Estimation of the <Emphasis Type="Italic">in situ</Emphasis> Ultraviolet-A absorption of seawater by a simple irradiance inversion model

An irradiance inversion model to estimate the in situ absorption coefficient of seawater has been developed for the Ultraviolet-A (UVA) wavelength domain. Input parameters are sun angle and the up-and downward planar irradiances measured for at least two depths. The present method does not require seawater to be sampled, and is a discrete wavelength method which returns the absorption coefficient at a given wavelength from the irradiances measured at that wavelength without assuming a spectral shape of any optical properties a priori. Comparison between the model results and spectrophotometric measurements shows that the model is practically useful when cloud cover in the atmosphere is ≤ 50%. According to the present method, measurements of the irradiances enable simultaneous observation of the in situ underwater UVA radiation level and the absorption capacity of bulk seawater using a radiometer.     

Reevaluation of historical ocean heat content variations with time-varying XBT and MBT depth bias corrections

As reported in former studies, temperature observations obtained by expendable bathythermographs (XBTs) and mechanical bathythermographs (MBTs) appear to have positive biases as much as they affect major climate signals. These biases have not been fully taken into account in previous ocean temperature analyses, which have been widely used to detect global warming signals in the oceans. This report proposes a methodology for directly eliminating the biases from the XBT and MBT observations. In the case of XBT observation, assuming that the positive temperature biases mainly originate from greater depths given by conventional XBT fall-rate equations than the truth, a depth bias equation is constructed by fitting depth differences between XBT data and more accurate oceanographic observations to a linear equation of elapsed time. Such depth bias equations are introduced separately for each year and for each probe type. Uncertainty in the gradient of the linear equation is evaluated using a non-parametric test. The typical depth bias is +10 m at 700 m depth on average, which is probably caused by various indeterminable sources of error in the XBT observations as well as a lack of representativeness in the fall-rate equations adopted so far. Depth biases in MBT are fitted to quadratic equations of depth in a similar manner to the XBT method. Correcting the historical XBT and MBT depth biases by these equations allows a historical ocean temperature analysis to be conducted. In comparison with the previous temperature analysis, large differences are found in the present analysis as follows: the duration of large ocean heat content in the 1970s shortens dramatically, and recent ocean cooling becomes insignificant. The result is also in better agreement with tide gauge observations. On leave from the Meteorological Research Institute of the Japan Meteorological Agency.     

Composition of the phytoplankton pigments in the surface waters along a transect from the Northwestern to the southeastern Pacific Ocean

Multidisciplinary oceanic investigation was undertaken in Aug–Sep. 2003 along a transect from Northwestern (Busan, Korea) to Southeastern Pacific (Talcahuano, Chile) to understand the physical, chemical and biological features in the surface water, and to depict their interaction with the atmosphere. Among the twenty parameters measured, we describe the physical, chemical and biological features. Physico-chemical data were analyzed in conjunction with the geographic position and yielded 7 peculiar surface water masses. The first water mass (28.4°N, 130.8°E to 21.5°N, 139.5°E) was warm and low in phosphate and nitrate content, and high in silicate. The concentration of phytoplankton pigment was one of the lowest. The second (20.4°N, 140.7°E to 2.2°S, 162.9°E) was the warmest and the least saline. Nitrate and phosphate concentration were one of the lowest. Chlorophyll a (Chl a) concentration was the lowest among the surface waters. The third (3.4°S, 164.0°E to 14.5°S, 173.3°E) was warm. Nitrate concentration was the lowest. CHL-a, peridinin (Perid), violaxanthin (Viola), zeaxanthin (Zea), chlorophyll-b (Chl b) and β-CAR were abundant. The fourth (18.6°S, 177.5°E to 31.8°S, 123.9°W) was saline and poor in nutrient concentration. The contributions of 19′-butanoyloxyfucoxanthin (But-fuco), 19′-hexanoyloxyfucoxanthin (Hex-fuco), and CHL b to CHL a were non-negligible. The fifth (32.4°S, 122.1°W to 33.8°S, 117.2°W) was relatively cold and well oxygenated. Concentration of Fuco, But-fuco, Hex-fuco and Chl b was high. The sixth (34.2°S, 115.4°W to 37.4°S, 92.1°W) was cold, well oxygenated and enriched with phosphate and nitrate. Concentration of phytoplankton pigment was, however, one of the lowest. The seventh, located off the Chilean coast, from 37.2°S, 87.2°W to 36.1°S, 74.1°W was well oxygenated and highly enriched with nitrate and phosphate. Phytoplankton pigments such as Fuco, Perid, But-fico, and Hex-fuco were rich. The 7 surface water masses are partially attributed to Kuroshio Current, North Equatorial Current and North Equatorial Countercurrent, South Equatorial current, South Pacific Subtropical Gyre, South Pacific Current, Subtropical Front and Chilean coastal water. The differences in physicochemical characteristics and the history of the surface water resulted in difference in quantity and composition of the phytoplankton pigment.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Effects of mass source/sink at the western boundary on the wind-driven gyres: Implications for the ventilation of the north pacific intermediate layer through convection in the Okhotsk Sea and tidal mixing at the Kuril Straits

