渤海—鲁西地区白垩-早第三纪裂谷活动——火山岩的地球化学证据

渤海—鲁西地区的白垩早第三纪火山岩在渤海东部主要沿郯庐断裂带呈北北东向分布,在渤海西部和鲁西地区主要沿北西向断裂带分布。白垩纪火山岩以安山岩类为主,早第三纪以玄武岩类为主,玄武岩浆源于富集型地幔,即富集轻稀土和大离子亲石元素,但明显亏损Yb、Ni和Cr等元素。火山岩的Sr和Nd同位素初始比值结果表明白垩纪的火山岩来源于Ⅱ型富集地幔,而早第三纪火山岩来源于接近原始地幔的略富集型地幔。这可能由于早第三纪岩石圈大规模伸展减薄,致使上地幔深部的亏损型物质上涌参与岩浆活动,与富集型地幔混染的结果。     

黔西南白层超基性岩墙锆石SHRIMP U-Pb年龄和Hf同位素组成研究

文章对黔西南白层地区出露的燕山期超基性岩墙进行了单颗粒锆石SHRIMP U-Pb年龄和Hf同位素组成研究,获得A、B两组不同的锆石年龄.A组锆石呈不规则粒状,具不完整的宽大条带,12颗锆石的 SHRIMP U-Pb年龄加权平均值为(84±1)Ma,代表了超基性岩墙的侵位年龄;锆石Hf原位分析表明,176Hf/177Hf从0.282561到0282719,εHf(84 Ma)平均为-3.61,表明岩浆源区主要以富集地幔为主,并受到部分地壳物质的混染.B组锆石晶形完整,具典型的中酸性岩浆型振荡环带,3颗锆石的SHRIMP U-Pb模式年龄为409～450 Ma.176Hf/177Hf从0282379到0282440,εHf(t)平均为-3.77,均低于A组锆石,属于捕获锆石.据此认为84 Ma左右由于华南岩石圈伸展,软流圈地幔上涌,导致岩石圈富集地幔部分熔融,熔体上升过程中与409～450 Ma左右形成的少量地壳岩石发生混染,随后快速侵位冷凝而形成基性-超基性岩墙.白层地区84 Ma的超基性岩浆活动是整个华南西部燕山晚期(80～90 Ma)岩浆活动的一部分.右江褶皱带周缘的燕山晚期岩浆活动主要与大规模的Sn、W、Ag、Cu、Pb、Zn等矿床有关,但右江褶皱带内部的燕山晚期岩浆活动是否与以卡林型金矿为代表的低温热液矿床有成因上的联系,尚需更多矿床年代学资料的证实.     

Contamination,chemical speciation and vertical distribution of heavy metals in soils of an old and large industrial zone in Northeast China

Heavy metal pollution of soils has become a major concern in China as a consequence of rapid urbanization and industrialization in recent years. However, the evaluation on soil heavy metal pollution in Shenyang, the largest heavy industrial base city in China, has not yet been conducted. In this study, accumulation, chemical speciation, and vertical distribution Cu, Zn, Pb and Cd in soils were studied and pollution condition was assessed in Tiexi Industrial District of Shenyang, the largest and oldest industrial zone in Northeastern China. The results showed that in topsoil, the average concentration of total Cu, Zn, Pb, and Cd was 209.06, 599.92, 470.19 and 8.59 mg kg⁻¹, respectively, much higher than the national threshold limit. The values of pollution index and integrated pollution index showed that the pollution level was Cd > Cu > Zn > Pb, and Cd, Cu and Zn belong to heavy pollution level. The residual, Fe and Mn oxide-bound, and organic-bound species accounted for about 90%, while carbonate-bound and exchangeable species accounted for about 10%. This study indicates that the soils in the industrial zone were widely and extremely polluted by multi-heavy metals as a result of long-term industrial activities.     

东昆仑东段中更新世以来的成山作用及其动力转换

对东昆仑造山带东段第四纪构造及与地貌关系的分析表明，现代山盆相间的地貌格局成型于中更新世，且在中更新世以来发生了多次构造变形体制的转换。根据布青山北部查干额热格地区第四系剖面的构造、地层时代及地层与构造关系的分析表明，中更新世时期为伸展构造体制，昆仑山内部开始发生了差异隆升，布青山开始崛起。中更新世末应力体制发生急剧变化，由伸展体制转为收缩事件，又急速转为伸展构造体系，短暂的收缩事件造成了中更新世冲洪积层的褶皱，随后的伸展则导致了影响深刻的向北依次断落的阶地状正断层系统。晚更新世应力体系再度发生重大转换，伸展正断层体系被左旋走滑运动体系所代替，并一直延续至今。中更新世以来多次隆升构造变形体制的转换说明东昆仑地区的成山过程受控于多种动力背景，而非单一的挤压抬升。隆升构造变形体系的确定及其时代约束为深入刻划青藏高原东北缘隆升作用的动力过程提供了重要信息。     

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

吉林六批叶沟金矿床绢云母40Ar-39Ar 快中子活化法定年研究

在六批叶沟金矿石中,精选出与金矿物同期生成的绢云母作为样品,采用40Ar-39Ar快中子活化法测年,获得8个一致相连的平坦型绢云母年龄谱,tp=(190.28±0.30) Ma,氩同位素计算得等时线年龄为(189.98±0.58) Ma,两者完全吻合.等时线截距为(296.9±10.0) Ma,与大气氩的该值(295.5 Ma)相比较,两者完全吻合,表明该样品出自未受明显后期热力作用影响的非扰动体系.锁定六批叶沟金矿床主要成矿年龄为190 Ma左右,属早侏罗世的燕山早期.     

