Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid, 相似文献
On the basis of an experimental study and thermodynamic calculation, the mechanisms of paragenesis and separation of silver, lead and zinc in the hydrothermal system have been studied. At acidic to nearly neutral pH, their chloride complexes are stable, and among them the chloride complexes of zinc are most stable. And the sulfide complexes are the dominant species at nearly neutral to alkaline pH,while the sulfide complexes of silver are most stable. With decreasing temperature, [ Cl^-] ,fO2, and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors affecting their stabilities. Complexes of different forms and stabilities respond to the variation of conditions to different extents, which gave rise to the paragenesis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition. 相似文献
A remarkable invariance in the ratio of 1,3-dimethylcarbazole (DMC) to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate. 相似文献
1 Introduction Soiland waterlossisoneofthe worldwide environm entalissuesthreatening sustainable land use in semiarid areas.However,soiland water loss is highly variable in space and time,and its variability resultsfrom m any factorsoperating ata wide ran… 相似文献
Most pingos in the permafrost region of the high northern Tibetan Plateau form along active fault zones and many change position annually along the zones and thus appear to migrate. The fault zones conduct geothermal heat, which thins permafrost, and control cool to hot springs in the region. They maintain ground-water circulation through broken rock in an open system to supply water for pingo growth during the winter in overlying fluvial and lacustrian deposits. Springs remain after the pingos thaw in the summer. Fault movement, earthquakes and man's activities cause the water pathways supplying pingos to shift and consequently the pingos migrate.
The hazard posed to the new Golmud–Lhasa railway across the plateau by migrating pingos is restricted to active fault zones, but is serious, as these zones are common and generate large earthquakes. Pingos have damaged the highway and the oil pipeline adjacent to the railway since 2001. One caused tilting and breaking of a bridge pier and destroyed a highway bridge across the Chumaerhe fault. Another has already caused minor damage to a new railway bridge. Furthermore, the construction of a bridge pier in the North Wuli fault zone in July–August 2003 created a conduit for a new spring, which created a pingo during the following winter. Measures taken to drain the ground-water via a tunnel worked well and prevented damage before the railway tracks were laid. However, pier vibrations from subsequent train motion disrupted the drain and led to new springs, which may induce further pingo growth beneath the bridge.
The migrating pingos result from active fault movement promoting artesian ground-water circulation and changing water pathways under the seasonal temperature variations in the permafrost region. They pose a serious hazard to railway construction, which, in turn can further disturb the ground-water conduits and affect pingo migration. 相似文献
Settling velocities of suspended cohesive sediment in estuaries vary over a range of several orders in magnitude. Variations in the suspended sediment concentration are often considered as the principal cause. Turbulence and the suspended sediment concentration, as well as other factors such as salinity, dissolved organic substances, flocculation ability, and the rate of floc growth affect setting velocities. A laterally–averaged finite difference model for hydrodynamics and cohesive sediment transport is developed and applied in the Tanshui River estuary, Taiwan. The model has been calibrated and verified with water surface elevation, longitudinal velocity, salinity, and cohesive sediment measured. The overall performance of the model is in qualitative agreement with the available data. The model is used to investigate the influence of settling velocity on cohesive sediment transport dynamics. The simulation indicates that the turbidity maximum zone is near Kuan–Du. When settling velocities increase the surface cohesive sediment concentration at Kuan–Du station trends to decrease and bottom cohesive sediment concentration increases. Both surface and bottom cohesive sediment concentrations decrease at Taipei Bridge and Pa–Ling Bridge. This implies that suspended sediment advected seaward and deposited. There is consequently a net seaward flux of suspended sediment near surface, and a net landward flux near the bed. 相似文献