A steady quasi-geostrophic 2.5-layer model, forced by both Ekman pumping and a mass source/sink situated at the western boundary has been constructed to investigate the effect of diapycnal transport due to convection in the Okhotsk Sea and tidal mixing at the Kuril Straits on the intermediate layer in the North Pacific. The model illustrates a combined effect of the wind-driven and mass-driven circulations. First, net mass input induces a “barotropic” mode inter-gyre flow along the western boundary through the dynamical influence of Kelvin waves. This flow creates characteristic curves (geostrophic contours) that facilitate inter-gyre communication through the western boundary layer from the location of the mass source to the subtropical gyre. Due to the effect of wind-driven circulation, the offshore part turns eastward into the interior, encircles the outer rim of the region (which would otherwise be the pool region in the absence of mass input), and then encounters the western boundary. Eventually, the water fed into the lower layer flows mostly along this path and later flows away to the equatorial region. Conversely, in the upper layer, water is fed from the equator to the subtropics, and to the subpolar interior region through the western boundary current. The water then circulates along the outer rim and is absorbed into the mass sink. The model is controlled mainly by three nondimensional parameters: (1) the ratio of net mass input rate to the maximum Sverdrup transport (Q/T _Sv ^max ), which affects the inter-gyre communication by altering the paths of geostrophic contours, (2) the ratio of a mass input rate into the lower layer to that in total (Q ₂/Q), which controls the vertical structure of the inter-gyre flow, and (3) the measure of the wind forcing effect relative to the β effect, which determines the horizontal extent of the area influenced by the mass input. The other parameter regimes with respect to Q/T _Sv ^max and Q ₂/Q are also presented.     

褐藻多酚合成的模拟研究

褐藻多酚是间苯三酚的聚合物,结构复杂,有关生物合成途径方面的研究报道甚少。近年发现,褐藻多酚具有多种生物活性和医药价值(Ragan & Glombitza,1986),因此，研究褐藻多酚的人工合成不仅可模似研究褐藻多酚的生物合成过程,而且为寻找替代自然资源打下了基础。 作者在实验中观察到配制的间苯三酚溶液放置一段时间后会逐渐发黄,因此认为间苯三酚在放置过程中发生了氧化聚合,并对此作了进一步研究。     

Truss Spar平台在波流联合作用下运动响应预报方法比较

基于细长体水动力模型比较了Truss Spar平台在波流联合作用下运动响应预报的三种方法。分别采用波流耦合、速度叠加及力叠加计算Truss Spar平台在波流联合作用下的水动力载荷,根据流场水质点运动规律和Truss Spar外部形状特点,分段高效计算水动力载荷。利用Runge-Kutta-Fehlberg方法求解刚体非线性运动方程得Truss Spar在波流场中的运动响应。研究结果表明力叠加法所预报的Truss Spar纵荡和纵摇运动明显大于其他两种方法的相应运动响应预报结果,而波流耦合法与速度叠加法所预报的纵荡与纵摇运动响应幅值相当,三种方法所预报的垂荡运动响应的大小取决于具体波流参数。     

Experimental Study on Sloshing Characteristics in the Elastic Tank Based on Morlet Wavelet Transform

Hydroelastic effect of sloshing is studied through an experimental investigation. Different excitation frequencies are considered with low-fill-depth and large amplitude. Morlet wavelet transform is introduced to analyze the free surface elevations and sloshing pressures. It focuses on variations and distributions of the wavelet energy in elastic tanks. The evolutions of theoretical and experimental wavelet spectra are discussed and the corresponding Fourier spectrums are compared. Afterwards, average values of the wavelet spectra are extracted to do a quantitative study at various points. From the wavelet analysis, sloshing energies are mainly distributed around the external excitation frequency and expanded to high frequencies under violent condition. In resonance, experimental wavelet energy of the elevation in elastic tanks is obviously less than that in the rigid one; for sloshing pressures, the elastic wavelet energy close to the rigid one and conspicuous impulse is observed. It recommends engineers to concern the primary natural frequency and impulsive peak pressures.     

Effect of upward internal flow on dynamics of riser model subject to shear current

Numerical study about vortex-induced vibration(VIV) related to a flexible riser model in consideration of internal flow progressing inside has been performed.The main objective of this work is to investigate the coupled fluid-structure interaction(FSI) taking place between tensioned riser model,external shear current and upward-progressing internal flow(from ocean bottom to surface).A CAE technology behind the current research which combines structural software with the CFD technology has been proposed.According to the result from dynamic analysis,it has been found that the existence of upward-progressing internal flow does play an important role in determining the vibration mode(/dominant frequency),vibration intensity and the magnitude of instantaneous vibration amplitude,when the velocity ratio of internal flow against external current is relatively high.As a rule,the larger the velocity of internal flow is,the more it contributes to the dynamic vibration response of the flexible riser model.In addition,multi-modal vibration phenomenon has been widely observed,for asymmetric curvature along the riser span emerges in the case of external shear current being imposed.     

Authigenic iron oxide formation in the estuarine mixing zone of the Yangtze River

Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.