安徽峙门口铜—铁—金—硫矿床地球化学特征

峙门口铜—铁—金—硫矿床发育上部层状矿体和下部脉状矿体。上部层状矿石重晶石的δ~(34)S值为+14.10‰～+18.90‰。上部层状矿石黄铁矿和方铅矿的δ~(34)S值为+3.50‰～+5.84‰,下部脉状矿石黄铁矿的δ~(34)S值为+4.80‰～+6.80‰。下部脉状矿石中脉石英的δ~(18)O值为+14.3‰～+1 8.5‰,δ~(30)Si值为-0.3%0～-0.2‰。下部脉状矿石黄铁矿Re/Os比值为78.342～175.540,上(顶)部层状矿石中黄铁矿Re/Os比值为62.298～169.545。从下部脉状矿石到上部层状矿石,δ~(34)S值、Re/Os比值和流体包裹体温度249 ℃→97 ℃逐渐降低,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb平均值和Os_总、Re、~(187)Re等含量逐渐增高。矿石黄铁矿Re-Os同位素等时线年龄303±33 Ma。地质地球化学特征反映峙门口铜—铁—金—硫矿床为海底热水喷流沉积成因。     

青海湖沉积物生物硅的环境意义初步研究

湖泊沉积物中生物硅含量的变化已经被广泛应用于评价湖泊生产力和古气候变化研究,但大型湖泊不同位置生物硅含量的时空变化及其与环境要素之间的关系仍缺乏详细的现代过程研究。通过对青海湖不同位置表层沉积样品的生物硅含量测定,建立其空间分布模式及最近数百年生物硅含量的时间序列。结果表明,青海湖表层沉积物生物硅含量变化范围是1.75 ％ ~2.98 ％ ,平均值为2.25 ％ 。与世界其他湖泊相比,青海湖生物硅含量处于相对较低水平,可能与其特殊的地理位置和气候条件有关。青海湖生物硅含量的空间分布规律与沉积物质量堆积速率以及陆源组分含量(如SiO2)相反,而与化学/生物沉积组分(如CaCO3)含量的空间分布规律大体一致,说明生物硅的空间分布受到陆源碎屑物质的"稀释效应"影响。时间序列上,生物硅含量与SiO2含量呈相反变化趋势,与指示降雨量变化的 C/N 比值也是反相变化,说明生物硅含量在时间序列上也受与气候条件密切相关的陆源输入的影响。青海湖湖心低沉积速率区域的生物硅指标具有指示古气候变化的潜力。     

太行山红层磁学性质及古环境意义初探

环境磁学研究磁性矿物特征（磁性矿物类型、含量和颗粒大小）及其转化与环境关系,在不同地质时期古气候和古环境重建中得到广泛应用。本文将磁学方法应用于太行山中元古界红层研究,并从其磁学性质角度初步探讨太行山红层的古环境。对太行山红色石英砂岩和紫红色砂质泥岩样品进行了高温磁学和常温磁学系统测试。结果显示,太行山红层主要以硬磁性的赤铁矿为主,包含少量磁铁矿,部分样品赤铁矿是唯一磁性矿物;磁性颗粒大小以单畴为主;红色石英砂岩不同样品间磁性差别显著,反映沉积环境的不稳定性。紫红色砂质泥岩中的青灰色层表现为顺磁性特征,原因可能是紫红色砂质泥岩中的赤铁矿在后期还原环境下溶解或转化为弱磁性矿物所致,说明紫红色层并非形成于长期的水下还原环境。太行山红层中普遍存在的红色波痕和泥裂说明水环境对其有短暂影响,但是红层及赤铁矿的富集说明其长时间处于氧化环境,推断太行山红层可能形成于高度氧化的陆地环境。     

利用QuikSCAT/NCEP混合风场及WAVEWATCH模拟东中国海风浪场

将国际上比较成熟的海浪模式WAVEWATCH-Ⅲ移植到东中国海,采用QuikSCAT卫星遥感资料与NCEP数据混合风场作为强迫项,对该海区2000年1月23日至31日的一个大风天气过程下的风浪场进行了模拟计算。计算结果与浮标观测资料的对比结果说明,所获得的风浪场数值结果不但具有较高的时空分辨率,其精度也是比较高的。