Plastic Pollution at a Sea Turtle Conservation Area in NE Brazil: Contrasting Developed and Undeveloped Beaches

Sea turtles are highly susceptible to plastic ingestion and entanglement. Beach debris were surveyed along the most important sea turtle nesting beaches in Brazil (Costa dos Coqueiros, Bahia State). No significant differences among developed and undeveloped beaches were observed in terms of total number of items. Local sources (tourism activities) represented 70% of debris on developed beaches, where cigarette butts, straws, paper fragments, soft plastic fragments, and food packaging were the most abundant items. Non-local sources (domestic and fishing activities) accounted for about 70% of debris on undeveloped beaches, where the most abundant items were rigid plastic fragments, ropes, soft plastic fragments, caps, and polystyrene. The projected surface area of beach debris did not vary among developed and undeveloped beaches. Overseas containers accounted for about 25% of regional plastic pollution, implying that international pollution prevention agreements are not being respected off the Brazilian coast.     

Watered down? Civil society organizations and hydropower development in the Darjeeling and Sikkim regions,Eastern Himalaya: A comparative study

ABSTRACT

Mitigating climate change is often framed as the ultimate collective action problem of this era and great emphasis is made on the need for approaches that foster ‘cooperation’ and ‘consensus’. This paper argues that the irony of this rhetoric could not be more stark; climate policy framing is an exclusionary process, and climate mitigating interventions that are engineered essentially to address neoliberal economic concerns rather than environmental challenges are often the source of multiple new conflicts. In this regard, this paper shows how the response of local non governmental organisations (NGOs) to hydropower development in the Darjeeling region of West Bengal in the Eastern Himalayas bears evidence to Gramscian analyses of ‘the manufacture of consent’ between elite bourgeois actors – the state, formal civil society, political parties and the private sector. Such ‘associational’ unions are only occasionally interrupted, as in the case of the people’s movement, Affected Citizens of Teesta (ACT) in North Sikkim. Finding a balance between resistance and enabling political space to think and act differently, the movement led to the cancellation of several hydropower projects put forward in the name of climate mitigation, and in the process, drew attention to political processes involved in the manufacture of consent. Using case studies from the Darjeeling and Sikkim regions, this paper distinguishes between Gramsci’s vision of the political space of disruption vis-à-vis the covert agenda of climate consensus.

Key policy insights

• A politics of consensus in relation to climate change is an outcome of, and in turn reiterates, a narrowing of distance between the state and civil society.

• Including civil society in climate policy decision making and implementation is considered positive and inclusive, however, it is important to note that civil society is not always and everywhere inclusive and transformative.

• Both at global and national levels, it is claimed that climate change interventions happen in an overall framework of participatory, inclusive environmental governance; in relation to hydropower development, we note that this is hardly the practice on the ground.

     

Heat capacity studies of phase transitions in langbeinites II. K2Mg2(SO4)3

Heat capacity measurements have been made on a synthetic sample of langbeinite, K₂Mg₂(SO₄)₃, from 13 to 342 K in an adiabatic calorimeter. Three phase transitions, at 51.0, 54.9 and 63.8 K, have been observed in this material. Our study is the first to report the existence of such phase transitions in K₂Mg₂(S0₄)₃ and disputes predictions that none would take place below 77 K. Two models which have been proposed to explain the transition in potassium langbeinites are discussed in light of these results.     

Temporal dynamics of evapotranspiration in semiarid native forests in Brazil and Spain using remote sensing

