Test of experimental set-ups for electrodialytic removal of Cu, Zn, Pb and Cd from different contaminated harbour sediments

Electrodialytic removal of heavy metals from different harbour sediments was investigated. Electrodialytic remediation experiments in laboratory scale were made with calcareous and non-calcareous harbour sediments. Two different experimental set-ups were used for the study, one with stirring of the sediment slurry, the other without stirring. The removal of heavy metals was highest in the non-calcareous sediment, where 94% Cd, 91% Zn and 73% Cu were removed after 24 days. The highest removal obtained for the calcareous sediment was 81% Cd, 76% Zn, 75% Pb and 53% Cu after 21 days, with stirred sediment slurry. Electrodialytic experiments without stirring of calcareous sediment gave high removals (84% Zn, 58% Pb and 48% Cu), but there were problems with precipitations in the sediment, which limited the removal. The stirred experiments gave the highest removals of heavy metals and the voltage was the most stable in these experiments, and thus, the stirred set-up is the best choice for experimental set-up. The order in which the heavy metals were removed from the harbour sediments was Cd>Zn>Pb>Cu.     

An approach to combined rock physics and seismic modelling of fluid substitution effects

The aim of seismic reservoir monitoring is to map the spatial and temporal distributions and contact interfaces of various hydrocarbon fluids and water within a reservoir rock. During the production of hydrocarbons, the fluids produced are generally displaced by an injection fluid. We discuss possible seismic effects which may occur when the pore volume contains two or more fluids. In particular, we investigate the effect of immiscible pore fluids, i.e. when the pore fluids occupy different parts of the pore volume. The modelling of seismic velocities is performed using a differential effective‐medium theory in which the various pore fluids are allowed to occupy the pore space in different ways. The P‐wave velocity is seen to depend strongly on the bulk modulus of the pore fluids in the most compliant (low aspect ratio) pores. Various scenarios of the microscopic fluid distribution across a gas–oil contact (GOC) zone have been designed, and the corresponding seismic properties modelled. Such GOC transition zones generally give diffuse reflection regions instead of the typical distinct GOC interface. Hence, such transition zones generally should be modelled by finite‐difference or finite‐element techniques. We have combined rock physics modelling and seismic modelling to simulate the seismic responses of some gas–oil zones, applying various fluid‐distribution models. The seismic responses may vary both in the reflection time, amplitude and phase characteristics. Our results indicate that when performing a reservoir monitoring experiment, erroneous conclusions about a GOC movement may be drawn if the microscopic fluid‐distribution effects are neglected.     

Inherent gravitational instability of thickened continental crust with regionally developed low- to medium-pressure granulite facies metamorphism

Petrological arguments show that regionally developed low- to medium-pressure, high-temperature granulite facies metamorphism may critically enhance the lowering of crustal density with depth. This leads to gravitational instability of homogeneously thickened continental crust, mainly due to changes in mineral assemblages and the thermal expansion of minerals in conjunction with the exponential lowering of the effective viscosity of rocks with increasing temperature. It is argued that crustal processes of gravitational redistribution (crustal diapirism) contributing to the exhumation of granulite facies rocks may be activated in this way.     

Population Belongs on the Johannesburg Agenda

The forthcoming World Summit on Sustainable Development (WSSD) in Johannesburg (August 26-September 4, 2002) has been set by the United Nations to consider strategies toward sustainable development in all its dimensions. Hence, its mandate is broader than that of the Rio 1992 United Nations Conference on Environment and Development (UNCED). Population issues have so far been discussed in a separate series of World Population Conferences (Bucharest 1974, Mexico City 1984, Cairo 1994). With no new World Population Conference scheduled for 2004 and Johannesburg having a mandate that is stated to explicitly include social and economic aspects, population as a key component of sustainable development should figure prominently on the Johannesburg agenda. Yet, after the third of four preparatory meetings for Johannesburg (which ended in New York on April 5th), consideration of population is completely absent. The reasons for this are not entirely clear. We assume that they have to do with the fear of entering into political controversies over abortion. We are concerned that, despite its broader mandate, in most countries inputs to Johannesburg are being prepared mainly by environment ministries who have little experience in dealing with population questions. This revised version was published online in July 2006 with corrections to the Cover Date.     

