MC-ICP-MS高精度测定Li同位素分析方法

以不同浓度Li元素标准样品和K、Ca、Na、Mg、Fe单元素标准样品的混合溶液为研究对象,采用3根阳离子交换树脂（AG 50W X8,200~400目）填充的聚丙烯交换柱和石英交换柱对Li进行分离富集,淋洗液分别为28 mol/L HCl、015 mol/L HCl以及05 mol/L HCl 30%乙醇,淋洗液体积小,仅为38 mL。分离回收率高,均大于976%。国际标样AGV 2（相对于IRMM 016）、BHVO 2（相对于IRMM 016）和IRMM 016（相对于L SVEC）的δ7Li值分别为(513±094)‰(2σ,n=10)、(408±060)‰(2σ,n=4)和(0038±073)‰(2σ,n=10),与前人分析结果吻合,分析精度与国际同类实验室水平相当。并对比了马里兰大学同位素实验室和笔者实验室对同种岩石矿物样品的分析结果,在误差范围内具有很好的一致性。此外,对美国地质调查局提供的准标样NKT 1霞石岩（相对于IRMM 016）给出了定值,δ7Li值为(871±046)‰(2σ,n=4)。因此,本方法可用于测定天然样品的Li同位素组成。     

Comparison of lipids in organs of the starfish Asterias amurensis associated with different treatments

Lipids were extracted from organs of the starfish Asterias amurensis associated with different treatments(raw-control,boiling and heating),and then analyzed for lipid content,lipid oxidation index,lipid classes and fatty acid composition.Results showed that boiling softened the hard starfish shells,thus facilitating the collection of starfish organs.As compared with raw organs,the boiled organs had lower water content and higher lipid content,possibly due to the loss of water-holding capacity caused by protein denaturation.Both boiling and heating increased the peroxide value(PV),thiobarbituric acid(TBA) value and carbon value(CV) of lipids.Despite slight increases in the content of complex lipids,associated lipid composition had no substantial variations upon boiling and heating.For simple lipids,the content of 1,2-diglyceride decreased in boiled and heated organs,with free fatty acids observed on thin layer chromatography(TLC).However,neither boiling nor heating significantly changed the fatty acid compositions of simple or complex lipids in starfish organs,suggesting that these two treatments had no significant effects on complex lipids in starfish organs.Together,our results indicated that boiling of starfish soon after capture facilitated the handling and extraction of useful complex lipids consisting of abundant glucosylceramide and eicosapentaenoic acid(EPA)-bounded phospholipids.     

甘肃省农村居民地震常识情况的调查分析

了解农村居民对地震常识的掌握情况是做好农村震害防御工作的重要参考.本文研究设计了调查表格,对农村居民地震常识的掌握情况进行了调查.通过甘肃省16个县(区)的现场抽样调查,得到了甘肃省农村居民的地震常识掌握情况,并通过对比研究,分析了造成农村居民地震常识掌握不足以及造成差异的影响因素.基于调查结果,本文针对农村居民地震常识的掌握情况,提出了增强农村居民防震减灾知识,提高其震害防御意识的工作建议.     

基于ArcGIS的国家台网地震速报地名查询辅助系统设计与实现

基于国家台网地震速报的实际工作需求,针对国家台网在全球地震速报中缺乏专门的地名查询系统,通过对国家台网实时、人机交互处理子系统和全国速报信息交换平台(EQIM系统)的相关协议和数据接口进行研究,并结合地震速报相关规定中对地名的要求,基于地理信息系统Arc GIS提供的Arc GIS Engine(AE)组件技术,采用Visual.Net开发平台和COM组件技术,来实现获取地震地名信息的功能,开发设计一套用于国家台网地震速报的地名查询辅助系统,希望可以有效提高国家台网地震速报的效率和准确度。     

三种地下水位动态预测模型在吉林西部的应用与对比

准确而可靠地预测地下水埋深对生态环境保护和水资源规划管理具有重要意义。针对吉林西部浅层地下水位动态变化的复杂性和非线性,提出了基于小波分析与人工神经网络相结合的预测方法小波神经网络(WA-ANN)模型。将研究区2002年1月2009年12月当月降水量、蒸发量、人工开采量和前月平均地下水埋深4个参数作为输入,当月平均地下水埋深作为输出,建立浅层地下水埋深预测模型,并与BP神经网络(BP-ANN)模型和自回归移动平均(ARIMA)模型进行比较,对比分析了三者的建模过程及其模拟精度。结果显示:相比两种ANN模型,ARIMA模型建模过程更为简单,计算效率更高;但WA-ANN模型的拟合精度高于BP-ANN和ARIMA模型,预测效果更好。总体来看,WA-ANN模型在浅层地下水埋深预测中具有一定的应用推广价值。     

Decoding Neoarchaean to Palaeoproterozoic tectonothermal events in the Rangnim Massif,North Korea: regional correlation and broader implications

