Das „Randcenoman“ der Nördlichen Kalkalpen und seine Bedeutung für den Ablauf der ostalpinen Deckenüberschiebungen und ihrer Schubweiten

Zusammenfassung Das Randcenoman erstreckt sich über 220 km als ein der Cenoman-Serie zugehöriger Grenzbereich gegen die Flyschzone am Nordrand der Kalkalpen vom Chiemsee bis in das Große Walsertal.An einer Anzahl durchgehender Profile wurden stratigraphische und sedimentologische Untersuchungen durchgeführt.Nach Mikrofaunen konnten neue stratigraphische Belege für eine örtliche Sedimentationsfortsetzung ohne erkennbare Schichtunterbrechung vom Alb bis in das Cenoman gefunden werden. Hinweise auf unterturones Alter ergaben sich an zwei Stellen. Die alttertiären Tratenbachschichten sind tektonisch von Randcenoman und Flysch abgegrenzt.Trotz eines heterogenen Gesteinsaufbaus in vertikaler und horizontaler Ausdehnung mit einer differenzierten Wechsellagerung von Peliten, Psammiten und Psephiten zeigt die Cenoman-Serie petrographische Konstanz in Gefüge und Mineralzusammensetzung, besonders im Geröllspektrum und der Schwermineralassoziation (Chromit-SpinellPicotit).Die Gesteine des Randcenoman sind in einem einheitlichen Ablagerungsraum sedimentiert worden. Das gilt auch für ihre Anteile in der Arosa-Zone im Allgäu und im Bregenzer Wald.Faziesbeziehungen zur Flyschzone gibt es nicht.Auf das Ablagerungsmilieu deuten Flachwasserbildungen hin, die im flachen Randbereich der Geosynklinale während langdauernder Ruhigwasserfazies mit episodischen Unterbrechungen abgelagert wurden.Die petrographische Zusammensetzung der allothigenen Gerölle, ihr Rundungsgrad, ihre metamorphe Beanspruchung und ihr Erhaltungszustand lassen Analogieschlüsse mit Gesteinen vom Verrucano-Typ zu. Im Zusammenhang mit der Tonmineralführung der Pelite (Kaolinit) und der typischen Chromit-Spinell-Beteiligung kann auf ein breites Festland geschlossen werden. An der Detritusanlieferung sind neben dem mesozoischen kalkalpinen Untergrund und Gesteinen vom Verrucano-Typ Unterostalpin und Südpenninikum beteiligt. Damit sind die nördlichen Kalkalpen im Süden der Tauern beheimatet.Der Zeitraum der Überschiebung über das Penninikum liegt nicht vor Unterturon.Mittelkretazische Bewegungen werden in der Cenoman-Serie nur untergeordnet wirksam, wo sich Konglomerate und Geröllpsammite an der Wende Alb-Cenoman horizontieren lassen.

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The Randcenoman extends over a distance of 220 km as a boundary part of the Cenomanian Series along the alpine Flysch at the northern margin of the Limestone Alps from Chiem-See to the Grosses Walsertal.Series of continuous profiles have been investigated by stratigraphic and sedimentologic methods.By use of microfossils it could be proved that sedimentation lasted from Albian up to Cenomanian without visible interruption. At two different localities it was possible to find references to Turonian age.The Tratenbach layers of Tertiary age are separated tectonically from the Randcenoman and the Flysch.The rocks of Randcenoman show a very constant texture and association of minerals, especially in boulders and heavy minerals (chromite-spinel-picotite).These rocks must have been sedimented into an uniform trough. Same may be said concerning their contents within the Arosa-Zone in the Algovian region and in the Woods of Bregenz. There are no connections possible with facies of the Flysch series.Sediments of low water type show that these series have been deposed along the margin of the Alpine Geosyncline during long times of stagnant waters with episodical interruptions.The petrographic composition of the allothigenic boulders, their roundness, metamorphic stress and their state of conversation allows comparisons with rocks of the series of the Verrucano.The existance of a vast continent may be derived from the clay contents of the pelites (kaolinite) and the typical appearance of chromite-spinel minerals. The detritus has been delivered partly by the Lower Austroalpine unit and southern Penninicum, and by Mesozoic series of the Limestone Alps and rocks of Verrucano type.Concluding the origin of the Northern Limestone Alps has to be located south of the Tauern window.The movement of the Austroalpine nappes over the Penninicum cannot have happened before Lower Turonian age. The movements of Middle Cretaceous time are only of small efficiency on the series of Cenomanian where conglomerates and psammites containing boulders could be dated to be of Albanian-Cenomanian age.

