高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

日本马氏贝珍珠化学组成的同步辐射X射线荧光光谱分析

采用同步辐射微区X射线荧光光谱技术,探测古铜色日本马氏贝珍珠剖面(珠核与珍珠层)的元素分布。测试结果表明,样品中主要含有Ca、Sr、Ba等3种碱土金属元素,Mn、Fe、Cu、Zn等4种3d过渡金属元素以及稀土元素,各元素在珍珠中表现出一定的空间分布规律:珠核表面稀土元素浓度最高,珍珠层和珠核的稀土元素浓度大致相当;Mn和Fe元素浓度自珠核浅表层向珠核表面有降低趋势;珍珠层内Mn和Fe元素浓度都出现大幅降低现象,且是在相同的圈层降低,显示其具有一定正相关性,推测二者大幅降低的圈层是平行层和棱柱层的分界,且Mn元素主要赋存于棱柱层;Ca与Sr、Ba元素的分布具有负相关性。     

延边开山屯花岗闪长岩-石英闪长岩体年代学、地球化学特征及对古太平洋板块俯冲作用时限的制约

近年来古太平洋构造域的构造演化备受学者关注。本文报道的延边开山屯地区花岗闪长岩-石英闪长岩体LAICP-MS U-Pb年龄表明其形成时间为早侏罗世早期(198±1Ma),所采样品可根据Zr/Hf值分为高Zr/Hf值组花岗闪长岩和低Zr/Hf值组石英闪长岩。高Zr/Hf值组花岗闪长岩起源深度浅,富集Rb、Th、U、K等大离子亲石元素(LILEs),贫Nb、Ta、Ti等高场强元素(HFSEs),具壳源岩浆的特点。低Zr/Hf值组为壳源岩浆与来自深部的亏损地幔岩浆混合而成,岩石亏损Nb、Ta、Zr、Hf、Ti等高场强元素,具有典型的弧型岩浆地球化学特征。岩体中存在细粒闪长质包体,镜下可见针柱状磷灰石。开山屯岩体属钙碱性系列岩石,结合前人资料,认为其与该地区同时代火成岩组成北-东向分布的早侏罗世活动大陆边缘型火成岩带,而位于该带西侧的小兴安岭-张广才岭地区存在同时代弧后拉张带,两者构成典型的大陆弧与弧后拉张带模型,共同揭示了早侏罗世早期古太平洋板块对东北地区的俯冲作用。     

冰层取心回转钻进模拟实验台的设计与测试

极地钻探实践表明,冰盖底部冰岩交界附近地质情况异常复杂,不但可能存在暖冰、基底融水,甚至还存在厚度不等的冰岩夹层,取心钻探异常困难,而优选钻头类型、确定合理的钻进参数是保证其安全、快速钻进的重要因素。本文设计了一套能够模拟冰层回转钻进的实验台,其技术参数为：钻压、转速分别可在0～10 kN、0～300 r/min范围内调节,最大扭矩约100 N·m。该实验台能够测量钻头切削具温度、钻孔深度及钻进速度等参数,为深入研究钻头类型及结构参数、钻进参数对扭矩、钻速和切削温度的影响规律提供了手段。采用PDC复合片钻头进行了冰钻实验,结果表明,实验台能够准确调节钻压和转速,可满足实验要求。     

Reconstruction of Holocene paleohydrological and sedimentological characteristics of Umm Ar-Rimam basin (northern Kuwait)

