3D alluvial aquifer reconstruction in polluted areas by means of GPR (Sabiñánigo,N Spain)

Assumptions of simple geometries for alluvial deposits (related to main rivers) can preclude determination of complexities that are revealed as fundamental controls in underground flow. Although subhorizontal contacts between alluvial and substratum materials are expected, previous sedimentary or erosional processes can result in irregular geometries, only accessible through detailed analysis. The studied case presents the 3D reconstruction of a Quaternary terrace in the proximities of Sabiñánigo (Southern Pyrenees, Northeastern Spain), lying on homogeneous Eocene marls. The studied area is located in an industrialized area supporting strongly pollutant chemical industry (chlorinated pesticides) for the past 50 years. The objective of the study was to constrain the groundwater pathway along the area to subsequently analyze leakage of chemicals to the water table. In order to reveal preferred flow paths, a detailed characterization of the internal structure of the alluvial deposits (0.5–13 m thick) and their relations with the Tertiary substratum was carried out by means of ground penetrating radar (GPR, 50 and 100 MHz antennas). The obtained models permit identifying several topographic highs in the alluvial/substratum contact, determining preferred pathways in water flow, favoring particular conditions associated with low levels of the water table. The presented results support the interest of application of GPR surveys in order to characterize the groundwater pathways in expected homogeneous areas and their importance in order to establish the contaminant surveillance network.     

Hydration shell structures in a LiI solution at elevated temperature and pressure: a molecular dynamics study

Molecular dynamics simulations of a 0.55 molal aqueous LiI solution have been performed at 508 K and 308 K and a density of 1.05 g/cm³. The structural changes resulting from increased temperature and pressure are discussed.     

Using a regional numerical weather prediction model for GNSS positioning over Brazil

The global navigation satellite system (GNSS) can provide centimeter positioning accuracy at low costs. However, in order to obtain the desired high accuracy, it is necessary to use high-quality atmospheric models. We focus on the troposphere, which is an important topic of research in Brazil where the tropospheric characteristics are unique, both spatially and temporally. There are dry regions, which lie mainly in the central part of the country. However, the most interesting area for the investigation of tropospheric models is the wet region which is located in the Amazon forest. This region substantially affects the variability of humidity over other regions of Brazil. It provides a large quantity of water vapor through the humidity convergence zone, especially for the southeast region. The interconnection and large fluxes of water vapor can generate serious deficiencies in tropospheric modeling. The CPTEC/INPE (Center for Weather Forecasting and Climate Studies/Brazilian Institute for Space Research) has been providing since July 2012 a numerical weather prediction (NWP) model for South America, known as Eta. It has yield excellent results in weather prediction but has not been used in GNSS positioning. This NWP model was evaluated in precise point positioning (PPP) and network-based positioning. Concerning PPP, the best positioning results were obtained for the station SAGA, located in Amazon region. Using the NWP model, the 3D RMS are less than 10 cm for all 24 h of data, whereas the values reach approximately 60 cm for the Hopfield model. For network-based positioning, the best results were obtained mainly when the tropospheric characteristics are critical, in which case an improvement of up to 7.2 % was obtained in 3D RMS using NWP models.     

Magnetic anisotropy of hematite natural crystals: high field experiments

Hematite is one of the most important carriers of remanent magnetization in natural samples. Its strong magnetocrystalline anisotropy makes it difficult to determine one single value for the magnetic anisotropy constant and other magnetic properties. In particular, the anisotropy of hematite within its basal plane is controversial because an assumed triaxial anisotropy compatible with the crystallographic structure has not always been detected. This study presents a comparative analysis of rock magnetic properties, compositional analysis and determination of the magnetic anisotropy constant. Different models with anisotropy constant within the basal plane ranging from 0 to 13 (J m⁻³) are considered in the evaluation of the factors that control the presence or absence of a triaxial anisotropy. A linear relationship between saturation magnetization (M _s ) and coercitivity (B _c ) in measurements at increasing temperatures is observed in samples where anisotropy is either uniaxial or biaxial while those with significant triaxial anisotropies have a power–law relationship between M _s and B _c .     

Genetic variability of wild Agave angustifolia populations based on AFLP: A basic study for conservation

Agave angustifolia is taken from wild populations in the desert of Sonora, Mexico, to make the alcoholic drink known as “bacanora”. An increase in the demand for this beverage has led to overexploitation of these agaves. We used AFLP to measure the genetic variability within and between natural populations of the species. The fixation index (FST) and population genetic distances (GD) were determined for three populations of A. angustifolia. At the clonal level, the expected heterozygosis (HE), the proportion of polymorphic loci (P), and the genetic similarity indices (GSIs) were lower in one population. Total GSI for adults and offshoots was 0.924. There were no differences in the GSI within or between the populations and dendrogram showed three groups that partially reflect the geographical distribution of the populations. Some degree of genetic variation between mother plants and their vegetatively produced rhizomes was observed. At the species level, total expected heterozygosity was high (HT = 0.314) with a P value of 78%, and intermediate gene flow (Nm = 1.18), giving rise to a moderate fixation index (FST = 0.175). Nm, FST and GD values observed, indicate that urgent measures must be implemented to preserve the genetic diversity.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.