Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Study on Polarized Spectral Characteristics of Soil with Different Water Content

Moisture is one of the important parameters in soil polarized spectrum. It has great significance in soil remote sensing band selection and image interpretation; it also provides the information for soil investigation and analysis on physical and chemical properties. In this paper we tested and analyzed the soil polarized spectrum with different moisture in 350?~?2,500 nm wavelength, to study on the relationship between soil polarized spectral data and moisture, to determine the spectral response and changes in soil moisture, and establish models between spectral data and soil moisture. We also designed a orthogonal test on the various factors that affect soil polarized spectral characteristics, in which we studied soil moisture, polarized angle, detected angle and azimuth of the various factors and their interactions. The results showed it was most significant that the soil moisture and the interaction of soil moisture and polarized angle, followed by the interaction effect of detected angle and moisture, while the polarized angle had a little impact on the soil polarized spectrum.     

Modeling the Population Effects of Hypoxia on Atlantic Croaker (<Emphasis Type="Italic">Micropogonias undulatus</Emphasis>) in the Northwestern Gulf of Mexico: Part 1—Model Description and Idealized Hypoxia

We developed a spatially explicit, individual-based model to analyze how hypoxia effects on reproduction, growth, and mortality of Atlantic croaker in the northwestern Gulf of Mexico lead to population-level responses. The model follows the hourly growth, mortality, reproduction, and movement of individuals on a 300 × 800 spatial grid of 1-km² cells for 140 years. Chlorophyll-a concentration, water temperature, and dissolved oxygen (DO) were specified daily for each grid cell and repeated for each year of the simulation. A bioenergetics model was used to represent growth, mortality was assumed stage- and age-dependent, and the movement behavior of juveniles and adults was modeled based on temperature and avoidance of low DO. Hypoxia effects were imposed using exposure effect submodels that converted time-varying exposures to low DO to reduced hourly growth, increased hourly mortality, and reduced annual fecundity. Results showed that 100 years of either mild or intermediate hypoxia produced small reductions in population abundance, while repeated severe hypoxia caused a 19% reduction in long-term population abundance. Relatively few individuals were exposed to low DO each hour, but many individuals experienced some exposure. The response was dominated by a 5% average reduction in annual fecundity of individuals. Under conditions of random sequences of mild, intermediate, and severe hypoxia years occurring in proportion to their historical frequency, the model predicted a 10% decrease in the long-term population abundance of croaker. A companion paper substitutes hourly DO values from a three-dimensional water quality model for the idealized hypoxia and results in a more realistic population reduction of about 25%.     

积极推进海域使用管理两项制度的落实

海域使用管理两项制度的推进,是国家海洋局2000年重点工作任务之一。在局党组的高度关注下,在海域管理司领导和全司同志的共同努力下,在财政部综合司的大力支持下,2000年海域使用管理工作成效显著,管理力度明显加大。 1 稳打稳扎,逐步贯彻落实海域使用管理的两项制度     

青海省都兰县果洛龙洼金矿成矿流体

果洛龙洼金矿是青海东昆仑地区最典型、最具规模的金矿床之一。在前人资料基础上,将果洛龙洼金矿热液成矿期划分为4个成矿阶段：贫矿化石英阶段、石英-多金属硫化物阶段（主要成矿阶段）、石英-贫硫化物阶段（次要成矿阶段）和石英-碳酸盐阶段。随后对主要和次要成矿阶段石英脉开展流体包裹体显微测温和H-O同位素研究。结果表明：原生流体包裹体主要包括气液两相、富CO₂三相、纯CO₂两相共3类;成矿流体总体以CO₂-NaCl-H₂O体系为主,均一温度为130.0~357.3 ℃,盐度（w(NaCl)）为1.83%~20.11%。石英-多金属硫化物阶段石英δ¹⁸O_V-SMOW值为14.8‰~17.2‰,据此计算流体的δ¹⁸O_H2O值为5.5‰~8.5‰,流体的δD_V-SMOW值为-61‰~-96‰;而石英-贫硫化物阶段石英δ¹⁸O_V-SMOW值为15.7‰~16.9‰,据此计算流体的δ¹⁸O_H2O值为4.1‰~5.3‰,流体的δD_V-SMOW值为-84‰~-101‰。由此认为：主要成矿阶段成矿流体可能为高温低盐度富CO₂变质热液和低温中高盐度岩浆热液两个端元组成的混合流体;次要成矿阶段成矿流体主要为混合后更均匀的中低温中低盐度热液,但后期明显有大气降水混入。总之,成矿流体的来源、性质及其演化等方面的研究结果进一步证明果洛龙洼金矿为造山型金矿。     

