A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

地面臭氧的变化规律和计算方法的初步研究Ⅱ.可见光波段

通过对广州鼎湖山近地面O3、NOx、太阳辐射,气象参数等项目的观测和理论分析,研究了地面O3与NOx等微量气体及太阳可见光辐射的变化规律,详细讨论了可见光波段、不同天气条件地面O3与NOx、光化学反应、气溶胶、可见光辐射等之间复杂的关系.提出以光能量传输与守恒的观点来考虑大气中与可见光辐射有关的主要过程,并以此来研究大气光化学过程中所遵循的能量规律,建立了一个简单、实用、省时的统计模式,用于计算地面O3浓度.结果表明:不同情况下,计算值与观测值吻合得均比较一致.     

Trends in temperature extremes over nine integrated agricultural regions in China, 1961–2011

By characterizing the patterns of temperature extremes over nine integrated agricultural regions (IARs) in China from 1961 to 2011, this study performed trend analyses on 16 extreme temperature indices using a high-resolution (0.5° × 0.5°) daily gridded dataset and the Mann-Kendall method. The results show that annually, at both daytime and nighttime, cold extremes significantly decreased but warm extremes significantly increased across all IARs. Overall, nighttimes tended to warm faster than daytimes. Diurnal temperature ranges (DTR) diminished, apart from the mid-northern Southwest China Region and the mid-Loess Plateau Region. Seasonally, DTR widely diminished across all IARs during the four seasons except for spring. Higher minimum daily minimum temperature (TNn) and maximum daily maximum temperature (TXx), in both summer and winter, were recorded for most IARs except for the Huang-Huai-Hai Region; in autumn, all IARs generally encountered higher TNn and TXx. In all seasons, warming was observed at daytime and nighttime but, again, nighttimes warmed faster than daytimes. The results also indicate a more rapid warming trend in Northern and Western China than in Southern and Eastern China, with accelerated warming at high elevations. The increases in TNn and TXx might cause a reduction in agriculture yield in spring over Northern China, while such negative impact might occur in Southern China during summer. In autumn and winter, however, the negative impact possibly occurred in most of the IARs. Moreover, increased TXx in the Pearl River Delta and Yangtze River Delta is possibly related to rapid local urbanization. Climatically, the general increase in temperature extremes across Chinese IARs may be induced by strengthened Northern Hemisphere Subtropical High or weakened Northern Hemisphere Polar Vortex.

     

Evaluating the suitability of different terrains for sustaining human settlements according to the local elevation range in China using the ASTER GDEM

The topographical suitability assessment of human settlements(SAHS) creates a solid foundation for regional population distribution and socio-economic development. Local elevation range(LER) is an important factor that can be used to assess the suitability of different terrains for sustaining human settlements. However, current digital elevation model(DEM)-based LER products suffer from some challenges typically because of their subjectively selected neighborhood scales and coarser spatial resolution. In this study, we initially determined the optimal statistical window and then calculated the appropriate LER with the finer resolution data of the Advanced Spaceborne Thermal Emission and Reflection Radiometer Global DEM(ASTER GDEM) products for China. Then, the appropriate LER was used to evaluate the topographical SAHS and its correlations with the national gridded population distribution(1 km × 1 km) in 2010. The results show that the optimal statistical window for calculating a 1 arc-second(about 30 m) resolution GDEM LER for China can be determined using a 51 × 51 grid unit(width × height) within a rectangular neighborhood, corresponding to an area of about 2.34 km~2. Secondly, the LER values in the southern and western China were greater than those of the north and east, showing a trend which consistently reflects the general spatial features of landforms. Finally, the relationship between GDEM LER and population density was highly correlated with the R~2 value of 0.81. It showed that 85.22% of the Chinese population was located in areas where the LER is lower than 500 m. The topographically suitable area within China decreased from the southeastern coastal zone towards the northwestern inland areas due to transition from plains and basins to plateaus and mountains. The total area of moderate to high suitable level was 423.84 × 10~4 km~2, or 44.15% of the total land area, with 88.17% of the national population. Our study demonstrates the usefulness of appropriate LER in evaluating the topographical SAHS as well as its significant impact on population distribution.     

Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.     

On the circulation in the East Frisian Wadden Sea: numerical modeling and data analysis

 In this paper we use a combination of numerical modeling and data analysis to gain a better understanding of the major characteristics of the circulation in the East Frisian Wadden Sea. In particular, we concentrate on the asymmetry of the tidal wave and its modulation in the coastal area, which results in a complex pattern of responses to the sea-level forcing from the North Sea. The numerical simulations are based on the 3-D primitive equation General Estuarine Transport Model (GETM) with a horizontal resolution of 200 m and terrain-following vertical coordinates. The model is forced at its open boundaries with sea-level data from an operational model for the German Bight (German Hydrographic Office). The validation data for our model simulations include time series of tidal gauge data and surface currents measured at a pile in the back-barrier basin of the Island Langeoog, as well as several ADCP transects in the Accumer Ee tidal inlet. Circulation and turbulence characteristics are investigated for typical situations driven by spring and neap tides, and the analysis is focused on dominating temporal and spatial patterns. By investigating the response of five back-barrier basins with rather different morphologies to external forcing, an attempt is made to elucidate the dominating physical balances controlling the circulation in the individual sub-basins. It is demonstrated that the friction at the seabed tends to slow down the tidal signal in the shallow water. This leads to the establishment of flood dominance in the shallow sea north of the barrier islands. South of the islands, where the water volume of the channels at low tide is smaller than the tidal prism, the asymmetry of the tidal signal is shifted towards ebb dominance, a feature which is particularly pronounced at spring tide. At the northern open boundary, the tidal wave propagating from west to east generates a sea-level difference of ∼1 m along the boundary, and thereby triggers vigorous alongshore currents. The frictional control in the model is located in the inlets, as well as along the northern boundary. The correlation between velocity and turbulent kinetic energy tends to the establishment of a net southward transport, giving theoretical support to the observed accumulation of sediments on the intertidal flats. Weak turbulence along the northern shores of the barrier islands and the small magnitude of the residual currents there promote accumulation of suspended matter in these areas, although wave action will generally counteract this effect. Received: 29 May 2002 / Accepted: 26 September 2002 Responsible Editor: Jean-Marie Beckers Acknowledgements We are indebted to S. Dick for providing the data from the operational model of BSH and to B. Flemming for the useful discussions. The topography data and Fig. 1 have been prepared in cooperation with F. Meyer. Figure 2 has been prepared by G. Brink-Spalink. We also thank for the comments from an anonymous reviewer which helped to improve our paper.     

Prediction of the Earlier Strong Aftershocks in the Earthquake Sequences by the Pseudo-Periodicity Method

We propose the pseudo-periodicity method and its quantitative prediction indexes for the occurrence time of earlier strong aftershock. We conducted tests of regressive prediction, and the R-value of the tests is 0.45, indicating that this method is effective for prediction.     

Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering,provenance, and tectonic setting

The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si₂O versus K₂O/Na₂O tectonic setting diagram.     

Geochemistry of ophiolite cherts from the Qinling orogenic belt and implications for their tectonic settings

Since the 1980s, one of the important progresses in the study of the Qinling orogenic belt is marked by findings of numerous ophiolite zones[1—4]. On the basis of the former orogenic models of the Paleozoic colli-sional orogeny[1,5,6] and the Mesozoic collision[7—9], another orogenic evolution model from the Paleozoic subduction-collision along the Shangdan suture to the Mesozoic final collision orogeny along the Mianle suture[3,10], including the relicts of the Jining orogeny, has been pr…     

雾探测器现场对比试验方法研究

简单介绍了WT-1型雾探测器的结构和现场试验情况，对试验期间(2001年12月1日至2002年5月31日)所获取的数据进行了统计分析，计算了试验期间雾探测器数据的缺测率、与人工观测数据及芬兰同类产品的测量结果之间的相关系数，三者之间的相符率，以及数据随时间的变化趋势。以数据处理结果为依据，客观地阐述了雾探测器的优缺点，以及与目前世界上普遍认可的芬兰能见度仪之间的差距，同时也提出了雾探测器改进的一些建议。