which transmitted the anomalous dynamic height equatorward. At the equator, coastally trapped wave activity excited eastward propagating equatorial Kelvin waves, yielding a pair of anomalous peaks in dynamic height variability in the E equatorial Pacific associated with the 1982–1983 ENSO event. The evolution of the peaks in dynamic height associated with the Rossby and Kelvin wave activity reflects the redistribution of observed upper-ocean heat content in the W tropical Pacific, providing a qualitative hindcast for the 1982–1983 ENSO event. In consequence of these results, and the results of a related study (Inoue et al. 1985), the redistribution of both observed and model heat content, as evidenced in dynamic height in the W Pacific during the 23-year period 1964–1985, is examined for its ability to hindcast and forecast ENSO events in this period. Complex EOF analysis is applied to the Onset Phase of ENSO events occurring in 1968–69, 1972–73, 1976–77, and 1982–83; it is used to determine the characteristic redistribution of heat content (dynamic height) prior to the Mature Phase of ENSO events. This analysis found both model and observed dynamic height in the N hemisphere to be characterized by wind-driven, westward propagating, baroclinic Rossby wave activity, having a remarkably stable period of 3 years over the 23-year period. The complex time series associated with these first spatial eigen-functions are used to construct observed and model hindcast indices that yield high values one year prior to the Mature Phase of ENSO events of the period. These indices achieve these values due to the incidence upon the Philippine coast in fall/winter of a positive anomaly in dynamic height propagating from the east at nondispersive Rossby long wave speeds.     

Observation of the Kyucho in the Bungo Channel by HF radar

Observations of sea surface currents by HF radar were carried out in the Bungo Channel in summer 1992. The current ellipses of M₂ constituent obtained by the observational results agree quite well with those obtained by the ADCP observations, showing that the accuracy of the HF radar measurements is of the same level as ADCP. The results revealed the current structures and their change with the Kyucho in detail. The Kyucho is influenced by the complicated coastal geometry and does not propagate straightly into the Bungo Channel. It propagates further inward after charging the coastal bays with warm water. The current directions change largely, since the currents turn around the stagnant region in the bay filled with the warm water. The northward intrusion begins to be weakened in the southern part of the channel, while it still persists in the northern part. The northward current speeds of the observed Kyucho are about 50 cm/s and sometimes attain 60 to 70 cm/s.     

Spatial Distributions of Phyllosoma Larvae (Crustacea: Decapoda: Palinuridae and Scyllaridae) in Taiwanese Waters

Distributions and taxonomy of phyllosoma larvae were examined in Taiwanese waters, based on ichthyoplankton samples collected from May 1990 to July 1995. Phyllosoma larvae belonged to the two families Scyllaridae and Palinuridae representing 6 genera and 13 species. Of the collected phyllosoma larvae, those of Scyllarus and Panulirus species were most abundant, forming 90% of total numbers. Early stage Scyllarus and Panulirus phyllosoma larvae were abundant in Taiwanese waters. Middle to late stages (except the final stage) of Panulirus phyllosoma larvae were absent from the waters throughout the year, while those of Scyllarus phyllosoma larvae were collected in the waters. This suggests that all stages of Scyllarus phyllosoma larvae may be retained in the northern part of the waters around northern Taiwan while middle to late stages of Panulirus phyllosoma larvae may be flushed out from the waters, the sub-final and final stages then possibly returning to the waters. An anticlockwise eddy existed in the waters off northeastern Taiwan, which may be closely related to flushing out and returning of Panulirus phyllosoma larvae through a much longer planktonic period. This revised version was published online in August 2006 with corrections to the Cover Date.     

Photographic monitoring system for observing heavy free-falling objects: Multi-stage design packages of radioactive waste

In the consideration of safety it is required that packages containing radioactive wastes when dumped at sea should keep their integrity and retain their contents until they reach the seabed. Packages containing simulated radioactive wastes (non-radioactive) were tested by a free-fall method at depthsca. 4,300 m in an area for dumping industrial waste off Shikoku Island. Since the weight of the largest package was 4,300 kg, special attention was paid to the connection of a buoyancy system with mooring rope. Descent and ascent velocities of the free-fall system were calculated prior to the experiment. A free-fall experiment with an extremely heavy object, heavier than ever previously reported, was accomplished without trouble by using the free-fall system. Recovery of a camera, flash-light, and other components was successful in each of the three experiments. Successive photographing of the package during descent was made and its integrity was observed using the photographs taken by the recovered camera. The packages remained intact during descent and at least for a short time after arrival on the seabed.     

