Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

2022年秋末初冬贵州一次超强寒潮天气过程分析

【目的】2022年 11月 29日—12月 1日贵州出现一次超强寒潮天气过程,为分析此次超强寒潮及其伴随的剧烈降温、大风和雪凝天气的成因。【方法】利用常规观测资料和 NECP1°×1°逐 6h再分析资料,运用天气学原理和天气动力学诊断分析方法。【结果】（1）此次超强寒潮天气过程是在中高纬地区配合有 -48℃冷中心的冷涡低槽发展东移南压,引导强冷空气大举南下以及副高加强西伸北抬、高原上多小槽东移的背景下产生的。（2）前期热低压发展加深,贵州大部地区最高气温异常回升至 27℃以上,850hPa冷平流强盛且维持时间长,是造成降温幅度大、气温低、降温持续时间长的主要原因。冷平流强度低于 -32×10^-5℃ ·s^-1 的区域与过程最低气温降幅超过 16℃的区域基本一致。【结论】（1）强气压梯度和变压梯度是此次超强寒潮强风形成的主要原因,大风区 ΔP₃普遍超过 3hPa,ΔP₂₄普遍超过 10hPa。ΔP₃ ＞3hPa、ΔP₂₄ ＞10hPa可作为寒潮大风预报指标。（2）西南低空急流维持加强,持续输送水汽并使贵州大气层结呈中间暖、上下冷的“三层”结构模式, 850hPa到地面温度 T＜0℃,为雪凝天气的发生发展提供了水汽和温度条件。当 850hPa温度 T≤ -2℃、地面温度 T≤0℃ 时,降水相态由雨转冻雨或雨夹雪或雪。     

回填贝壳砂耐久性试验研究

介绍了对我国浅海大量存在的贝壳砂进行化学性质和耐久性试验研究结果,从贝壳在酸雨中质量损失、溶蚀对贝壳成分和形态的影响及溶蚀对贝壳砂工程特性的影响三方面研究了贝壳砂的化学性质和耐久性,发现酸雨对贝壳有一定的溶蚀作用,在贝壳表面形成溶蚀凹坑,但是溶蚀作用缓慢,质量损失很小,酸雨溶蚀和海水溶出后的贝壳砂工程特性与未溶蚀的贝壳砂的工程特性相近,因而贝壳砂可用作海洋工程或港口工程回填砂。     

MM5数值预报产品在舟山海域风力分区预报中的释用

本文阐述了舟山海域地理气候特征及开展舟山海域风力分区预报的重要性,详细介绍了利用海岛测风站资料研究的MM5数值预报产品在舟山海域风力分区预报中的释用技术,实践证明该释用技术能为风力分区预报提供重要的技术支撑,并为研究同类数值预报产品释用技术提供重要的参考依据。     

利用HOAPS资料研究南海海气界面热通量时空分布

基于第二版本HOAPS(Hamburg Ocean Atmosphere Parameters and Fluxes from Satellite data)潜热、感热和海表温度(SST)3个参量的15 a(1988~2002年)逐月平均资料,利用经验正交方法分解分析了这3个参量在南海的时空分布.结果表明,在夏季模态,潜热表现为南高北低,感热表现为中间低两边高,两者主要都是海洋向大气输送热量,但大气有时也向南海中部输送感热;在冬季模态,潜热和感热的高值区都在南海北部,东北部有一强中心,该中心主要是由风场引起的;夏季SST的变化导致全年SST呈准半年周期变化.冬季SST的变化滞后于潜热变化1个月;除夏季和冬季模态外,冬夏转换季节模态也十分明显;HOAPS与NCEP(National Center of Environment Prediction)资料相比,两者3个参量的时空分布大体一致,区别在于HOAPS资料能更好地反映参量的一些细微特征.     