Any knowledge about Archaean to Palaeoproterozoic magmatic and metamorphic events in North Korea has the potential to make a significant difference to our understanding of the early tectonic configuration and evolution of East Asia. This zircon U–Pb dating and Hf isotopic study documents multiple Neoarchaean to Palaeoproterozoic tectonothermal events from the meta-igneous complex in the Machollyong ‘Group’ of the Rangnim Massif. Two tonalitic-trondjemitic gneiss samples record a crystallization age of meta-igneous protoliths at ca. 2.56 Ga and multiple migmatization and metamorphism from 2.52 to 1.85 Ga. A meta-dolerite sample yields a magmatic emplacement age of ca. 1.83 Ga. In situ zircon Hf isotopic data indicate that most zircons from the gneiss samples have ε_Hf(t) values from –16.9 to + 3.1 and crustal model ages from 2.84 to 3.73 Ga, whereas magmatic zircons from the meta-dolerite dike record ε_Hf(t) values from –5.2 to + 5.2 and model ages of 2.05–2.44 Ga. The first-recognized Neoarchaean tonalitic-trondjemitic migmatite complex in the Rangnim Massif, together with previously identified tonalitic-trondhjemitic-granodioritic (TTG) rocks in the Rimjingang Belt and the coeval counterparts in western Gyeonggi massif, represents the oldest crustal nuclei in the Korean Peninsula. The multiple tectonothermal events in this study present reliable evidence not only for attesting to consanguinity of the basement between the Korean Peninsula and the North China Craton but also for defining the influence scope of the late Palaeoproterozoic orogeny in the Korean Peninsula.     

Purification and characterization of an alkaline protease from <Emphasis Type="Italic">Micrococcus</Emphasis> sp. isolated from the South China Sea

Protease is wildly used in various fields, such as food, medicine, washing, leather, cosmetics and other industrial fields. In this study, an alkaline protease secreted by Micrococcus NH54PC02 isolated from the South China Sea was purified and characterized. The growth curve and enzyme activity curve indicated that the cell reached a maximum concentration at the 30th hour and the enzyme activity reached the maximum value at the 36th hour. The protease was purified with 3 steps involving ammonium sulfate precipitation, ion-exchange chromatography and hydrophobic chromatography with 8.22-fold increase in specific activity and 23.68% increase in the recovery. The molecular mass of the protease was estimated to be 25 kDa by SDS-PAGE analysis. The optimum temperature and pH for the protease activity were 50°C and pH 10.0, respectively. The protease showed a strong stability in a wide range of pH values ranging from 6.0–11.0, and maintained 90% enzyme activity in strong alkaline environment with pH 11.0. Inhibitor trials indicated that the protease might be serine protease. But it also possessed the characteristic of metalloprotease as it could be strongly inhibited by EDTA and strongly stimulated by Mn²⁺. Evaluation of matrix-assisted laser desorption ionization/time-of-flight MS (MALDI-TOF-TOF/MS) showed that the protease might belong to the peptidase S8 family.     

有关地震烈度速报信息化发展的思考

汶川8.0级地震给我们很多警示,其中之一就是地震观测系统应当在大地震后快速产出地震烈度分布图。本文对快速产出地震烈度的策略和方法进行了探讨,着重介绍了用同震位移分布快速获得地震烈度产出的方法。实现地震烈度快速产出这一目标应当走测震学、强地面运动学与信息技术有效结合的道路,这是大震后地震烈度快速产出的有效途径。     

基于多参数指标的长江口滨岸多环芳烃来源辨析(英文)

Samples of suspended particulate matters(SPMs),surface sediment and road dust were collected from the Yangtze estuarine and nearby coastal areas,coastal rivers,and central Shanghai.The samples were analyzed for the presence of 16 polycyclic aromatic hydrocarbons(PAHs)in the USEPA priority-controlled list by GC-MS.The compound-specific stable carbon isotopes of the individual PAHs were also analyzed by GC-C-IRMS.The sources of PAHs in the SPMs and surface sediments in the Yangtze estuarine and nearby coastal...     

Broader pattern of tandem repeats in the mitochondrial control region of Perciformes

Perciformes, the largest order of vertebrates with 20 suborders, is the most diverse fish order that dominates vertebrate ocean life. The complete mitochondrial control region (CR) of Trichiurus japonicus (Trichiuridae, Scombroidei) and Pampus sp. (Stromateidae, Stromateoidei) were amplified and sequenced. Together with data from GenBank, the tandem repeats in the mitochondrial CR from 48 species, which covered nine suborders of Perciformes, are reported in this study. The tandem repeats tend to be long in the suborder Percoidei and Stromateoidei. The identical repeats in 21 species of Cichlidae suggest a common origin and have existed before species divergence. Larimichthys crocea shows tandem repeats instead of the typical structure of the central conserved sequence blocks, which was first reported in Perciformes and vertebrates. This might have resulted from interruption of the polymerase activity during the H-strand synthesis. The four broader patterns presented here for the tandem repeats, including those in both the 5′ and 3′ ends, only in the either 5′ or 3′ end, and in the central conserved domain of the control region, will be useful for understanding the evolution of species.