Direct observation of Cm(III)-fulvate species on fulvic acid-montmorillonite hybrid by laser-induced fluorescence spectroscopy

Particulate matter plays an important role in the removal of metal ions from water in natural aquifers. Some of the most important of these materials consist of associations of inorganic particles (clay minerals, oxides) with humic substances, associations that can form readily in such an environment due to the strong affinity between inorganic particles and humic substances. These associations are referred to in this paper as organic-inorganic hybrids. However, it is not clear whether the sorbed species of metal ions in such organic-inorganic hybrids are organic or inorganic species because of the complexity of such hybrids and the lack of appropriate methods for characterizing the trace metal ions incorporated in them. In this study, laser-induced fluorescence spectroscopy (LIF) was used successfully to characterize the Cm(III) species on an FA(fulvic acid)-montmorillonite hybrid, an example of such organic-inorganic hybrids. The LIF clearly showed that Cm(III) can be sorbed as Cm(III)-fulvate complex in the FA-montmorillonite hybrid. These results were consistent with those of experiments of solid-water partitioning of Cm(III) (or Eu(III) used as an analogue) and speciation calculations based on the stability constants of Cm(III)-fulvate complexes determined in this study. The results of LIF and the partitioning experiments showed that the solid-water distribution of humic substances governed that of Cm(III) under our experimental conditions. The Cm(III) preference for forming Cm(III)-fulvate complexes was also evident under a condition that would be found in a natural aquifer with a fairly low concentration of organic matter in freshwater (dissolved organic carbon: 2 mg/dm³), as determined by our speciation calculations. These findings on the importance of humic substances in the migration of Cm(III) indicate that the clarification of the environmental behavior of humic substances is necessary to understand fully the behavior of Cm(III), or actinide(III) and lanthanide(III) ions, in natural aquifers.     

Simulation analysis of ground liquefaction induced by earthquake

A dynamic effective stress analysis with the finite element method has long been recommended to predict the liquefaction phenomena of sandy soil by authors and Zienkiewicz et al. as well as the similar approaches by the others. Our approach of the analysis is summarized in the first.

Until recently, however, these approaches has not commonly been used as the means of design, although its capability of prediction is appreciated by geotechnicians. This method has been neglected because of the lack of verification studies of soil models of sand and mathematical formulation for boundary problems of liquefaction phenomena. Therefore the verification of the numerical method to evaluate liquefaction potential are urgent requirement of the recent engineering practice. To respond this requirement, extensive numerical studies on the liquefation simulations are performed by DIANA program for shaking table tests which have been conducted by the authors. The test models are soil-structure type models with combination of homogenous ground and partially improved ground by compaction.

The good performance of our approach is proved by the results of numerical simulation showing good agreement with experimental data in terms of response acceleration, excess pore pressure, and deformation profile. It is also demonstrated that the numerical results can provide substantial information to understand the mechanisms of soil ground behavior which is not easily obtained by experiments.

The procedure to identify soil constants for the reflecting surface model is also reported in details.     

The degradation of submarine permafrost and the destruction of hydrates on the shelf of east arctic seas as a potential cause of the “Methane Catastrophe”: some results of integrated studies in 2011

On the basis of the analysis of published data and in the course of the authors’ long-term geochemical and acoustic surveys performed in 1995–2011 on the East Siberian shelf (ESS) and aimed to research the role of the Arctic shelf in the processes of massive methane outbursts into the Earth’s atmosphere, some crucially new results were obtained. A number of hypotheses were proposed concerning the qualitative and quantitative characterization of the scale of this phenomenon. The ESS is a powerful supplier of methane to the atmosphere owing to the continued degradation of the submarine permafrost, which causes the destruction of gas hydrates. The emission of methane in several areas of the ESS is massive to the extent that growth in the methane concentrations in the atmosphere to values capable of causing a considerable and even catastrophic warning on the Earth is possible. The seismic data were compared to those of the drilling from ice performed first by the authors in 2011 in the southeastern part of the Laptev Sea to a depth of 65 m from the ice surface. This made it possible to reveal some new factors explaining the observed massive methane bursts out of the bottom sediments.     

Magnetic properties of siliceous marine sediments in Northern Hokkaido,Japan: a quantitative tectono‐sedimentological study of basins along an active margin

The formation processes of the late Neogene sedimentary basins in Northern Hokkaido have been investigated on the basis of rock magnetism, structural geology and numerical modelling. Untilted site‐mean directions of remanent magnetization of the Wakkanai Formation, obtained from oriented core samples in Horonobe, suggest remarkable counterclockwise block rotation (ca. 70°) since the late Neogene. Uniform microscopic fabric of the siliceous sediments was inferred from the alignment of the principal axes of the anisotropy of magnetic susceptibility (AMS). After correction for tectonic rotation, the maximum axis of AMS, which reflects the sedimentary fabric of the dominant paramagnetic minerals, is in an E‐W direction, which is concordant with the influx direction of diatomaceous particles into the N‐S elongate sedimentary basins. The difference in the bulk initial magnetic susceptibility of the siliceous sediments of the Wakkanai Formation between the depocenter of the basin and its peripheral part implies that terrigenous non‐magnetic fraction has been sorted out during transportation of the detrital grains as gravity flows. As for the development mechanism of the N‐S elongate late Neogene basins in Northern Hokkaido, their depocenter arrangement and subsidence pattern indicates dextral motions upon a longitudinal fault zone along the Eurasian convergent margin. Dislocation modelling was adopted to explain vertical displacement and rotational motion around the study area and successfully restored the deformation pattern based on the assumption of dextral slip at a left‐stepping part of a strand of the transcurrent fault.     