澳大利亚寒武纪Heathcote绿岩带中变质拉斑玄武岩和层间沉积物:维多利亚州金矿化的来源?

ＬａｋｅＣｏｏｐｅｒ露天矿区寒武系变质拉斑玄武岩和层间沉积物由９个块状－枕状熔岩和７层沉积物组成,位于澳大利亚维多利亚州中部Ｈｅａｔｈｃｏｔｅ绿岩带的北部,岩层厚度为２８１ｍ．矿区的变质玄武岩在岩性和地球化学上与正常的大洋中脊玄武岩及维多利亚州其他地区绿岩体中的变质玄武岩极为相似,并且未遭受热液蚀变作用．层间沉积物由细条带状硫化物、层状含硫化物的碳质泥岩、燧石和沉积碳酸盐岩组成．沉积物中异常矿物组合、微量元素、稀土元素等特征表明,沉积物为喷气火山成因．露天矿中的变质拉斑玄武岩含金低于５×１０－９,而层间沉积物金品位随Ａｓ、Ｃｕ、Ｚｎ含量变化而变化,金含量平均为６７×１０－９．根据沉积学特征和硫化物矿物推测,沉积物中成矿金属元素是在喷气沉积期间聚集的,即可能是从区内拉斑玄武岩之下的厚层玻古山岩中萃取和交换出来的．物质平衡计算表明,早—中古生代期间变质流体使金从层间沉积物中活化并在构造薄弱带、膨胀带再沉淀,故喷气成因的变沉积岩在金聚集和提供金源上起了重要作用,在维多利亚州Ｌａｃｈｌａｎ褶皱带中形成浊积围岩型岩金矿床．     

Assessing the Validity of Seismo-Acoustic Predictor Equations for Obtaining Seabed and Sub-Surface Sediment Physical Properties

The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.     

Slow drift oscillations of a ship in irregular waves

A procedure to calculate horizontal slow drift excitation forces on an infinitely long horizontal cylinder in irregular beam sea waves is presented. The hydrodynamic boundary-value problem is solved correctly to second order in wave amplitude. Results in the form of second order transfer functions are presented for different two-dimensional shapes. It is concluded that Newman's approximative method is a practical way to calculate slow drift excitation forces on a ship in beam sea and suggested that it may be used in a more general case. Applications of the results for moored ships are discussed.     

Leaching of nitrate from arable land into groundwater in Sweden

The agricultural influence on the quality of the groundwater in Sweden is mostly associated with infiltration areas. The local conditions here determine the extent of the nitrate leakage. It is evident that certain combinations of factors in normal cropping can give unduly high nitrate concentrations in the groundwater.     

Model analysis of the measured concentration of organic gases in the Norwegian Arctic

A 2-D meridional model for the chemistry and transport in the troposphere is used to study the seasonal variation of the concentration of organic gases like C₂H₂, C₂H₆, C₃H₈, C₆H₆, C₇H₈. CHCl₃ and C₂Cl₄ at high latitudes. The anthropogenic sources for these species were estimated, and the temporal and latitudinal distribution of OH and O₃ was calculated using a complex photochemical reaction system. There is fair agreement between the calculated annual variation and the measured concentrations for C₂H₂, C₂H₆, C₃H₈, C₇H₈ and C₂Cl₄ at Spitsbergen during July 1982 and March/April 1983, with a distinct late winter maximum and summer minimum. For CHCl₃, the direct anthropogenic source is minor compared to indirect anthropogenic or natural sources. For benzene, emission in car exhaust is important, but other anthropogenic sources are required for the calculations to agree with the measurements. Measured C₂H₄ and C₃H₆ concentrations are much higher than the calculated ones based on anthropogenic emissions, and show opposite seasonal trends. This indicates biogenic sources for these compounds.A buildup of PAN (300 pptv) is calculated at high latitudes during winter. This makes it the dominant source for NO_x as the temperature increases in the spring. NO_x is found to be a limiting factor for O₃ production at high latitudes during spring.