IV. Bücher- und Zeitschriftenschau

Ohne Zusammenfassung     

Assessing the potential for CO2 adsorption in a subbituminous coal,Huntly Coalfield,New Zealand,using small angle scattering techniques

Small angle scattering techniques (SAXS and SANS) have been used to investigate the microstructural properties of the subbituminous coals (R_max 0.42–0.45%) from the Huntly Coalfield, New Zealand. Samples were collected from the two thick (> 5 m) coal seams in the coalfield and have been analysed for methane and carbon dioxide sorption capacity, petrography, pore size distribution, specific surface area and porosity.Specific surface area (SSA) available for carbon dioxide adsorption, extrapolated to a probe size of 4 Å, ranged from 1.25 × 10⁶ cm^? 1 to 4.26 × 10⁶ cm^? 1 with total porosity varying from 16% to 25%. Porosity was found to be predominantly composed of microporosity, which contributed the majority of the available SSA. Although considerable variation was seen between samples, the results fit well with published rank trends.Gas holding capacity at the reservoir pressure (approximately 4 MPa) ranged from 2.63 to 4.18 m³/t for methane on a dry, ash-free basis (daf) and from 22.00 to 23.72 m³/t daf for carbon dioxide. The resulting ratio of CO₂:CH₄ ranged from 5.7 to 8.6, with an average of 6.7:1.Holding capacities for both methane and carbon dioxide on a dry ash free basis (daf) were found to be correlated with sample microporosity. However, holding capacities for the two gases on an as analysed (aa) basis (that is including mineral matter and moisture), showed no such correlation. Carbon dioxide (aa) does show a negative correlation with both specific surface area and microporosity. As the coals have low inorganic matter content, the reversal is thought to be related to moisture which is likely concentrated in the pore size range 12.5–125 Å. Methane holding capacity, both daf and aa, correlates with macroporosity, thus suggesting that the holding capacity of micropores is diminished by the presence of moisture in the pores.     

On the behaviour of liquefied soil

Engineering mechanics of liquefied soil is presented. Firstly, experimental methods and their results are described in order to show that liquefied soil can be approximated as a viscous fluid. The experiments proposed allow for determination of dynamic viscosity of liquefied soil, which is of the order of 10⁶ Ns/m². This value agrees with some theoretical estimates. Then, the model of viscous fluid is applied to practically important problems, in order to predict sinking of structures in liquefied subsoil, and to describe underwater flows of seabed. Enclosed examples show that the model and methods proposed lead to realistic results and, therefore, can be applied in engineering calculations.     

Are any granite landscapes distinctive of the humid tropics? Reconsidering multiconvex topographies

Geomorphologists have long debated over whether certain geomorphic types of landscapes may evolve only in certain climatic conditions, with granite terrains often chosen to illustrate such climate–relief relationships. The view deeming inselberg landscapes in particular to be distinctively tropical is difficult to sustain in the light of research demonstrating both the wide global distribution of inselbergs and evident rock control on their origins and development. However, another geomorphic type of granite landscapes has emerged as possibly specific to low latitude terrains, characterized by efficient deep weathering. In the context of the ongoing debate, this paper considers the case of multiconvex topography, consisting of low hills weathered throughout, which is widely distributed in South America, Africa and Southeast Asia but not yet reported from middle or high latitudes. Multiconvex landscapes require that weathering operates efficiently in all topographic settings and that dissection proceeds to maintain relative relief. Hence they tend to be associated with areas subject to moderate uplift. There is little chance for this type of relief to survive major environmental changes towards aridity or cooling because stripping of the weathering mantle will not be compensated by saprolite renewal.     

The Influence of Fluctuations of the Solar Emission Line Profileon the Doppler Shift of Interplanetary HLyα Lines Observed by the Hubble–Space–Telescope

In an earlier research the employment of a radiation transport model with angle-dependent partial frequency redistribution, self-absorption by interplanetary hydrogen, realistic solar H_Lyαemission profile, and a time dependent `hot' hydrogen model to analyze 5 interplanetary H_Lyα glow spectra obtained with theHubble–Space–Telescope–GHRS spectrometer, has not resulted in unequivocal determination of a set of thermodynamical parameters of the interstellar hydrogen The residual discrepancies between the model and the data concern the observations performed within an interval of 1 year close to the solar minimum from very similar lines of sight. In this paper we investigate by calculating interplanetary H_Lyα lines with the use of a one hydrogen distribution and several solar H_Lyα line profiles whether this residual may be caused by possible variations in time of the shape of the solar H_Lyα emission line profile which cause variable illuminations of the interplanetary gas. These variations of illuminations cause variations in Doppler shift of the resonant interplanetary H_Lyα line that can amount to ≃ 4 km s^-1in the line peak. Consequently we conclude that without adequate knowledge of the solar H_Lyα emission line profile during spectral observations of the interplanetary hydrogen gas it is impossible to obtain an agreement between models and observations better than by this value. This revised version was published online in July 2006 with corrections to the Cover Date.