Image analysis of seafloor photographs for estimation of deep-sea minerals

Factors such as non-uniform illumination of seafloor photographs and partial burial of polymetallic nodules and crusts under sediments have prevented the development of a fully automatic system for evaluating the distribution characteristics of these minerals, necessitating the involvement of a user input. A method has been developed whereby spectral signatures of different features are identified using a software ‘trained’ by a user, and the images are digitized for coverage estimation of nodules and crusts. Analysis of >20,000 seafloor photographs was carried out along five camera transects covering a total distance of 450 km at 5,100–5,300 m water depth in the Central Indian Ocean. The good positive correlation (R² > 0.98) recorded between visual and computed estimates shows that both methods of estimation are highly reliable. The digitally computed estimates were ∼10% higher than the visual estimates of the same photographs; the latter have a conservative operator error, implying that computed estimates would more accurately predict a relatively high resource potential. The fact that nodules were present in grab samples from some locations where photographs had nil nodule coverage emphasises that nodules may not always be exposed on the seafloor and that buried nodules will also have to be accounted for during resource evaluation. When coupled with accurate positioning/depth data and grab sampling, photographic estimates can provide detailed information on the spatial distribution of mineral deposits, the associated substrates, and the topographic features that control their occurrences. Such information is critical for resource modelling, the selection of mine sites, the designing of mining systems and the planning of mining operations.     

Dissociation constants of protonated cysteine species in seawater media

The dissociation constants (pK₁, pK₂ and pK₃) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK₃ in the Na–Mg–Cl solutions have been attributed to the formation of Mg²⁺ complexes with Cys²⁻ anions

Mg²⁺ + Cys²⁻ = MgCys

The stability constants have been fitted to

after corrections are made for the interaction of Mg²⁺ with H⁺.The pK₁ seawater measurements indicate that H₃Cys⁺ interacts with SO₄²⁻. The Pitzer parameters β⁰(H₃CysSO₄), β¹(H₃CysSO₄) and C(H₃CysSO₄) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK₂ and pK₃ in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK₁, pK₂ and pK₃ that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids.     

Environment and Deep-Sea Mining: A Perspective

Abstract

As the quest for deep-sea mineral resources is gaining momentum, environment and ocean mining have become important aspects of study. Because many of these deposits occur in international waters, the concern for environmental conservation in view of the effects of deep-sea mining is resulting in these effects being studied in different oceans, and efforts to develop regulations governing this exploitation are also underway at national and international levels. The impact assessment of deep-sea mining needs to encompass a variety of subjects, including environmental, socioeconomic, technological, and legal aspects. At the same time, effects of in situ environmental conditions on mining activities also need to be considered for effecient performance by the mining system. Differences in the degree of impact have been noticed during the mining simulation experiments by different investigating agencies. Therefore, interparameter comparisons, standardization of methods, and improvement in mining design are important considerations for proper utilization of resources, conservation of environment, and cost efficiency of the mining operations.     

Soil chemical changes resulting from irrigating with petrochemical effluents

Irrigating food crops with treated wastewater is a popular management option in India. This study evaluated the impacts of land application of treated petrochemical effluent on soil chemical properties. Soil samples were collected from different depths from sites irrigated with petrochemical effluent for 2?years and from control sites. The effluent collected was analysed for different physic?Cchemical properties and its impact on Lagenaria siceraria (Bottle gourd) growth. 100% concentrated effluent was used for the study and compared with the control. It was observed that application of effluent significantly increased the major cations and anions in the field. On the basis of the study, it may be suggested that treated petrochemical effluent can be used as an alternate source for irrigating crops as it increases the nutrient content of the soil. The overall application indicates a lavishing growth of L. siceraria crop in petrochemical irrigated soil than control sites. This study provides information for better understanding of changes in soil properties due to land application of petrochemical effluent. These changes must be considered in developing possible criteria for preserving delicate ecosystems.     

The chemical composition of tertiary Indian coal ash and its combustion behaviour – a statistical approach: Part 2

In Part 1 of the present investigation, 37 representative Eocene coal samples of Meghalaya, India were analyzed and their physico-chemical characteristics and the major oxides and minerals present in ash samples were studied for assessing the genesis of these coals. Various statistical tools were also applied to study their genesis. The datasets from Part 1 used in this investigation (Part 2) show the contribution of major oxides towards ash fusion temperatures (AFTs). The regression analysis of high temperature ash (HTA) composition and initial deformation temperature (IDT) show a definite increasing or decreasing trend, which has been used to determine the predictive indices for slagging, fouling, and abrasion propensities during combustion practices. The increase or decrease of IDT is influenced by the increase of Fe₂O₃, Al₂O₃, SiO₂, and CaO, respectively. Detrital-authigenic index (DAI) calculated from the ash composition and its relation with AFT indicates Sialoferric nature of these coals. The correlation analysis, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) were used to study the possible fouling, slagging, and abrasion potentials in boilers during the coal combustion processes. A positive relationship between slagging and heating values of the coal has been found in this study.