Magma evolution beneath Bequia,Lesser Antilles,deduced from petrology of lavas and plutonic xenoliths

Extrusive and intrusive igneous rocks represent different parts of a magmatic system and ultimately provide complementary information about the processes operating beneath volcanoes. To shed light on such processes, we have examined and quantified the textures and mineral compositions of plutonic and cumulate xenoliths and lavas from Bequia, Lesser Antilles arc. Both suites contain assemblages of iddingsitized olivine, plagioclase, clinopyroxene and spinel with rare orthopyroxene and ilmenite. Mineral zoning is widespread, but more protracted in lavas than xenoliths. Plagioclase cores and olivine have high anorthite (An?≤?98) and low forsterite (Fo?≤?84) compositions respectively, implying crystallisation from a hydrous mafic melt that was already fractionated. Xenolith textures range from adcumulate to orthocumulate with variable mineral crystallisation sequences. Textural criteria are used to organize the xenoliths into six groups. Amphibole, notably absent from lavas, is a common feature of xenoliths, together with minor biotite and apatite. Bulk compositions of xenoliths deviate from the liquid line of descent of lavas supporting a cumulate origin with varying degrees of reactive infiltration by evolved hydrous melts, preserved as melt inclusions in xenolith crystals. Volatile saturation pressures in melt inclusions indicate cumulate crystallization over a 162–571 MPa pressure range under conditions of high dissolved water contents (up to 7.8 wt% H₂O), consistent with a variety of other thermobarometric estimates. Phase assemblages of xenoliths are consistent with published experimental data on volatile-saturated low-magnesium and high-alumina basalts and basaltic andesite from the Lesser Antilles at pressures of 200–1000 MPa, temperatures of 950–1050 °C and dissolved H₂O contents of 4–7 wt%. Once extracted from mid-crustal mushes, residual melts ascend to higher levels and undergo H₂O-saturated crystallization in shallow, pre-eruptive reservoirs to form phenocrysts and glomerocrysts. The absence of amphibole from lavas reflects instability at low pressures, whereas its abundance in xenoliths testifies to its importance in mid-crustal differentiation processes. A complex, vertically extensive (6 to at least 21 km depth) magmatic system is inferred beneath Bequia. Xenoliths represent fragments of the mush incorporated into ascending magmas. The widespread occurrence of evolved melts in the mush, but the absence of erupted evolved magmas, in contrast to islands in the northern Lesser Antilles, may reflect the relative immaturity of the Bequia magmatic system.     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).     

Crystal nucleation and growth produced by continuous decompression of Pinatubo magma

High-temperature decompression experiments demonstrate that crystal textures preserve a record of the style and rate of magmatic ascent. To reinforce this link, we performed a suite of isothermal decompression experiments using starting material from the climactic 1991 Pinatubo eruption. We decompressed experiments from 220 MPa to final, quench pressures of 75 or 30 MPa using continuous decompression rates of 100, 30, 10, 3, 1, and 0.3 MPa h^?1. Amphibole, clinopyroxene, and plagioclase crystallized during the experiments, with plagioclase microlites dominating the assemblage. Total microlite number densities range from 10^7.6±0.4 up to 10^8.2±0.2 cm^?3, with plagioclase accounting for up to 65% of the total number. Plagioclase microlite area increased systematically from 19?±?8 to 937?±?487 µm² with increasing experiment duration. Our textures provide time-integrated records of crystal kinetics. Average nucleation and areal growth rates of plagioclase are highest in the fastest decompressions (~?10^7.5 cm^?3 h^?1 and 10.1?±?4.1 µm² h^?1, respectively) and more than an order of magnitude lower in the slowest experiments (~?10^5.5 cm^?3 h^?1 and 0.8?±?0.2 µm² h^?1, respectively). Both nucleation and growth rates are highest at high degrees of disequilibrium. We find that peak supersaturation-dependent instantaneous rates are generally more than an order of magnitude faster than average rates. We use those instantaneous nucleation and growth rates to introduce an iterative model to evaluate the effects of different decompression rates, decompression paths (continuous, single-step or multistep), and the presence of phenocrysts on final crystallinity and microlite size distribution.     

Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.     

The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.     