三江源国家公园生态系统服务时空变化及权衡-协同关系

本文基于“当量因子法”、空间自相关及相关系数等方法,定量分析了1990—2015年三江源国家公园生态系统服务的时空变化及生态系统服务间的权衡与协同关系。结果表明：① 1990—2015年,三江源国家公园生态系统服务价值呈不断上升趋势,从研究初期的542.37亿元增加至研究末期的834.70亿元,增长292.33亿元,增幅53.90%,每一阶段平均增长率为9.01%;长江源园区与黄河源园区生态系统服务价值占比情况与三江源国家公园整体情况一致,水域的生态系统服务价值最高,其次为草地、湿地,其中草地与水域提供了各园区90%以上的生态服务;澜沧江源园区的生态系统服务占比则为草地（70.58%）、湿地（23.58%）、水域（3.38%）。② 空间上,长江源园区及澜沧江源园区的生态系统服务价值呈东南高西北低的特征;黄河源园区则呈现西高东低特征。③ 相关分析表明,协同关系是三江源国家公园生态系统服务之间的主导关系,但各生态系统服务之间的相关程度各异。④ 数量方面,4类典型生态服务之间的权衡与协同关系的Moran′s I指数与相关性系数表现一致;空间分析方面,生态系统服务之间权衡与协同关系的异质性显著。     

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性,属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高,α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高,且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸,并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示,α螺旋和β片层围成了蛋白酶的催化腔,EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体,且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性,并有助于其催化功能的发挥,为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。     

A case study on Landscape Component Niche based on Landscape Pattern Indices: Yanchi,Ningxia Province,China

Yanchi County is located in the agro-pastoral ecotone and belongs to the ecologically fragile area of Northwest China.It is important to study the evolution of landscape pattern to curb its environmental degradation.In order to intuitively show how the landscape pattern of the study area changes over time,Landsat Thematic Mappers(TM)and Landsat Operational Land Imager(OLI)data of 1991,2000,2010 and 2017 were used.This paper attempts to apply niche theories and methods into landscape ecology,and constructs a niche model of landscape components by using"n-dimentional hypervolume niche theory"and landscape pattern indices.By evaluating the spatial and temporal evolution of niche from the perspective of two-dimensional space to reflect the changes of landscape pattern in the study area over the past 26 years,new theories and methods were introduced for the characterization of landscape pattern.The results indicate that:1)The larger the attribute and dominance value of landscape components,the higher the ecological niche and the stronger the control effect on the overall landscape.2)The ecological niche of each landscape component was significantly different,just as its control effect on the overall landscape.3)The dynamic change of the ecological niche of each landscape component was different,with grassland,unused land and arable land always in a high dominant position,although the ecological niche of construction land and water area was always low.In general,the introduction of niche theory into the landscape ecology provided a new method to study the changes in regional landscape pattern.     

数字技术背景下地图产品的变革

电子地图一边吸收传统地图学理论的精髓,同时引进新的技术和方法,摆脱了传统地图制图的局限和束缚,成为一种地理学研究与应用的新的语言形式。通过对传统地图同电子地图产品的比较来阐述地图产品在数字技术背景下产品模式、制图技术及应用领域等方面的变革。     

应用最小二乘法建立钾长石释光测年标准生长曲线

标准生长曲线（Standardised Growth Curve,SGC）法的提出为高效快速地测定释光样品的等效剂量（D_e）值提供了可能。不同实验室的放射源剂量率、操作流程、仪器误差等的不同会导致SGC参数的不同。运用最小二乘法标准化实验剂量校正后的信号L_ri/T_ri*D_e得到一条本实验室的标准生长曲线,用来快速得到等效剂量值。通过R软件实现了最小二乘法标准化过程,建立了50、100、150、200、250℃激发温度下的钾长石的标准生长曲线,分析发现250℃下的SGC收敛性最好,由于此温度下的信号衰退率可忽略不计,因此,我们用250℃激发温度下的SGC方程来估计样品的等效剂量。比较250℃ SGC D_e和250℃ MET-pIRIR D_e的一致性,发现在0~500 Gy范围内用SGC法估计的D_e和MET-pIRIR法估计的D_e非常接近,表明了此范围内SGC法的可靠性,而在>600 Gy范围内出现较大差别。一方面,此范围内用于拟合SGC的数据点较少导致高剂量区域内拟合的方程参数不够准确;另一方面,600 Gy与SGC对应的饱和剂量水平值844.5 Gy已经接近,所以在>600 Gy区域测出的D_e很可能出现较大偏差。因此需在今后工作中逐步积累更多样品,完善SGC参数,使其也能胜任较老年龄样品。