The paleohydrological and sedimentological characteristics of a playa lake in northern Kuwait (Arabian Gulf) are reconstructed using sedimentological, geochemical, and isotopic techniques. The sequence consists of up to 8 cycles of S-poor, alluvial sediments capped by a thin organic soil interbedded with gravity-fall calcrete sediments. The succession is locally derived from mainly Quaternary sediments and is regressive with upsection filling of the subsiding basin by cycles of sheetwash flow in response to climatic change. There is no natural, open-water lake water as indicated by low total organic carbon (TOC) data, but the presence of incised calcrete yardangs suggests that more extensive open-water conditions were operative in the past. Stable isotope (δ¹⁸O‰ and δ¹³C‰) values of the authigenic carbonates indicate the following three distinct processes: evaporation, meteoric fluid infiltration, and rapid per-descensum flow (rapid downward movement of water and playa sediment through pipes) through a porous, clastic sequence. Because evaporites are scarce, other factors besides evaporation action control chemical and isotopic compositions of the per-decensum lake fluids. Consequently, the isotopic composition cannot be interpreted exclusively as an indicator of salinity or evaporation ratio. The degassing of CO₂ during groundwater discharge may explain the enriched carbon isotope values for the authigenic carbonates precipitated in the sediments. Hydrologically closed lake water bodies tend to show low negative carbonate oxygen and carbon isotopic signatures. Isotopically negative δ¹³C values imply a strong input of soil-zone carbon to the groundwater of the top 60 cm of the sediment. Lakes that are hydrologically closed and evaporate or equilibrate with atmospheric CO₂ will tend to have low negative δ¹⁸O and δ¹³C values in the carbonates as reported by Talbot (Chem Geol: Isotope Geosci Sect 80(4):261–279, 1990). Biologically active lakes will tend toward lower δ¹³C of dissolved carbon due to the photosynthetic effects of ¹²C withdrawal as reported by Dunagan and Driese (J Sed Res 69:772–783, 1999). Increased biological activity during sedimentation may account for low carbon isotope values where plants were abundant, but in shrinkage-dominated systems (those of clay-rich soil subjecting to wet-dry conditions), carbon isotopes will be largely inherited from the calcretic limestones in the land extending landward of the coast and not influenced by coastal processes (known as hinterland), such as Umm Ar-Rimam depression. This basin does not fit the classic shallow playa-type basins of the Arabian Peninsula but rather the recharge playas of the southwestern USA.     

Tectono-sedimentary evolution of the Miocene Oued Dayr Formation (Ghomaride Complex,Internal Domain of the Maghrebian Rif Belt,Morocco)

This work deals with sedimentological, petrographic, and structural analyses of a middle Miocene late-orogenic sedimentary cycle, denoted Oued Dayr Formation, recognized in the Rifian sector of the Maghrebian Chain (Morocco). The analyzed Formation (75 m thick) starts with 15–20 m of light colored polymict conglomerates, with minor sandstone beds, lying on the Paleozoic basement and Mesozoic cover of the Ghomaride Nappe. Facies analysis indicates a fining-upward deposition in a marine environment characterized by increasing deepening, reflecting a subsidence rate that exceeds sedimentary supply. Petrographic analysis points out that sandstones are represented by litharenites originated by erosion of recycled orogen. The conglomerates pebbles and cobbles consist of Alpine low- to high-grade metamorphic rocks as metarenites, phyllites, mylonitic quartzites, micaschists, augen gneisses deriving from the exhumed deep metamorphic basement, the overlying metasedimentary of the Sebtide Nappes and of sedimentary rocks as sandstones, jaspes, limestones, and shales deriving from the Ghomaride Nappes and their sedimentary cover. Data reveal mixed provenance indicating that the Oued Dayr Formation was fed by the Internal Nappes stack of the Maghrebian Chain. Structural analysis shows that the Oued Dayr Formation accumulated in a Thrust-Top basin, during an early extension (D₀ phase), recorded by synsedimentary normal faults within middle Langhian deposits on the rear of the Internal Nappes stack. Subsequent ductile and brittle compressional (D₁, D₂, D₃) and extensional (D₄) deformation phases occurred during and/or after the stacking, exhumation, and early unroofing of Sebtide Complex coeval with the opening of the western Mediterranean back-arc basins since middle Miocene time.     

Sensitivity analysis for the GALDIT method based on the assessment of vulnerability to pollution in the northern Sfax coastal aquifer,Tunisia

Coastal aquifer of northern Sfax (Tunisia) suffers from the high risk to seawater intrusion and the water quality degradation due to the overexploitation. Hence, assessing the study area vulnerability to pollution is highly crucial so as to protect the groundwater resources. The assessment has been performed by applying the GALDIT method using Geographic Information System (GIS) software and multi-criteria evaluation techniques, and the sensitivity analysis approach to evaluate the effect of each GALDIT parameter on the vulnerability assessment. The GALDIT vulnerability map classifies the study area into three vulnerability classes: low vulnerability (30–50), moderate vulnerability (50–70), and high vulnerability (70–90), which represent 5, 30, and 65 % of the study area, respectively. The map illustrates that the coastal zones of the aquifer are the most threatened areas. The sensitivity analysis results show that the aquifer hydraulic conductivity (A) and the thickness of the aquifer (T) represent the determining factors in the modified vulnerability model. The real weight was used to elaborate the modified GALDIT model which was correlated with resistivity values for validation. This study could serve as a scientific basis for sustainable land planning and groundwater management in the study area.     