Experimental study of reaction between perovskite and molten iron to 146 GPa and implications for chemically distinct buoyant layer at the top of the core

Partitioning of oxygen and silicon between molten iron and (Mg,Fe)SiO₃ perovskite was investigated by a combination of laser-heated diamond-anvil cell (LHDAC) and analytical transmission electron microscope (TEM) to 146 GPa and 3,500 K. The chemical compositions of co-existing quenched molten iron and perovskite were determined quantitatively with energy-dispersive X-ray spectrometry (EDS) and electron energy loss spectroscopy (EELS). The results demonstrate that the quenched liquid iron in contact with perovskite contained substantial amounts of oxygen and silicon at such high pressure and temperature (P–T). The chemical equilibrium between perovskite, ferropericlase, and molten iron at the P–T conditions of the core–mantle boundary (CMB) was calculated in Mg–Fe–Si–O system from these experimental results and previous data on partitioning of oxygen between molten iron and ferropericlase. We found that molten iron should include oxygen and silicon more than required to account for the core density deficit (<10%) when co-existing with both perovskite and ferropericlase at the CMB. This suggests that the very bottom of the mantle may consist of either one of perovskite or ferropericlase. Alternatively, it is also possible that the bulk outer core liquid is not in direct contact with the mantle. Seismological observations of a small P-wave velocity reduction in the topmost core suggest the presence of chemically-distinct buoyant liquid layer. Such layer physically separates the mantle from the bulk outer core liquid, hindering the chemical reaction between them.     

High-pressure and high-temperature stability of chlorite and 23-Å phase in the natural chlorite and synthetic MASH system

A series of experiments was conducted on the decomposition of natural and chemically mixed chlorites to examine the stable hydrous phases in the MgO–FeO–Al₂O₃–SiO₂–H₂O (MFASH) system under 5–12 GPa and 700–1100 °C. The upper pressure and temperature limits of the stability region of chlorite are consistent with those observed in previous studies. The hydrous aluminum bearing pyroxene (phase HAPY) and Mg-sursassite (Sur) were observed just above the temperature stability region of chlorite (Chl); clinohumite (cHm) was observed coexisting with phase HAPY at 6 GPa and 800 °C and coexisting with the 23-Å phase at 7 GPa and 800 °C, which may suggest the transportation of water through Chl → (HAPY → cHm) → 23-Å phase along a relatively warm slab. The 23-Å phase has a wider stability region in the pure MASH system (up to 12 GPa and 1100 °C) than it does in the MFASH system (7–10 GPa, up to 1000 °C). The stability of the 23-Å phase beyond the chlorite breakdown pressure indicates that it may play an important role in transporting water into the deep Earth and even into the mantle transition zone.     

Diurnal Cycle of Sound Scatterers and Measurements of Turbidity Using ADCP in Beppu Bay

From September 20 to 22 in 1994, the vertical profiles of echo intensity and three-component velocities were measured with a bottom-mounted 300 kHz broadband acoustic Doppler current profiler (ADCP) in Beppu Bay in the Seto Inland Sea of Japan. A very strong thermocline was observed from 50 to 60 m. A pronounced diurnal cycle of backscatter strength (BS) was found above the thermocline. However, it was not found under the thermocline where there was a lack of dissolved oxygen. We suggest that the diurnal cycle of BS is caused by the vertical migration of zooplankton. The downward and upward migration occurred in early morning and late afternoon, respectively. The migration speeds estimated from BS isopleth displacements were about 1 cm s^–1. Further, the contribution of turbidity (Tur) to BS was examined by separating out the effect of migrating zooplankton. There was a significant correlation between BS and turbidity under the thermocline. The maximum contributions of the Tur, migrating zooplankton and non-migrating plankton on BS were estimated at 3, 12, 25 dB, respectively. These data suggest that when using an ADCP to estimate Tur, it is very important to consider carefully the backscatter signal from zooplankton.