Evapotranspiration (ET) plays an important role in integrated water resource planning, development and management. This process is particularly relevant in semiarid regions. The aim of this study is, hence, to compare spatial and temporal patterns of actual ET, as well as the temporal trends in two different semiarid forests, Caatinga (Brazil) and Tierra de Pinares (Spain). We used the surface energy balance algorithm for land (SEBAL) to assess actual evapotranspiration (ET_a) in both areas. In the Brazilian semiarid forest, Caatinga is the main vegetation, while it is Pinares in Spain. For this purpose, 69 Landsat-5 and 42 Landsat-8 images (1995–2019) were used. The Mann–Kendall test was applied to assess the occurrence of trends in precipitation, temperature and potential ET data; and the Temporal Stability Index (TSI) to know which areas have greater seasonal ET_a. The annual amplitude of the potential evapotranspiration (ET₀) is the same in both areas, however, the Caatinga values are higher. In the Caatinga forest, when ET₀ presents its highest values throughout the year, ET_a presents the lowest, and vice versa. In the Pinares forest, ET_a follows the ET₀ dynamics during the year, and the difference between ET₀ and ET_a is maximum during the summer. The Caatinga forest showed a greater spatial variation of ET_a than the Pinares forest as well as a greater extension with lower temporal stability of ET_a than the Pinares forest. Both the Caatinga forest and the Pinares forest showed significant positive trends in annual ET₀ and ET_a. We estimate that the value of ET_a increases more rapidly in Pinares than in the Brazilian Caatinga. Taking Caatinga as a hydrological mirror, some consequences are expected to Pinares, such as significant changes in the water balance, increase of biodiversity vulnerability, and reduction of water availability in soil and reservoirs.     

Characterization and evaluation of a tropical peat for the removal of Cr(VI) from solution

Tropical peat soils present higher ash content than those generated at temperate climate areas. Therefore, this study evaluated the characteristics of a Brazilian organic soil (OS), commercialized as peat, as well as its capacity in removing Cr(VI) from contaminated waters. The OS is composed of 35.5 wt% of organic matter and 56 wt% of inorganic fraction (ash), which is formed by minerals and phytoliths rich in silica (29.2 wt%) and alumina (23.6 wt%). The Cr(VI) removal tests were carried out in batch and column systems using OS and solutions of Cr(VI) prepared with distilled water and groundwater. Batch tests revealed that the organic substances in the OS caused the reduction of Cr(VI) to Cr(III), with an efficiency depending on solution pH. At pH 5.0 the Cr(VI) removal was 0.45 mg g^?1 in 24 h; whereas at pH 2.0, this removal increased to 1.10 mg g^?1. Since this redox reaction is very slow, the removal of Cr(VI) at pH 5.0 increased to around 2 mg g^?1 after 5 days. The removal of Cr(VI) was more effective in the column tests than in the batch test due to the greater solid/solution ratio, and their half-lives were 4.4 and 26.2 h, respectively. Chemical analysis indicated that Cr(VI) was reduced by the humic substances of OS, followed by the precipitation and/or adsorption of Cr(III) into the organic and inorganic components, as anatase. The presence of Cr(III) increased the stability of anatase structure, avoiding its transformation into rutile, even after being heated at 800 °C/2 h.     

Methane Production and Isotopic Fingerprinting in Ethanol Fuel Contaminated Sites

Biodegradation of organic compounds in groundwater can be a significant source of methane in contaminated sites. Methane might accumulate in indoor spaces posing a hazard. The increasing use of ethanol as a gasoline additive is a concern with respect to methane production since it is easily biodegraded and has a high oxygen demand, favoring the development of anaerobic conditions. This study evaluated the use of stable carbon isotopes to distinguish the methane origin between gasoline and ethanol biodegradation, and assessed the occurrence of methane in ethanol fuel contaminated sites. Two microcosm tests were performed under anaerobic conditions: one test using ethanol and the other using toluene as the sole carbon source. The isotopic tool was then applied to seven field sites known to be impacted by ethanol fuels. In the microcosm tests, it was verified that methane from ethanol (δ¹³C = −11.1‰) is more enriched in ¹³C, with δ¹³C values ranging from −20‰ to −30‰, while the methane from toluene (δ¹³C = −28.5‰) had a carbon isotopic signature of −55‰. The field samples had δ¹³C values varying over a wide range (−10‰ to −80‰), and the δ¹³C values allowed the methane source to be clearly identified in five of the seven ethanol/gasoline sites. In the other two sites, methane appears to have been produced from both sources. Both gasoline and ethanol were sources of methane in potentially hazardous concentrations and methane could be produced from organic acids originating from ethanol along the groundwater flow system even after all the ethanol has been completed biodegraded.     