蚌埠隆起老山片麻状二长花岗岩的成岩与变质特征及其地质意义

蚌埠隆起是华北地块上中生代地质研究的一个十分难得的地质单元,它映现了中国东部最重要的两次构造运动(印支运动和燕山运动)所引起的岩浆作用和变质作用,其中,老山片麻状二长花岗岩就是一个代表性产物。该花岗岩的岩相学、地球化学以及锆石学的系统研究显示,它具有两个不同的岩石学特征:①它的斜长石斑晶的牌号(An_(14～18))、相对低硅高钙的主量元素、富Ba、Sr和贫Rb及无Eu负异常的微量元素等特征,以及它所含的岩浆锆石({211}锥面发育、较强的CL亮度及韵律环带构造、包含残核、正常的Hf含量)的U-Pb年龄(223.1 Ma)和ε_(Hf)(t)值(平均值为-14.2),表明它应该是印支运动的同造山花岗岩;②它的片麻状构造(斑晶矿物压扁拉长、各种交代—熔蚀结构)和变质结晶锆石({101}锥面发育、较弱的CL亮度、较高的Hf含量)的U-Pb年龄(156.2 Ma)和ε_(Hf)(t)值(平均值为-17.8),说明它在燕山运动中遭受了同造山变质作用。因此,老山片麻状二长花岗岩的存在,一方面使得大别造山带作为印支期陆陆碰撞造山带的岩石学记录完整,同时也制约了华南与华北两大板块之间碰撞挤压作用峰期的准确时间;另一方面,对燕山运动的起始时间(约170 Ma左右)和挤压高峰出现的时间(155±3 Ma)作出了合理的推断。这两方面的研究结果对于深入了解中国东部中生代的构造演化、岩石类型、成矿作用的现象及其机制具有深远的意义。     

Two Phases of Mineralization in the Dabaoshan Polymetallic Deposit,Guangdong Province: Constraints from Re-Os Geochronology of Black Carbonaceous Mudstone and MolybdeniteEI北大核心CSCD

The Dabaoshan polymetallic deposit is a polygenetic composite ore deposit located at south of the Qinhang (Qinzhou-Hangzhou) Metallogenic Belt, which is composed mainly of SEDEX type Cu-Pb-Zn and porphyry-skarn type W-Mo orebodies. Systematic field study shows that the W-Mo mineralization exhibits as quartz-vein type and skarn type orebodies around the granodioritic porphyry, or superimposes on the SEDEX type Cu-Pb-Zn orebody, while the Cu-Pb-Zn mineralization occurs mainly in the Qiziqiao Formation as stratiform-substratiform type and breccia type orebodies with typical SEDEX-type characteristics. Re-Os dating of five molybdenite separates from porphyry-skarn type W-Mo orebodies yielded isochron ages of 163.6±1.0 Ma (MSWD=0.58), which represents the age of W-Mo mineralization. Re-Os dating of seven black carbonaceous mudstone samples from a Cu-Pb-Zn orebody yielded isochron age of 387.6±9.9 Ma (MSWD=56), which is interpreted to be the age of SEDEX-type Cu-Pb-Zn mineralization. These ages indicate that there are at least two stages of ore mineralization in the Dabaoshan polymetallic deposit. The W-Mo mineralization is related to the Yanshanian intermediated-acidic intrusions, while the stratiform-substratiform SEDEX-type Cu-Pb-Zn mineralization is associated with the Hercynian seafloor hydrothermal activities. © 2018, Science Press. All right reserved.     

Spatio-temporal Distribution of Three Kinds of Flash Droughts over Agricultural Land in China from 1983 to 2015

At present, flash drought occurs globally and regionally and causes a lot of socio-economic loss in a very short time. Therefore, flash drought has been regarded as one of the hottest issues in drought research. However, flash drought monitoring, prediction and decision-making have encountered a lot of challenges due to its multiple driven factors and complex spatio-temporal process. Aiming at this problem, this paper focused on the agricultural land in China, and analyzed the spatio-temporal distribution of three kinds of flash droughts (i.e., precipitation-deficit, high-temperature, and composite flash droughts) from 1983 to 2015. We studied the occurrences, duration, spatial distribution, temporal distribution, and trend of all three kinds of flash droughts. Our results demonstrated that, the occurrences of flash drought agricultural land in China increased year by year, among which high-temperature flash drought increased dramatically; duration of flash droughts had different trends, but the variations were relatively smooth; Northeast China was identified as a vulnerable area of flash drought, indicating more flash drought events and longer duration; flash droughts in China were found to concentrate in spring (high-temperature drought) and summer seasons (precipitation-deficit drought). This study is helpful for building new flash drought monitoring method and system, and it is also valuable for flash drought preparedness on regional scale.     

新时代地热行业发展特点及几点思考

当前,中国特色社会主义进入了新时代,社会各项建设取得重大成就,地热产业也发展壮大。在大力倡导生态文明建设、推进绿色发展、提升环境保护、推进资源的节约和循环利用的社会发展形势下,一些重要规划和政策的实施、一批重点区域和重大项目的建设、大量地热能开发利用新技术的推广,又给地热产业带来了新的发展契机。不同形式、不同利用方式的地热能都将迎来更广阔的市场、更高的产业增长态势。为顺应新时代行业发展,地热产业应抓住机遇,迎接挑战,创新突破,成就未来。本文将从上位决策、项目建设、技术创新、管理等方面,分析当下地热行业发展的形势、特点和存在的问题,提出相关建议,以共同探讨,相互借鉴。