Interdecadal Variability of East Asian Summer Monsoon Precipitation over 220 Years （1777-1997）

In this study, long-term (1777–1997) precipitation data for Seoul, Korea, wetness indices from eastern China, and modern observations are used to identify the interdecadal variability in East Asian summer monsoon precipitation over the last 220 years. In the East Asian monsoon region, two long-term timescales of dry–wet transitions for the interdecadal variability and quasi-40-and quasi-60-year timescales are dominant in the 220-year precipitation data of Seoul, as well as in the wetness indices over China....     

闽西南晚中生代四方岩体同位素年代学、地球化学及其构造意义

闽西南地区四方岩体主要由花岗闪长岩和花岗闪长斑岩组成 ,花岗闪长岩单颗粒锆石 U-Pb年龄为 10 7.8±1.2 Ma,角闪石 Ar-Ar年龄为 10 4.8± 0 .8Ma,形成于早白垩世。岩体是在伸展拉张构造环境下以快速冷却 (50～ 60℃ / Ma)侵位的 ,岩石相对富 Na2 O,A / CNK<1,具壳 -幔混合源 I型花岗岩特征。岩石富 K、Rb、Th、U、L REE,贫 Ti、Nb、Ta、Sr,具火山弧/活动大陆边缘钙碱性岩系的特征。 (87Sr/ 86Sr) i为 0 .70 63 5～ 0 .70 898,εNd(t)为 -5.2 4～ -3 .69,TDM为 1.3 3～ 1.2 1Ga。岩石主要由幔源岩浆与中下地壳物质部分熔融形成的花岗质岩浆的混合形成的。与闽东沿海地区相比 ,晚中生代时闽西南地区总体处于与华南软流圈地幔上涌有关的伸展拉张构造环境 ,但由玄武岩浆底侵作用引发的壳幔作用并不强烈。该时期中酸性岩浆作用与成矿关系十分密切     

Contrast in Fluid M etallogeny between the Tianmashan Au-S Deposit and the Datuanshan Cu Deposit in Tongling, Anhui Province

A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion     

玩具业中重金属的等离子体发射光谱分析

为了支持玩具业,许多实验室需要分析各种复杂基体中的金属含量。人们关心的主要元素是铅,但很多其他有毒元素也具有潜在的威胁,尤其对于儿童。这些重金属元素包括锑、砷、钡、镉、铬、硒、汞和铅,累积在人体中将产生不利的影响。一些塑料和木制玩具,特别是表面色彩鲜艳的玩具被证实含有更高水平的铅和其他元素,儿童因接触易摄入,相关法规对产品表面含有这些元素的材料作了一些限制。为了保证玩具和其他物品的生产、流通和销售,有必要检测其中的重金属含量。不同的管理机构对各类样品中的元素提供了限量要求。在玩具安全性的欧洲标准EN71第3部分(已纳入ISO8124-3),其中在“特定元素的迁移”一节给出了玩具材料中元素迁移的     

龙门山中段中央断裂和前山断裂的晚新生代垂向活动性差异及其构造意义

2008汶川地震之后,多个研究组对龙门山的新生代剥蚀历史进行了研究,但是在龙门山推覆构造带中段,剥蚀历史研究主要集中在彭灌杂岩,而彭灌杂岩东侧(即中央断裂下盘)的热年代学资料相对缺乏,其剥蚀历史还比较模糊.对于彭灌杂岩东侧岩体的新生代剥蚀历史研究,不仅可以了解龙门山推覆构造带的新生代断层活动历史,而且对于青藏高原东缘的新生代隆升机制具有重要约束作用.在前人热年代学研究基础上,在龙门山推覆构造带中段中央断裂和前山断裂附近补充了一些裂变径迹样品.采用外探测器法(external detector method)对样品进行裂变径迹分析,实验测试在台湾中正大学裂变径迹实验室完成.实验获得了6个锆石裂变径迹和6个磷灰石裂变径迹年龄.前山断裂上盘,AFT(磷灰石裂变径迹)年龄以小鱼洞断裂为界存在明显的差异,其中小鱼洞断裂以南的样品AFT年龄为39 Ma,小鱼洞断裂以北的4个AFT年龄介于6—8 Ma之间.研究揭示出中央断裂和前山断裂的新生代活动性以NW向小鱼洞断裂为界存在较大差异:距今8 Ma以来,小鱼洞断裂以北,中央断裂和前山断裂的平均垂向滑动速率分别为约0.1 mm·a-1和约0.55 mm·a-1;小鱼洞断裂以南,平均垂向滑动速率则分别为约0.55 mm·a-1和约0.1 mm·a-1.低温热年代学方法获得的断层新生代垂向滑动速率与汶川地震断层垂向同震位移分布基本一致.前山断裂(小鱼洞断裂以北)距今8 Ma以来北西-南东向水平缩短量达到8~12 km,表明地壳缩短是造成龙门山抬升和剥蚀的重要因素之一.本研究结论不支持下地壳增厚模型对于龙门山隆升的解释.     