<Emphasis>H</Emphasis>ydrological variability of the <Emphasis>S</Emphasis>oummam watershed <Emphasis>(N</Emphasis>ortheastern <Emphasis>A</Emphasis>lgeria<Emphasis>)</Emphasis> and the possible links to climate fluctuations

The long-term variability of rainfall in the Soummam watershed (NE Algeria) has been analysed over the past 108 years using continuous wavelet method in order to identify the interannual modes controlling the rainfall variability. Statistical analyses of rainfall timeseries have shown its distribution following five periods of time, limited by a series of discontinuities around 1935, 1950, 1970 and 1990. The continuous wavelet transform have demonstrated different low frequency modes: 2–4, 4–8, 8–16 and 16–32 years.The annual band is expanded during the full study period with some pics around 1905, 1920–1935 and 1960; it shows a negative long-term trend, in particular since the period 1970–1990 when a major change has been identified. Then, the relationships between climate patterns of North Atlantic Oscillation (NAO) and Southern Oscillation Index (SOI) and the hydrological variability in the frequency domain have been investigated; they have shown a mean explained variance of 40 and 24 %, respectively. Such variances are less obvious for the annual mode and increase for the interannual frequencies. The coherence suffer from high perturbations since the period 1970–1990 when the NAO (SOI) shifts from negative (positive) phases to positive (negative) ones. Such anomalies are responsible for significant changes of rainfall variability, emphasising the global warming effects.     

Investigation of moment-rotation relation in different joint types and evaluation of their effects on segmental tunnel lining

This paper presents the results of a numerical study that has been performed to investigate the different joint types that affect the moment-rotation relation and ultimate bending moment capacity of a joint. A 3D finite element method was adapted to establish elaborate numerical models of segments. To evaluate the possible differences in moment-rotation behavior between different joint types, 10 different joint types were simulated. Additionally, the effect of different joint types on behavior of a lining ring was investigated. The validity of the peridynamic simulation was tested by comparing results obtained in this paper against the results obtained in a study performed by Hordijk and Gijsbers. Observations of the results demonstrate that in a flat joint, the expanding of joint height increased the rotation stiffness of the joint in the linear branch, and accordingly, the ultimate bending moment of the joint increased. In the ring model, it was observed that the expanding of joint height led to the decreased of ring displacement and stress concentration in the joint. Whenever there were full surface contacts (contact two segment in total cross section) in the joints, the rotation stiffness of the joints in the linear branch became equal, and, as a result, the displacement in the ring model was the same in all joint types. In addition, it was observed that using a convex joint in the ring model increases the displacement of the ring. The ultimate bending moment of bolted joints was higher than that of joints without bolts, especially in the case of a negative moment.     

Characterization of the Tertiary reservoir in Khabbaz Oil Field,Kirkuk area,Northern Iraq

Tertiary reservoir represented by Jeribe, Anah, Azkand, and Azkand/Ibrahim formations has been studied from reservoir characterization point of view in Khabbaz Oil Field/Northern Iraq. Examined thin sections prepared from core rock samples which are selected from the wells Kz-8 and Kz-9 revealed the existence of different microfacies in which are varies types of porosity such as interparticle, intraparticle, moldic, vuggy, and fractures have been noticed. In addition to these different types of diagenetic features are represented mainly by cementation, dolomitization, recrystallization, and dissolution. The available log data for the wells Kz-11, Kz-14, and Kz-16 have been used in characterizing the reservoir properties of the studied formations. The detected lithologies from porosity logs showed domination of limestone, dolomitic limestone, and dolomites in addition to few thin beds of anhydrites in Jeribe Formation and thin beds of sand dominated lithologies in Azkand Formation. Clay content has been calculated from gamma ray log along the studied sections and appeared to be mostly of dispersed clay type as shown from density-neutron porosity crossplot of Thomas-Stieber. Correction from the effect of clay content has been done for all the measured sonic, density, and neutron porosities. The available porosity and permeability values which are measured from core tests in the well Kz-9 for the formations of Jeribe, Anah, and Azkand have been adapted to formalize the best equation for calculating permeability in the other studied wells which have no core test measurements but only log data (Kz-11, Kz-14, and Kz-16 wells). Depending on porosity, permeability, and shale content, the studied sections have been subdivided into seven reservoir units in the wells Kz-11 and Kz-16, and for eight reservoir units in the well Kz-14.