Accumulation of trace elements in harp seals (Phoca groenlandica) from Pangnirtung in the Baffin Island, Canada

Nineteen trace elements were determined in liver, muscle, kidney, gonads, and hair of 18 harp seals (Phoca groenlandica) from Pangnirtung in the Baffin Island, Canada. Concentrations of V, Mn, Fe, Cu, Mo, Ag, and Hg in the liver, Co, Cd, and Tl in the kidney, and Ba and Pb in the hair were significantly higher than those in other tissues. Significant positive correlations between Hg concentrations in the hair, and liver, kidney and testis imply usefulness of the hair sample for non-destructive monitoring of Hg in the harp seals. It is suggested that whereas Hg preferentially accumulates in the liver, the accumulation in other tissues is induced at higher hepatic Hg levels. In contrast, Se may not be accumulated in other tissues compared with the liver even at higher hepatic Hg levels because of the presence of excess Se for Hg detoxification in other tissues.     

Evaluation of intrinsic vulnerability to nitrate contamination of groundwater: appropriate fertilizer application management

In agricultural areas, fertilizer application is the main source of nitrate contamination of groundwater. To develop fertilizer management strategies to combat this problem, arable land in Hokkaido, Japan was evaluated using geographic information system techniques for intrinsic groundwater vulnerability to nitrate contamination. The DRASTIC method was modified to adapt it to the Hokkaido environment and used for the evaluation. Of the seven original DRASTIC factors, the depth to water (D), net recharge (R), soil media (S), topography (T), and impact of vadose zone media (I) were selected and used to explain the vertical movement of contaminants to the aquifer. The rating for the net recharge factor was also modified to a dilution factor for contaminants, rather than as a transporter. The frequency of wells with nitrate concentrations exceeding the Japanese environmental standard (10 mg/L) was reasonably explained by vulnerability evaluation results (GLM: logit-link, quasi-binomial distribution, Y = [1 + exp(6.873765 − 0.045988 × X)]⁻¹, p < 0.001). However, in the paddy fields and pastures, vulnerability did not exhibit a clear relationship with the frequency of wells exceeding the standard. This suggests that the modified DRASTIC method is applicable for fertilizer application management in upland fields. In addition, under the ongoing policy for acreage allotment for rice production, this method will be useful for deciding the arrangement of arable land and crop rotation taking into consideration the potential risk of fertilizer-induced nitrate contamination of groundwater.     

New data on the subaerial low-center-polygonal relief and factors controlling its transformation and current state on the East Siberian Shelf

The problem of the current state of subaerial morphosculptures on the periglacial East Siberian Shelf is still debatable due to the lack of in situ data. Therefore, any new information contributes to the knowledge of the evolution of the Arctic environment. In view of this, a complex of interdisciplinary oceanological studies was carried out in the southeastern part of the Laptev Sea. Using a side-scan sonar, images of the bottom surface were made, which show the shape of low-center-polygonal relief of the part of the modern coastal lowland area in the coastal zone near the area under study. Possible factors controlling the state of this morphosculpture within the East Siberian Shelf area of interest are considered.     

Effects of the Chemical Compositions of Salars de Uyuni and Atacama Brines on Lithium Concentration during Evaporation

During Li recovery from salar brines, Li concentration is typically increased to about 60,000 mg L^?1 by evaporation. We investigated the concentration changes of Li, Na, K, Mg, Cl, SO₄, and B during evaporation of both natural Uyuni and artificial Atacama brines. The Uyuni brine exhibited a maximum Li concentration of 6810 mg L^?1 at 31 days of evaporation, at which point the majority of the Na and K in the brine was removed. The Li concentration decreased with further evaporation due to precipitation as Li₂SO₄, such that the level at the 56 day mark was approximately 4130 mg L^?1. In contrast, the artificial Atacama brine showed no pronounced Li precipitation, even after 54 days, at which point the Li concentration was 21,800 mg L^?1. The initial concentrations of Na and K in the Atacama brine were higher than those in the Uyuni brine, and the Atacama solution still retained K after 54 days of evaporation. The order of precipitation of cation species during the evaporation of both brines was: Na, followed by K, Mg, and Li. Thus, Li precipitation in the Atacama brine might be prevented due to the more favored precipitations of Na and K, such that significant Li removal did not occur in this brine.