Dissolved silica concentrations and reactions in pore waters from continental slope sediments offshore from Cape Hatteras, North Carolina, USA

The pore water concentrations of dissolved silica in sediment cores from the continental slope offshore from Cape Hatteras, North Carolina, varied from 150 to almost 700 μ,M with depth in the top 40 cm of sediment. Sediment cores from 630 to 2010 m depth had very similar profiles of dissolved silica in their pore waters, even though these cores came from regions greatly different in slope, topography, sedimentation rate, and abundance of benthic macrofauna. Cores from 474 to 525 m were more variable, both with respect to pore water dissolved silica profiles, and with respect to sediment texture. Experiments indicate that both the rate of dissolution of silica and the saturation concentration decrease as sediment depth below the sediment-seawater interface increases. These data are consistent with depletion of a reactive silica phase in surface sediment, which may be radiolarian tests, or the alteration of biogenic silica to a less reactive form over time. Experimental results suggest that the pore water dissolved silica concentration in sediments below the top few centimeters may be higher than the sediments could now achieve. The flux of dissolved silica out of these sediments is estimated to be 15 μmoles cm⁻² yr⁻¹.     

Evaluating prey capture by larval mummichogs (Fundulus heteroclitus) as a potential biomarker for contaminants

We evaluated larval prey capture as a "behavioral biomarker" of contamination by examining feeding behavior of larval mummichogs (Fundulus heteroclitus) from many different sites, including a severely contaminated "Superfund" site, moderately contaminated sites, and reference areas. Prey capture ability was related to sediment contaminant levels. The levels of contaminants at a site were highly correlated with each other, so that the impact of individual contaminants was confounded. The number of captures of brine shrimp by mummichog larvae from all sites was highly variable, but significant negative correlations of prey capture were seen with mercury, lead, zinc, cadmium, and PCBs. As observed previously with adults, polyaromatic hydrocarbons (PAHs) did not appear to impair prey capture ability. The only site in which prey capture rates of 8-day old larvae were severely affected was the most highly contaminated Superfund site, Berry's Creek, NJ. This implies that larval prey capture is not as sensitive a behavioral biomarker for contamination as adult behavior studied previously.     

Megabenthic diversity patterns and community structure of the Blanes submarine canyon and adjacent slope in the Northwestern Mediterranean: a human overprint?

The composition and structure of megabenthic communities in the Blanes canyon and adjacent open margin (Northwestern Mediterranean) were studied. The aim was to assess the effect of the canyon and commercial fishing intensity on the community composition and structure of benthic megafauna by (i) describing the megabenthic community composition, (ii) quantifying faunal abundance and biomass and (iii) describing community structure with MDS analyses and biodiversity indices. The results are compared between three sites (canyon head, canyon wall and open margin) located between 435 m and 700 m. Samples were collected using a commercial bottom trawl between April 2003 and March 2004. These sites are exploited by the local fishing fleet that targets the rose shrimp Aristeus antennatus . A total of 131 megabenthic species were identified from the three sites, with fishes and decapod crustaceans being the most speciose, most abundant and of higher biomass. The species richness, abundance and biomass of non-crustacean invertebrates were low. There were no significant differences in total abundance and biomass between the three sites. However, community structure analysis suggests that the open margin community is significantly different from the canyon head and canyon wall, with a lower species richness, lower diversity and lower evenness. The open margin community also reflects a higher degree of disturbance compared to the two canyon habitats. The results indicate that there is a canyon effect on the community structure of benthic megafauna, but this may be modulated by differing fishing pressure, which adds an additional factor to margin heterogeneity.     

HASSET: a probability event tree tool to evaluate future volcanic scenarios using Bayesian inference

Event tree structures constitute one of the most useful and necessary tools in modern volcanology for assessment of hazards from future volcanic scenarios (those that culminate in an eruptive event as well as those that do not). They are particularly relevant for evaluation of long- and short-term probabilities of occurrence of possible volcanic scenarios and their potential impacts on urbanized areas. In this paper, we introduce Hazard Assessment Event Tree (HASSET), a probability tool, built on an event tree structure that uses Bayesian inference to estimate the probability of occurrence of a future volcanic scenario and to evaluate the most relevant sources of uncertainty from the corresponding volcanic system. HASSET includes hazard assessment of noneruptive and nonmagmatic volcanic scenarios, that is, episodes of unrest that do not evolve into volcanic eruption but have an associated volcanic hazard (e.g., sector collapse and phreatic explosion), as well as unrest episodes triggered by external triggers rather than the magmatic system alone. Additionally, HASSET introduces the Delta method to assess precision of the probability estimates, by reporting a 1 standard deviation variability interval around the expected value for each scenario. HASSET is presented as a free software package in the form of a plug-in for the open source geographic information system Quantum Gis (QGIS), providing a graphically supported computation of the event tree structure in an interactive and user-friendly way. We also include further in-depth explanations for each node together with an application of HASSET to Teide-Pico Viejo volcanic complex (Spain).     

Maada’oonidiwag gete-dibaajimowen (“sharing old stories”): reflections on a place-based reparatory research partnership in Nbisiing Anishinaabeg Territory

In this paper, we reflect on an emerging community-based partnership rooted in place-based reparative research. Braiding knowledges (Atalay, 2012) from Nbisiing Anishinaabeg communities, northern Ontario universities, and multi-scalar museums, the partnership focuses on repatriation, reparative environmental histories, and action-based research in the context of settler colonialism and climate change. We reflect on ongoing projects that attempt to put Anishinaabe gikendaasowin (knowledge) into action alongside historical geographical research. We discuss how the partnership resonates with community geography values of relationship, collaboration, equity, and reciprocity, and urge non-Indigenous geographers to acknowledge how Indigenous knowledges and approaches have shaped these ideas long before geography became a discipline. We contend that historical geographers have a deeper role to play in community geography scholarship, citing examples of two projects related to (1) repatriation of Anishinaabeg cultural heritage and (2) storymapping through historical Geographic Information Systems (HGIS). However, we argue, geographers must continue to acknowledge their own positionality in a discipline that was built through settler colonial violence and knowledge production. Finally, we reflect on the role of academic institutions in facilitating First Nation-university-museum partnerships through access to funding, space, and databases, while addressing the challenges of relying on institutional support for reparatory and decolonizing projects.

     

History of sedimentary infilling and faulting in Subic Bay, Philippines revealed in high-resolution seismic reflection profiles

Subic Bay sediments and faults identified in seismic-reflection profiles were dated using sea-level curves. The oldest sedimentary packages are marine sediments subaerially exposed and eroded 20 ka. Fluvio-marine to wholly marine sediments were deposited during the ensuing transgression, and prograding units were deposited during stillstands or minor sea-level falls. Faults within the bay have three age ranges. The oldest set cuts through the pre-δ¹⁸O Stage 2 rock units, >18 ka; a second disrupts 10.2–11.3 ka sediments; and the youngest, which cut the uppermost sedimentary package, show that movements occurred about every 2 ky, most recently about 3 ka. Northwest–southeast faults that parallel onshore structures associated with Paleogene emplacement of the Zambales Ophiolite Complex to the west and north likely represent rejuvenated tectonism. The northern coastline and north–south-trending axial bay islands appear related to a lineament that dissects Mt Pinatubo farther northeast. A breach in the caldera of Mt Natib is the most likely source of a presumed pyroclastic deposit in the eastern bay that is associated with sediments about 11.3–18 ka, indicating that a Natib eruption occurred much more recently than previously documented for this volcano.     

Temporal Variability of Iron Speciation in Coastal Rainwater

Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)₂ ⁺(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented.