THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

甚高频电磁波多参数层析成像技术及其应用研究

电磁波速度或衰减层析成像技术单独用于岩溶勘察存在多解性缺陷,降低了应用的准确性.基于电阻率和相对介电常数直接反映溶洞与周围介质存在的电性差异,以电磁波速度和衰减层析成像理论为基础,提出了电阻率和相对介电常数层析成像理论,并应用于实例工程.通过对其电磁波速度、衰减、相对介电常数、电阻率4参数层析成像结果进行对比分析和钻探验证,证明了基于电磁波的电阻率和相对介电常数层析成像技术是可行的,形成了电磁波速度、衰减、相对介电常数、电阻率多参数层析成像综合分析方法,提高了电磁波层析成像技术探测溶洞及其充填情况的准确性.     

新疆罗布泊地区凝结水试验

采用称重法,在高含盐量的罗布泊北部凹地首次进行了凝结水的野外监测,根据监测数据分析了罗布泊地区凝结水的生成规律.研究结果表明罗布泊存在凝结水;2005年7月、10月、12月3次监测时期里日均凝结水量分别为0.293,0.127,0.275 mm;凝结水来源于空气中的水气和深部土壤水分;发生的时间基本在晚上22∶00至次日凌晨8∶00;影响凝结水产生的主要因素为近地面大气温度与地表土壤温度差、空气相对湿度、冻结期等,土壤的高含盐量也有利于凝结水的生成.     

华北板块北缘东段陆缘活动带构造岩片划分及变质变形特征

1∶25万和龙市幅、汪清县幅等九幅区域地质调查成果显示,华北板块北缘东段残存着数条元古代-古生代不同时期的构造岩片,这些构造岩片均经历了强烈的变形改造及变质作用叠加,记录了增生型造山带在不同演化阶段热-动力学条件。吉林东部华北板块北缘陆缘活动带东段内元古代-古生代构造地层单位的确定,对探讨吉黑地区的大地构造演化具有重要意义。     

MAPGIS投影变换子系统的应用

介绍了利用MAPGIS投影变换子系统对地质勘查成果图件进行投影转换的方法步骤,同时用实例说明了不同坐标系之间投影转换过程中的参数选择,对计算机制图具有一定的借鉴作用。     

某矿山天然放射性核素的调查

对某矿山工作场所和生活区分别进行了样品采集,并使用ORTEC公司生产的16000道HPGeγ能谱仪进行了测量。结果表明,该矿山工作场所天然放射性核素的比活度大多高于生活区,其中危害最大的为尾矿坝;某些生活区天然放射性核素的比活度比对照点和国家均值要高,但多数都在国家均值范围内,最高值出现在3号生活区的农田土样中,其天然放射性核素的比活度分别为：α（226^Ra）——750．4Bq/kg、α（232^Th）——91．5Bq/kg、α（40^K）——1202Bq/kg。