Schul- und Laiengeologie im Jahre 1910

Ohne Zusammenfassung     

Origin of Dissolved Organic Carbon Studied by UV‐vis Spectroscopy

Dissolved organic carbon (DOC) distributions in water from Lake Ipê, MS, Brazil, were investigated. The samplings were performed monthly (surface, 1 m depth, and bottom) from June 1999 to June 2000. Absorbance at 285 nm and DOC concentrations in mg dm^—3, p(DOC), were highly correlated for the three depths. 77% of the surface, 85% for 1 m and bottom samples presented a variation between 20 dm³ g^—1 cm^—1 and 50 dm³ g^—1 cm^—1 of A(285 nm)/p(DOC), that characterizes the dissolved organic matter in lake water as essentially fulvic. The ratio A(254 nm)/p(DOC) was also sensitive for fulvic matter, and an A(250 nm)/A(365 nm) = 4 ratio was characteristic of strongly colored waters. The ratios A(436 nm)/p(DOC) for the three depths also showed a significant correlation. The predominance of fulvic acid is explained by environmental characteristics such as the tropical climate, temperatures above 18 °C, and the lake environment. It was demonstrated that the variation in the water carbon content due to different compartments in the lake can be monitored by UV‐vis spectroscopy ratios.     

A comparison of congeneric PCB patterns in American eels and striped bass from the Hudson and Delaware River estuaries

The Hudson River estuary has enormous spatial variation in polychlorinated biphenyl (PCB) contamination due in large part to historical point source discharges above Troy Dam. The Delaware River estuary has accumulated significant levels of PCBs through decades of industrial, municipal, and non-point source inputs. The overall goal of this research was to use existing data sets to compare and contrast the patterns of accumulated PCB congeners in sub-populations of American eels and striped bass inhabiting these two estuaries and surrounding coastal waters. Using principal component analysis and analysis of covariance (ANCOVA), inter- and intra-estuarine differences in accumulated congeneric patterns were denoted for both species. Results from our study support the idea that migratory behaviors of striped bass hamper the use of accumulated congener-specific PCB patterns in providing information on localized contamination, although major regional differences were seen between upriver Hudson River fish, downriver Hudson River fish and fish from other areas within this study. This study provides additional evidence for the use of the American eel as a biomonitoring tool, since its limited home range provides finer resolution of regional contamination.     

A comparison of three-dimensional interpolation techniques for plume characterization

Interpolation of contaminant data can present a significant challenge due to sample clustering and sharp gradients in concentration. The research presented in this paper represents a study of commonly used interpolation schemes applied to three-dimensional plume characterization. Kriging, natural neighbor, and inverse distance weighted interpolation were tested on four actual data sets. The accuracy of each scheme was gauged using the cross-validation approach. Each scheme was compared to the other schemes and the effect of various interpolation parameters was studied. The kriging approach resulted in the lowest error at three of the four sites. The simpler and quicker inverse distance weighted approach resulted in a lower interpolation error on the other site and performed well overall. The natural neighbor method had the highest average error at all four sites in spite of the fact that it has been shown to perform well with clustered data. Another unexpected result was that the computationally expensive high order nodal functions resulted in reduced accuracy for the inverse distance weighted and natural neighbor approaches.     

Organochlorine contaminant exposure and associations with hematological and humoral immune functional assays with dam age as a factor in free-ranging northern fur seal pups (Callorhinus ursinus)

Potential effects of organochlorine contaminant (OC) exposure on humoral immune function and health of free-ranging northern fur seals were investigated. Forty-two "neonates" were captured for blood sample collection and re-sampled as "pups" 29-51 days later. OCs were extracted from whole blood to identify polychlorinated biphenyl congeners and chlorinated pesticides by high performance liquid chromatography. Humoral immune function was assessed by antibody responses to vaccination and immunoglobulin concentrations. Additional health status indicators included leukocyte counts and haptoglobin concentrations. Mean OC concentrations were higher in neonates than at recapture. Neonates of young dams had higher mean OC concentrations than neonates of older dams. A higher proportion of old dam's pups developed a twofold or greater increase in antigen-specific antibodies compared to young dam's pups. Higher OC exposure and poor immune responses in first-born pups may indicate a higher risk of secondary morbidity and mortality than pups of multiparous dams.     

Reventador Volcano 2005: Eruptive activity inferred from seismo-acoustic observation

Reventador Volcano entered an eruptive phase in 2005 which included a wide variety of seismic and infrasonic activity. These are described and illustrated: volcano-tectonic, harmonic tremor, drumbeats, chugging and spasmodic tremor, long period and very long period events. The recording of this simultaneous activity on an array of three broadband, seismo-acoustic instruments provides detailed information of the state of the conduit and vent during this phase of volcanic eruption. Quasi-periodic tremor at Reventador is similar to that observed at other volcanoes and may be used as an indicator of vent aperture. Variations in the vibration modes of the volcano, frequency fluctuations and rapid temporal fluctuations suggest the influx of new material, choking of the vent and possible modification of the conduit geometry during explosions and effusion over a period of six weeks.     

Acoustic source characterization of impulsive Strombolian eruptions from the Mount Erebus lava lake

We invert for acoustic source volume outflux and momentum imparted to the atmosphere using an infrasonic network distributed about the erupting lava lake at Mount Erebus, Ross Island, Antarctica. By modeling these relatively simple eruptions as monopole point sources we estimate explosively ejected gas volumes that range from 1,000 m³ to 24,000 m³ for 312 lava lake eruptions recorded between January 6 and April 13, 2006. Though these volumes are compatible with bubble volumes at rupture (as estimated from explosion video records), departures from isotropic radiation are evident in the recorded acoustic wavefield for many eruptions. A point-source acoustic dipole component with arbitrary axis orientation and strength provides precise fit to the recorded infrasound. This dipole source axis, corresponding to the axis of inferred short-duration material jetting, varies significantly between events. Physical interpretation of dipole orientation as being indicative of eruptive directivity is corroborated by directional emissions of ejecta observed in Erebus eruption video footage. Although three azimuthally distributed stations are insufficient to fully characterize the eruptive acoustic source we speculate that a monopole with a minor amount of oriented dipole radiation may reasonably model the primary features of the recorded infrasound for these eruptions.     

Buried rhyolites within the active,high-temperature Salton Sea geothermal system

Previously unrecognized pulses of rhyolite volcanism occurred in the Salton Trough between 420 ± 8 ka and 479 ± 38 ka (2σ), based on high-spatial resolution U–Pb zircon geochronology. Presently, these rhyolite lavas, tuffs and shallow subvolcanic sills are buried to depths between ~ 1.6 and 2.7 km at ambient temperatures between 200 and 300 °C, and are overprinted by propylitic to potassic hydrothermal alteration mineral assemblages consisting of finely intergrown quartz, K-feldspar, chlorite, epidote, and minor pyrite. Alteration resistant geochemical indicators (whole-rock Nd-isotopes, zircon oxygen-isotopes) reveal that these rhyolites are derived from remelting of MORB-type crust that was chilled and hydrothermally altered by deep-circulating hydrothermal waters. U–Pb zircon dating confirms the presence of Bishop Tuff in well State 2-14 at ~ 1.7 km depth, approximately 5 km NE of the geothermal wells that penetrated the buried rhyolites. These results indicate accelerated subsidence towards the center of the Salton Trough, increasing from 2.2 mm/a to 3.8 mm/a. Based on these results, the present-day Salton Sea geothermal field is identified as a focus zone of episodic rhyolitic volcanism, intense heat flow and metamorphism that predates present-day geothermal activity and Holocene volcanism by at least ~ 400 ka.