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Résumé Le «Randcenomanien» s'étend sur 220 Km comme un ensemble-limite appartenant au Cénomanien, au contact de la zone du Flysch à la bordure Nord des Alpes calcaires, depuis le Lac de Chiem jusqu'à la «Grosse Walsertal»,L'auteur a effectué, le long d'un certain nombre de profils, des recherches stratigraphiques et sédimentologiques.A partir des microfaunes, on peut trouver de nouvelles preuves stratigraphiques en faveur d'une continuité de la sédimentation de l'Albien jusqu'au Cénomanien, sans aucune interruption reconnaissable. A deux endroits l'auteur a trouvé des indications concernant la présence du Turonien inférieur. Les couches du «Tratenbach» appartenant au Tertiaire inférieur sont séparées par voie tectonique du «Randcenomanien» et du Flysch.Malgré une constitution lithologique hétérogène, tant suivant la verticale que l'horizontale, avec des alternances bien marquées de pélites, psammites et pséphites, la série du Cénomanien montre une constance pétrographique quant à la texture et la composition minéralogique, spécialement dans la gamme des galets et l'association des minéraux lourds (Chromite-Spinelle-Picotite).Les roches du «Randcenomanien» ont été sédimentées dans un bassin uniforme; c'est aussi le cas dans la zone d'Arosa dans l'Allgäu et de la forêt de Bregenz.Il n'y a aucune connection avec les facies de la zone du Flysch.Quant au milieu de sédimentation, is est donné par les formations d'eaux profondes qui ont été déposées dans la région de bordure peu profonde du géosynclinal au cours de périodes de longue durée, en eau calme, avec seulement quelques interruptions épisodiques.La composition pétrographique des galets allothigènes, leur degré d'arrondi, leur degré de métamorphisme et leur état de conservation permettent de faire des analogies avec des roches du type Verrucano. Compte tenu aussi des minéraux argileux intervenant dans la constitution des pélites (kaolinite) et à la participation typique de la Chromite et du spinelle, on en arrive à la conclusion que le continent fournisseur de ces sédiments a été assez vaste. Aux apports détritiques du Mésozoïque inférieur des Alpes calcaires et des roches du type «Verrucano», sont venus s'ajouter ceux en provenance de l'Austroalpin inférieur et du Pennique méridional. C'est pourquoi le lieu d'origine des «Alpes calcaires» du Nord doit se trouver au sud des Tauern.Le chevauchement sur le Penninicum n'a pas eu lieu avant le Turonien inférieur.Les mouvements Crétacé inférieur dans le Cénomanien n'ont été que peu actifs, là où des conglomérats et des psammites à galets se sont épandus entre l'Albien et le Cénomanien.

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Randcenoman 220 , Chiem Große Valsertal. . . , . Tratenbach Randcenoman . , , , , , (- -). Randcenoman . Arosa Allgäu Bregenzer Wald. . . , , . , () - . , . . . Tauern. . , , / .

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Erweiterte Fassung eines am 25. Februar 1972 auf der 62. Jahrestagung der Geologischen Vereinigung in Frankfurt gehaltenen Vortrages.     

Oxide minerals in lithic fragments from Luna 20 fines

One hundred and seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvöspinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO₂-rich phase were also found.Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The $\text{Fe}\text{(Fe + Mg)}$ ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains.Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinzet al. (1973a).Sub-micron wide rods of metallic Fe occur in plagioclase grains and may have formed by sub-solidus reduction processes.     

Ferroan anorthosite: A widespread and distinctive lunar rock type

Eight of eleven Apollo 16 rake-sample anorthosites are very similar to each other, to hand-specimen Apollo 16 anorthosites, and to Apollo 15 anorthosites. They have feldspar An_96.6, both high- and low-Ca pyroxene with a restricted range of (low-magnesium) composition, minor olivine (～ Fo₆₀), traces of ilmenite and chromite, and originally coarse-grained, but now cataclastic texture. Such ferroan anorthosite is evidently a coherent, distinctive and widespread lunar rock type of cumulate origin which may not necessarily be very closely related genetically to other highland rock types.     

Drinking water production from surface water sources in the tropics: Brasília DF,Brazil

Drinking water production at three waterworks was evaluated with respect to variable weather conditions in the Brasília Distrito Federal. Results of the investigation revealed that seasonal variations in rainfall play an important role in influencing the quality of the surface water sources used for drinking water production in the district. In most surface sources, particles and apparent colour are likely to originate from erosion during rain events. This represents the primary challenge facing waterworks, notably when the raw water qualities of the sources to be treated at one facility differ by one order of magnitude, as well significantly varying from one season to the next. Treatment efficiencies in terms of turbidity, apparent colour and dissolved organic carbon (DOC) removal were evaluated. Drinking water quality was found to be significantly influenced by raw water quality at all considered treatment plants. With regard to DOC removal, treatment was most efficient in waterworks which treated raw water with high percentages of biopolymers and humics. Most dissolved organics were removed by coagulation. Finally, conclusions are drawn on how to better cope with challenges facing drinking water production in a tropical climate. The first of these recommendations is the introduction of online turbidity and dissolved organic matter monitoring in order to optimise the coagulation process for the removal of these two parameters. A combination of different coagulants could also be considered for this process. Additional more sophisticated improvements to process stability, such as determination of floc characteristics, introduction of artificial neural networks or the eventual upgrade of the treatment train using membrane filtration, are also suggested.     

