Fluid inclusion study of the Wunugetu Cu–Mo deposit,Inner Mongolia,China

Hydrothermal alteration and mineralization at the Wunugetu porphyry Cu–Mo deposit, China, include four stages, i.e., the early stage characterized by quartz, K-feldspar and minor mineralization, followed by a molybdenum mineralization stage associated with potassic alteration, copper mineralization associated with sericitization, and the last Pb–Zn mineralization stage associated with carbonation. Hydrothermal quartz contains three types of fluid inclusions, namely aqueous (W-type), daughter mineral-bearing (S-type) and CO₂-rich (C-type) inclusion, with the latter two types absent in the late stage. Fluid inclusions in the early stage display homogenization temperatures above 510°C, with salinities up to 75.8 wt.% NaCl equivalent. The presence of S-type inclusions containing anhydrite and hematite daughter minerals and C-type inclusions indicates an oxidizing, CO₂-bearing environment. Fluid inclusions in the Mo- and Cu-mineralization stages yield homogenization temperatures of 342–508°C and 241–336°C, and salinities of 8.6–49.4 and 6.3–35.7 wt.% NaCl equivalent, respectively. The presence of chalcopyrite instead of hematite and anhydrite daughter minerals in S-type inclusions indicates a decreasing of oxygen fugacity. In the late stage, fluid inclusions yield homogenization temperatures of 115–234°C and salinities lower than 12.4 wt.% NaCl equivalent. It is concluded that the early stage fluids were CO₂ bearing, magmatic in origin, and characterized by high temperature, high salinity, and high oxygen fugacity. Phase separation occurred during the Mo- and Cu-mineralization stages, resulting in CO₂ release, oxygen fugacity decrease and rapid precipitation of sulfides. The late-stage fluids were meteoric in origin and characterized by low temperature, low salinity, and CO₂ poor.     

铜陵舒家店矿床年代学-地球化学特征及其意义

本文对铜陵舒家店辉石闪长岩开展了年代学和地球化学的系统研究。结果表明,舒家店辉石闪长岩的侵入年龄为140.5±1.4Ma,低于铜陵地区花岗闪长岩年龄。辉石闪长岩是矿床赋矿岩石,据此推测成矿时代也应该同为140.5Ma左右,或稍晚于岩浆岩侵位的时代。舒家店辉石闪长岩的地球化学特征表明其SiO2含量为50%左右,属于稍偏基性的岩类,并且具有大离子亲石元素(LILE:Ba,Sr,Th,Pb)的富集,而相对亏损高场强元素(HFSE:Zr,Nb,Hf),反映出该侵入岩的原始岩浆可能来源于受到了板片俯冲作用改造的富集地幔。舒家店岩体及铜金矿床形成的大地构造背景可能与古太平洋板块俯冲密切相关,位于大陆边缘岩浆弧的内陆一侧环境,它可能是俯冲洋壳部分熔融形成的熔体或流体交代地幔楔并使地幔楔发生部分熔融而形成的玄武质岩浆侵位到地壳浅部过程中混染了大量地壳物质而成。     

Geochemical anomaly structure of South Mining District of Fenghuangshan Copper Mine

To study the geochemical anomaly structure of multi-element associations in the South Mining District of the Fenghuangshan Copper Mine,samples were collected and analyzed for their trace element contents.Multi-element anomaly associations were divided according to the correlations between Cu and each of the other elements,and the distribution characteristics of multi-element anomaly associations were also described.Among them,the anomaly distribution of metallogenic element Cu indicates the environment of mineralization.This study provided the basis for research on the metallogenic prediction and geochemistry of the Fenghuangshan Copper Mine.     

Attitude estimation based on fusion of gyroscopes and single antenna GPS for small UAVs under the influence of vibration

An attitude estimation method is presented for small unmanned aerial vehicles (UAVs) powered by a piston engine which is the major source of vibration. Vibration of the engine significantly degrades the accuracy of the inertial measurement unit, especially for low-cost sensors that are based on micro electro-mechanical system. Therefore, a vibration model for a small UAV is proposed in order to examine the influence of vibration on attitude estimation with different sensors. The model is derived based on spectrum analysis with short-time Fourier transform. The vibration is compared with the drift of the gyroscope in order to examine the impact on attitude estimation. An attitude estimation method that fuses the gyroscopes and single antenna global positioning system (GPS) is proposed to mitigate the influence of engine vibration and gyroscope drift. The quaternion-based extended Kalman filter is implemented to fuse the sensors. This filter fuses the angular rates measured by the gyroscopes and the pseudo-attitude derived from the GPS velocity to estimate the attitude of the UAV. Simulations and experiment results indicate that the proposed method performs well both in short-term and long-term accuracy even though the gyroscopes are affected by drift and vibration noise, while the pseudo-attitude contains severe noise.     

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.     

Stochastic 1D site response analysis at a site in central Italy

Site response analysis is strongly influenced by the uncertainty associated to the definition of soil properties and model parameters. Deterministic, or even parametric analyses are unable to systematically assess such uncertainty, since the site characterisation can hardly be sufficiently accurate for a deterministic prediction of site response and alternative approaches are hence needed. A fully stochastic procedure for estimating the site amplification of ground motion is proposed and applied to a case study in central Italy. The methodology allows to take into account the record-to-record variability in an input ground motion and the uncertainty in dynamic soil properties and in the definition of the soil model. In particular, their effect on response spectra at the ground surface is evaluated.     