A multi-scale particle-tracking framework for dispersive solute transport modeling

Particle-tracking simulation offers a fast and robust alternative to conventional numerical discretization techniques for modeling solute transport in subsurface formations. A common challenge is that the modeling scale is typically much larger than the volume scale over which measurements of rock properties are made, and the scale-up of measurements have to be made accounting for the pattern of spatial heterogeneity exhibited at different scales. In this paper, a statistical scale-up procedure developed in our previous work is adopted to estimate coarse-scale (effective) transition time functions for transport modeling, while two significant improvements are proposed: considering the effects of non-stationarity (trend), as well as unresolved (residual) heterogeneity below the fine-scale model. Rock property is modeled as a multivariate random function, which is decomposed into the sum of a trend (which is defined at the same resolution of the transport modeling scale) and a residual (representing all heterogeneities below the transport modeling scale). To construct realizations of a given rock property at the transport modeling scale, multiple realizations of the residual components are sampled. Next, a flow-based technique is adopted to compute the effective transport parameters: firstly, it is assumed that additional unresolved heterogeneities occurring below the fine scale can be described by a probabilistic transit time distribution; secondly, multiple realizations of the rock property, with the same physical size as the transport modeling scale, are generated; thirdly, each realization is subjected to particle-tracking simulation; finally, probability distributions of effective transition time function are estimated by matching the corresponding effluent history for each realization with an equivalent medium consisting of averaged homogeneous rock properties and aggregating results from all realizations. The proposed method is flexible that it does not invoke any explicit assumption regarding the multivariate distribution of the heterogeneity.     

U–Pb dating of granites in the Neoproterozoic Sergipano Belt,NE-Brazil: Implications for the timing and duration of continental collision and extrusion tectonics in the Borborema Province

The Sergipano Belt is the outcome of collision between the Pernambuco–Alagoas Massif and the São Francisco Craton during Neoproterozoic assembly of West Gondwana. Field relationships and U–Pb geochronology of granites intruded in garnet micaschists of the Macururé Domain are used to constrain the main collisional event (D₂) in the belt. The granites are divided into two groups, the pre-collisional granites (pre- to early-D₂) and the syn-collisional granites (syn- to tardi-D₂), the latter were emplaced as sheets along the S₂ axial plane foliation or they were collected at the hinge zones of F₂ folds. A U–Pb SHRIMP zircon age of 628 ± 12 Ma was obtained for the pre-collisional Camará tonalite. Two U–Pb TIMS titanite ages were obtained for the syn-collisional granites, 584 ± 10 Ma for the Angico granite and 571 ± 9 Ma for the Pedra Furada granite, and these ages are close to the garnet-whole rock Sm–Nd isochron of 570 Ma found for the peak of metamorphism in the Sergipano Belt. The ages of the Camará tonalite (628 Ma) and the Pedra Furada granite (571 Ma) mark respectively the maximum age for beginning of the D₂ event and minimum age for the end in the Macururé Domain. Using these ages, the main Neoproterozoic D₂ collisional event has been in operation in the Sergipano Belt for at least 57 million years. Correlation with coeval granitoids farther north in the Borborema Province indicate that while in the Sergipano Belt the syn-D₂ granites (ca. 590–570 Ma) were emplaced under compression, in the Borborema Province they emplaced under extensional conditions related to regional strike-slip shear zones. These contrasting emplacement settings for contemporaneous Neoproterozoic granitoids are explained by a combination of continent–continent collision and extrusion tectonics.     

Quantification of displacement and particle crushing around a penetrometer tip

Particle crushing occurs near the tip of a penetrometer and influences the development of the tip resistance.To study particle crushing near a penetrometer tip,a cone penetrometer was monotonically jacked and then load-tested in medium dense and dense silica sand samples prepared in a halfcylindrical calibration chamber with viewing windows.During the tests,images of the advancing penetrometer and the surrounding soil were taken using digital cameras and analyzed to obtain the displacement and strain fields around the penetrometer using the Digital Image Correlation(DIC)technique.Subsequently,soil samples were collected near the tip of the penetrometer using a novel agarimpregnation technique and digitized using an X-ray microscope.The digitized samples were analyzed to reconstruct the three-dimensional models of individual particles,generating the gradation and relative breakage parameters of the sand around the cone penetrometer.