Description of an aerodynamic levitation apparatus with applications in Earth sciences

Background  

In aerodynamic levitation, solids and liquids are floated in a vertical gas stream. In combination with CO₂-laser heating, containerless melting at high temperature of oxides and silicates is possible. We apply aerodynamic levitation to bulk rocks in preparation for microchemical analyses, and for evaporation and reduction experiments.     

Simulating coseismic deformation of quartz in the middle crust and fabric evolution during postseismic stress relaxation — An experimental study

Non-steady state deformation and annealing experiments on vein quartz are designed to simulate earthquake-driven episodic deformation in the middle crust. Three types of experiments were carried out using a modified Griggs-type solid medium deformation apparatus. All three start with high stress deformation at a temperature of 400 °C and a constant strain rate of 10^− 4 s^− 1 (type A), some are followed by annealing in the stability field of α-quartz for 14–15 h at zero nominal differential stress and temperatures of 800–1000 °C (type A + B), or by annealing for 15 h at 900 °C and at a residual stress (type A + C).The quartz samples reveal a very high strength > 2 GPa at a few percent of permanent strain. The microstructures after short-term high stress deformation (type A) record localized brittle and plastic deformation. Statisc annealing (type A + B) results in recrystallisation restricted to the highly damaged zones. The new grains aligned in strings and without crystallographic preferred orientation, indicate nucleation and growth. Annealing at non-hydrostatic conditions (type A + C) results in shear zones that also develop from deformation bands or cracks that formed during the preceding high stress deformation. In this case, however, the recrystallised zone is several grain diameters wide, the grains are elongate, and a marked crystallographic preferred orientation indicates flow by dislocation creep with dynamic recrystallisation. Quartz microstructures identical to those produced in type A + B experiments are observed in cores recovered from Long Valley Exploratory Well in the Quaternary Long Valley Caldera, California, with considerable seismic activity.The experiments demonstrate the behaviour of quartz at coseismic loading (type A) and subsequent static annealing (type A + B) or creep at decaying stress (type A + C) in the middle crust. The experimentally produced microfabrics allow to identify similar processes and conditions in exhumed rocks.     

Feldspathic clast populations in polymict ureilites: Stalking the missing basalts from the ureilite parent body

Polymict ureilites DaG 164/165, DaG 319, DaG 665, and EET 83309 are regolith breccias composed mainly of monomict ureilite-like material, but containing ∼2 vol% of feldspathic components. We characterized 171 feldspathic clasts in these meteorites in terms of texture, mineralogy, and mineral compositions. Based on this characterization we identified three populations of clasts, each of which appears to represent a common igneous (generally basaltic) lithology and whose mafic minerals show a normal igneous fractionation trend of near-constant Fe/Mn ratio over a range of Fe/Mg ratios that extend to much higher values than those in monomict ureilites. The melts represented by these populations are unlikely to be impact melts, because the ubiquitous presence of carbon in polymict ureilites (the regolith of the ureilite parent body) implies that impact melts would have crystallized under conditions of carbon redox control and therefore have highly magnesian mafic mineral compositions with constant Mn/Mg ratio. Therefore, these melts appear to be indigenous products of igneous differentiation on the ureilite parent body (UPB), complementary to the olivine-pigeonite residues represented by the majority of monomict ureilites.The most abundant population is characterized by albitic plagioclase in association with pyroxenes, phosphates, ilmenite, silica, and incompatible-element enriched glass. Model calculations suggest that it formed by extensive fractional crystallization of the earliest melt(s) of precursor materials from which the most magnesian (shallowest) olivine-pigeonite ureilites formed. A less abundant population, characterized by labradoritic plagioclase, may have formed from melts complementary to more ferroan olivine-pigeonite ureilites, and derived from deeper in the UPB. The third population, characterized by the presence of olivine and augite, could only have formed from melts produced at greater depths in the UPB than the olivine-pigeonite ureilites. Many other feldspathic clasts cannot be positively associated with any of these three populations, because their mafic mineral compositions exhibit carbon redox control. However, they may be products of early crystallization of basaltic melts produced on the UPB, before carbon was exhausted by reduction.Partial melting on the ureilite parent body was a fractional (or incremental) process. Melts were produced early in UPB history, and most likely extracted rapidly, thus preserving primitive chemical and oxygen isotopic signatures in the residues.