特提斯喜马拉雅带江孜地区古近纪地层源区分析——对造山带早期地壳加厚的制约

特提斯喜马拉雅北亚带江孜地区上古新统-下始新统甲查拉组记录了喜马拉雅碰撞造山带的早期地壳加厚和沉积历史。本文我们报道了甲查拉组详细的碎屑锆石U-Pb年龄和全岩Sm-Nd同位素数据。甲查拉组由青灰色厚层的岩屑砂岩夹泥岩组成,不整合覆盖在宗卓组之上,碎屑锆石主要的峰值介于350～80 Ma, 900～470 Ma以及1 300～950 Ma,次要的峰值介于2 800～1 500 Ma。全岩⁸⁷Sr/⁸⁶Sr介于0.707 505～0.713 174,¹⁴³Nd/¹⁴⁴Nd介于0.512 206～0.512 355,ε_Nd(0)介于-5.52～-8.43。甲查拉组物源区以再循环的日喀则弧前盆地和上三叠统郎杰学群为主,少量物质来自雅鲁藏布江缝合带。上述研究表明,甲查拉组沉积在周缘前陆盆地的背景下,且特提斯喜马拉雅北亚带在始新世期间经历了明显的地壳加厚。     

Removal of 2,4-dichlorophenol and pentachlorophenol from aqueous media by electrochemical process

Chlorophenols are persistent toxins in the natural environment. In this investigation, 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in aqueous media were degraded using an electrokinetic process (EK) and an electro-Fenton process (EF) using stainless steel and graphite as the anode and cathode, respectively. Chlorophenols were degraded via direct electrolysis at the surface of the electrode in the EK process. However, in the EF process, the degradation mechanism includes direct electrolysis and oxidation by hydroxyl radicals. The optimal conditions were a current density of 0.75 mA/cm² and an air flow of 0.7 l/min at pH 4. Under the optimal conditions, the 2,4-DCP and PCP removal rates in the EF process were 80.18 and 64.03 %, respectively. The mineralization efficiencies of 2,4-DCP and PCP were 78.23 and 75.77 %, respectively. The results of dechlorination reveal that almost all of the chlorines were released, but some were retained in the intermediates. The dechlorination efficiency revealed that the EF and EK4 processes two chlorines from 2,4-DCP. They released four or five chlorines and four chlorines from PCP, respectively. The kinetic results provide evidence of pseudo-first degradation. The rate constant (k _cp) declined as pH_i was increased from 4 to 10. The k _cp values reveal that the pH is an important factor that affects the degradation efficiency in the electrochemical process.     

Analysis of earthquake ground motions using an improved Hilbert–Huang transform

Some limitations of the Hilbert–Huang transform (HHT) for nonlinear and nonstationary signal processing are remarked. As an enhancement to the HHT, a time varying vector autoregressive moving average (VARMA) model based method is proposed to calculate the instantaneous frequencies of the intrinsic mode functions (IMFs) obtained from the empirical mode decomposition (EMD) of a signal. By representing the IMFs as time varying VARMA model and using the Kalman filter to estimate the time varying model parameters, the instantaneous frequencies are calculated according to the time varying parameters, then the instantaneous frequencies and the envelopes derived from the cubic spline interpolation of the maxima of IMFs are used to yield the Hilbert spectrum. The analysis of the length of day dataset and the ground motion record El Centro (1940, N–S) shows that the proposed method offers advantages in frequency resolution, and produces more physically meaningful and readable Hilbert spectrum than the original HHT method, short-time Fourier transform (STFT) and wavelet transform (WT). The analysis of the seismic response of a building during the 1994 Northridge earthquake shows that the proposed method is a powerful tool for structural damage detection, which is expected as the promising area for future research.     

Magma mingling in the Tungho area,Coastal Range of eastern Taiwan

Complex rocks, consisting of different lithologic breccias and sediments in the Tungho area of the southern Coastal Range, eastern Taiwan, were formed by magmas and magma–sediment mingling. Based on field occurrences, petrography, and mineral and rock compositions, three components including mafic magma, felsic magma, and sediments can be identified. The black breccias and white breccias were consolidated from mafic and felsic magma, respectively. Isotopic composition shows these two magmas may be from the same source. Compared to the white breccias, the black breccias show clast-supported structures, higher An values in plagioclase, higher contents of MgO, CaO, and Fe₂O₃ and lower SiO₂, greater enrichment in the light rare earth elements (LREE), and depletion in the heavy rare earth elements (HREE). The white breccias show matrix-supported blocks and mingling with tuffaceous sediments to form peperite. Physical and chemical evidence shows that the characteristics of these two components (mafic and felsic magmas) are still apparent in the mingled zone. According to their petrography, mafic and felsic magmas did not have much time for mingling. White intrusive structures and black flow structures show that mingling occurred before they solidified. Finally, the occurrence of mingling between magmas and sediments suggests that the mingling has taken place at the surface and not in the magma chamber.