淡水双壳类壳体碳同位素研究:以河蚬(corbicula fluminea,Müller 1774)为例

双壳类壳体碳酸盐(文石)稳定同位素组成已被广泛地用于古气候和古环境重建研究中,但是双壳类壳体碳同位素组成所指示的气候和环境意义一直是争议的问题.对双壳类河蚬(corbicula fluminea)进行了室内养殖,并选取两个壳体样品(壳高,A=13 mm,B=9mm),测定其生长部分壳体和生长期间水体碳同位素,研究表明,随着水体碳同位素的升高(δ13CDIC由-5.24‰升至1.41‰),两壳体碳同位素也随之升高,表明水体对壳体碳同位素的影响;δ13CA分布范围为-4.76‰～2.09‰,δ13CB为-8.49‰～2.89,壳体A和B碳同位素均比预测平衡值偏负,表明壳体在形成过程中利用了新陈代谢产生的富集12C的CO2.根据计算壳体A在实验中沉淀部分壳体利用新陈代谢碳的比例(M值)为24%～43%,平均值为33%;壳体B为33%～75%,平均值为58%.M值随生物的生长呈下降变化,这说明在实验中河蚬主要是通过增加对DIC的吸收和利用来满足壳体生长对物质量增加的需求.     

针式微萃取结合GC-IRMS测定水溶液中甲酸、乙酸的稳定碳同位素组成

甲酸和乙酸稳定碳同位素组成（δ^13C）的分析对环境、食品、制药和自然产品等的研究具有重要的应用价值。但目前尚缺乏有效的测定方法。本研究利用最近出现的针式固相微萃取技术（NeedlEX）,以吹扫．捕集方式对水溶液中的有机酸进行了萃取,然后利用气相色谱．同位素比值质谱联用仪（GC—IRMS）对所萃取的有机酸分子进行了占δ^13C的测定。结果显示,质谱计的信号强度与水溶液中有机酸的浓度存在显著的线性相关关系（R^2〉0．99,P〈0．05）,表明Needl EX对水溶液中有机酸具有稳定的萃取能力。在甲酸与乙酸含量分别不低于300μg／mL与200μg／mL的水溶液中,1000mL的吹扫体积可以使两者δ^13C多次分析结果的相对误差分别保持在3％和1％左右,且整个实验流程没有造成可检测的碳同位素分馏作用。低于这两个浓度界线,则分析误差随浓度的降低迅速增加。本研究虽然是针对水溶液中有机酸δ^13C的测定,其萃取方法对其他水溶性挥发和半挥发有机物δ^13C的分析也同样具有应用价值。     

Fossil-Winged Fruits of Fraxinus(Oleaceae) and Liriodendron(Magnoliaceae) from the Duho Formation,Pohang Basin,Korea

Abstract: A total of 16 specimens of fossil-winged fruits were found from the Middle Miocene marine deposits, Duho Formation, Pohang Basin, Korea. They were identified into two structurally different groups: 15 specimens into a winged fruit of Fraxinus, and one specimen of Liriodendron. The most samaras (13 specimens) were identified as Fraxinus oishii, which is characterized by narrowly ovate or ovate–elliptic shapes that are 2.7–3.6 cm in length and 0.7–1 cm in width (l/w ratio=3.4–4). The apexes of the Fraxinus oishii samara are round or slightly emarginated, and a seed of the samara is always located at the base, of which the general shape is narrow rhombic-ellipsoidal. The seed is 1.2–2 cm long and 0.5–0.7 cm wide. Two specimens are different from the samara of Fraxinus oishii. They have a 6.6 length/width ratio (3.3 cm long and 0.5 cm wide), and thus, are temporarily classified into the Fraxinus sp. One specimen was recognized as a winged seed of Liriodendron meisenense. The wing is broadly lanceolate to elliptic in shape, has a smooth, acute apex, and is approximately 3 cm long and 0.7 cm wide. Samaras of Fraxinus oishii and Liriodendron meisenense were early reported from the Middle Miocene deposits from North Korea, but these specimens are the first discovery in South Korea. Further study of the Duho Formation may connect flora relationships between North and South Korea.     

岩质边坡稳定性的工程地质研究

岩质边坡稳定问题是工程地质学的一个重要研究課题,也是工程实践中迫切要求解决的问题。但是,对这个问题的研究,无论是国內国外都在进行探讨,还沒有形成一套完整的理论体系。为了推动这一方面的研究工作和解决生产实践中所提出的问题,本文试图从工程地质观点,并结合力学概念作一初步探讨,不妥和错误之处,希读者批评指正。