华南古岩溶型铀矿床矿物学及其矿床成因意义

华南古岩溶铀矿床的矿物学特征为:表生矿物发育,原生成矿矿物少见;矿化脉体几乎没有;矿石中铀主要呈吸附状态,其次呈显微和超显微沥青铀矿存在。与古岩溶有关铀矿床则出现典型低中温热液矿物组合,矿化脉体期次分明,矿石中铀基本呈可见状沥青矿存在,沥青铀矿具有热液成因标型。鉴于该类矿床成矿前主岩溶为冷水成因,而热液成矿流体是与岩溶无关的体系,故属古岩溶热液叠造成矿      

古炭屑与古森林火?

森林火普遍发生在地质历史时期中，它对自然植被系统的演替起着重要作用。不同强度和频率的森林火培育出不同类型的植被：频繁的森林火导致草甸的形成，而热带雨林形成的原因之一是森林火的缺乏。古炭屑作为古森林火的遗迹，具有分布广泛、细胞结构保存完好以及原地埋藏等特点，为研究古森林火发生的强度和频率提供了宝贵的材料。古炭屑的出现与当时的气候因素、植被类型和地理状况有密切关系：干旱、少雨的气候常常伴随高频率森林火的发生，表现出古炭屑的数量增多；易燃物种组成的植被易发生森林火，古炭屑的出现也会增多，而耐火树种会降低森林火的强度，古炭屑则出现少。因此，从古炭屑的数量和种类的变化，可探讨古森林火的发生规律，进而推断长期地质历史时期的气候、植被、地理状况的演变。     

A device for rainfall simulation in geotechnical centrifuges

Rainfall-induced slope instabilities are ubiquitous in nature, but simulation of this type of hazards with centrifuge modelling still poses difficulties. In this paper, we introduce a rainfall device for initiating slope failure in a medium-sized centrifuge. This rainfall system is simple, robust and affordable. An array of perforated hoses is placed close above the model slope surface to generate the raindrops. The rainfall intensity depends on the centrifuge acceleration and the flow rate of the water supply, which is controlled by the size and number of the tiny pinholes in the hose walls. The rainfall intensities that are tested range from 2.5–30 mm/h, covering the intensity range of moderate, heavy and torrential rainfall events. Our model test with rainfall-induced slope failure shows that this system is capable of generating relatively uniform rainfall of wide intensities and leads to various patterns of slope failure.

     

造山带中增生楔识别与地质意义

增生楔主要由海沟复理石、远洋—半远洋沉积和洋岛/海山等大洋板块地层岩石及蛇绿岩共同构成,是汇聚板块边缘古俯冲带构造—沉积作用的综合产物,以发育叠瓦状逆冲断层、双冲断层和紧闭—倒转褶皱,以及片理、碎裂构造、小型褶皱、膝折等不同尺度的构造为特征。增生楔组成包括连续单元和混杂岩两部分,严格受滑脱面位置控制。增生楔是增生型造山带最基本大地构造相,它与弧前盆地、岛弧/大陆边缘弧的时空配置关系可直接指示大洋板块俯冲极性、揭示洋盆演化与造山作用方式。准确识别增生楔,详细解剖其结构特征与组成特征,综合判别并恢复大洋板块地层,可为古板块边界与古大洋盆地消亡位置确定、造山带结构精细划分及造山作用过程重建提供基本依据。大比例尺地质填图是研究增生楔结构和组成、以及大洋板块地层重建的有效手段。以南祁连拉脊山石灰窑增生楔为例,地质填图结果表明它是由中寒武世—早奥陶世洋壳物质构成,自北而南依次可分为海沟—大洋盆地—海山OPS和六道沟SSZ型蛇绿岩,被南倾逆冲断层分割成多个岩片。海沟—大洋盆地OPS岩片基本保留完整地层序列,海山OPS岩片包括连续单元和混杂岩两部分。顶帽山增生楔主要由海山OPS构成,内部结构层序相对完好,是南祁连构造带中保留最为完整、规模最大的海山OPS岩石组合序列。上述不同类型OPS片段和六道沟SSZ型蛇绿岩组成的增生楔与其南侧岛弧带同时代。增生楔—岩浆弧的时空配置暗示寒武纪—早奥陶世时期原特提斯洋自北向南俯冲极性。这些认识为南祁连早古生代火山—岩浆—沉积构造演化以及是否存在古洋盆与古洋盆演化重建提供基本佐证。     

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.