山东蓬莱大黑山岛碱性火山岩地球化学特征

庙岛群岛中的大黑山岛出露碱性火山岩,对研究壳-幔过程及黄、渤海演化具重要意义。文中作者对大黑山岛火山岩的常、微量元素、K-Ar年龄及Nd-Sr-Pb同位素体系进行测试确定。结果表明,岩石属钠质碱性玄武岩系列,岩浆岩喷发可分为8Ma前和8Ma后两个阶段;岩石常量元素含量除K2O、Na2O外差异小;随着火山岩的演化,岩浆源区深度变大;大黑山火山岩Nd-Sr-Pb同位素比值与夏威夷洋岛玄武岩相似,其岩浆的地幔端元组分为PREMA DM,又以PREMA为主,并有MORB物质混入。     

罗非鱼、南美白对虾对重金属富集的研究

对广东省养殖的罗非鱼Oreochromis niloticus及南美白对虾Litopeneaus vannamei体内Pb、Cd、Hg、As 4种重金属富集及分布状况进行研究。比较了不同规格罗非鱼及南美白对虾体内重金属差异。分析重金属在罗非鱼及南美白对虾不同部位的分布状况。结果表明,罗非鱼及南美白对虾体内Pb、Cd、Hg、As均有不同程度的检出,但含量均低于国家限定标准(NY5125-2002);其中Pb的含量最高,罗非鱼和南美白对虾体内Pb含量最高值分别为限量的39.32%和42.18%;重金属含量因其规格大小及部位而异,趋势为大规格样品重金属含量相对较高,重金属含量在罗非鱼及南美白对虾体内的增长情况与其体重具有正相关性;罗非鱼内脏重金属含量明显高于肌肉组织,虾头为虾重金属富集的主要部位。     

A comparison of several wave spectra for the random wave diffraction by a semi-infinite breakwater

A comparison of the diffraction of multidirectional random waves using several selected wave spectrum models is presented in this paper. Six wave spectrum models, Bretschneider, Pierson–Moskowitz, ISSC, ITTC, Mitsuyasu, and JONSWAP spectrum, are considered. A discrete form for each of the given spectrum models is used to specify the incident wave conditions. Analytical solutions based on both the Fresnel integrals and polynomial approximations of the Fresnel integrals and numerical solutions of a boundary integral approach have been used to obtain the two-dimensional wave diffraction by a semi-infinite breakwater at uniform water depth. The diffraction of random waves is based on the cumulative superposition of linear diffraction solution. The results of predicted random wave diffraction for each of the given spectrum models are compared with those of the published physical model presented by Briggs et al. [1995. Wave diffraction around breakwater. Journal of Waterway, Port, Coastal and Ocean Engineering—ASCE 121(1), 23–35]. Reasonable agreement is obtained in all cases. The effect of the directional spreading function is also examined from the results of the random wave diffraction. Based on these comparisons, the present model for the analysis of various wave spectra is found to be an accurate and efficient tool for predicting the random wave field around a semi-infinite breakwater or inside a harbor of arbitrary geometry in practical applications.     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.     

水下智能潜器的神经网络运动控制

本文介绍一种基于神经网络的水下智能潜器的运动控制方法，该方法通过在线学习，融控制与滤波为一体。计算机仿真与水池实验验证表明，该方法的控制与滤波性能良好，对环境的学习与适应能力强。该方法事实上可用于一般动力系统的控制。     

虾蟹海产品香味的前体物质的加热变化

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。     

可编程序控制器的多机联用

多台可编程序控制器通过输入、输出点的直接连接,传递命令、状态和数据,实现多机联用系统。     

环胶州湾公路海上段汽车尾气的环境影响

对类比路段进行连续模拟试验,进行现场调查,给出汽车尾气主要污染物的排污强度,预测了汽车尾气中CO、C_nH_m和NO_x的扩散范围。     

Refraction-Diffraction Mathematical Model for Waves With Lateral Energy Transmission Mechanism and Its Verification

To solve problems concerning wave elements and wave propagation, an effective way is the wave energy balance equation, which is widely applied in oceanography and ocean dynamics for its simple computation. The present papaer advances wave energy balance equations considering lateral energy transmission and energy loss as the governing equation for the study of wave refraction-diffraction. For the mathematical model, numerical simulation is made by means of difference method, and the result is verified with two examples.     

碘－钒盐催化下合成的四溴邻苯二甲酸酐

报道一种新的有效催化剂－碘－钒盐和在一定条件下合成四溴邻苯二甲酸酐的方法。探讨催化剂的组成配比、用量、温度及废酸循环使用等因素对合成方法的影响。该催化剂的催化效果和常用的碘、碘－铁催化剂相同，适用于四溴邻苯二甲酸酐的合成。