Geogene Versus Anthropogene Origin of Trace Metals in Sediments in Cua Luc Estuary and Ha Long Bay, Vietnam

In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on ¹³⁷Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs.     

Notes on the Geological Structure of the Washan-Omeishan Region

I. INTRODUCTION Bordering the SW margin of the Red Basin of Szechuan runs a roughly N-S mountain range which includes such mountains as Washan, Omeishan and Talliangshan (Pl. I) and for the sake of convenience is designated with the name of Liangshan Range. Among these mountains only the geology of the Omeishan region is fairly well known in consequence of the works done by many a geologist; of the Washan region, though had been visited by     

Massive sedimentation of fine sediment with organic matter and enhanced benthic-pelagic coupling by an artificial dyke in semi-enclosed Chonsu Bay, Korea

To assess the impact of an artificial dyke in Chonsu Bay (CBD) on the organic carbon (C(org)) cycle, we measured excess (210)Pb activities, C(org) and nitrogen content in sediment cores. The C(org) oxidation rates (C(ox)) on the surface sediment and benthic nutrient fluxes were also quantified with an in situ benthic chamber. The higher excess (210)Pb inventory, C(org) and nitrogen in cores near the CBD indicated lateral transport and local, massive deposition of particulate matter due to tidal circulation altered by artificial dyke construction. The C(ox) in sediment near the CBD was about twice as high as that out of the bay, suggesting the importance of benthic remineralization of organic matter. The benthic fluxes of dissolved inorganic nitrogen and phosphate were four to six times higher than those outside the bay, corresponding to 141% and 131% respectively, of the requirements for primary production.     

Cadmium and phosphorus cycling in the water column of the South China Sea: The roles of biotic and abiotic particles

The concentrations of cadmium, phosphorus, and aluminum in size-fractionated phytoplankton, zooplankton, and sinking particles are determined using ICPMS to evaluate the roles of biotic and abiotic particles on the cycling and ratios of Cd and P in the water column. Plankton were collected with a filtration apparatus equipped with 10-, 60-, and 150-μm aperture plankton nets on two occasions (2002 and 2006), and sinking particles were sampled by moored sediment traps deployed at depths of 120, 600, and 3500 m from 2004 to 2005. In contrast to what our previous study revealed, i.e., that most of the other bioactive trace metals in plankton were strongly correlated with abiotic Al and adsorbed on phytoplankton [Ho, T.Y., Wen, L.S., You, C.F., Lee, D.C., 2007. The trace metal composition of size-fractionated plankton in the South China Sea: biotic versus abiotic sources. Limnol Oceanogr 52, 1776–88.], Cd/P ratios, ranging from 0.12 to 0.34 mmol/mol P, did not vary with Al and exhibited fairly consistent values among different sizes of plankton, showing that Cd was mostly incorporated on an intracellular basis. In terms of the sinking particles, fluxes in Cd and P as well as in Cd/P ratios were strongly influenced by both biotic and abiotic particles. Overall, the Cd/P ratios in the sinking particles ranged from 0.03 to 1.2 mmol/mol, with the highest value observed in traps at 120 m during the productive season. The lowest value was observed in deep water during high flux periods for lithogenic particles. At surface depth, flux and Cd/P ratios were elevated during the most productive season in the region. The elevated ratios in the traps at 120 m were most likely related to preferential uptake of Cd for the dominant species (coccolithophores) during the productive period. Relatively, Cd/P ratios sharply decreased with increasing Al flux in deep water and ratios were much lower than the expected Cd/P ratios obtained from the relative portion of lithogenic and biogenic particles, indicating that the adsorption of soluble P into lithogenic particles was significant in the deep water during high lithogenic particle flux periods. Using averaged annual fluxes and standing stock in the water column, the residence time of biogenic Cd and P are 0.10 and 0.20, 250 and 100, and 9100 and 5000 years respectively in the top 120 m, 600 m, and water column as a whole, also showing preferential removal for Cd in the euphotic zone but relatively higher removal rates for P in the deep water. Our study suggests that the shift in microalgal community structure along with input of lithogenic minerals are both potentially important factors in influencing Cd/P ratios in oceanic water on a geological time scale.     

Behavior of soil plugs in open‐ended model piles driven into sands

Calibration chamber tests were conducted on open‐ended model piles driven into dried siliceous sands with different soil conditions in order to clarify the effect of soil conditions on load transfer mechanism in the soil plug. The model pile used in the test series was devised so that the bearing capacity of an open‐ended pile could be measured as three components: outside shaft resistance, plug resistance, and tip resistance. Under the assumption that the unit shaft resistance due to pile‐soil plug interaction varies linearly near the pile tip, the plug resistance was estimated. The plug capacity, which was defined as the plug resistance at ultimate condition, is mainly dependent on the ambient lateral pressure and relative density. The length of wedged plug that transfers the load decreases with the decrease of relative density, but it is independent of the ambient pressure and penetration depth. Under several assumptions, the value of earth pressure coefficient in the soil plug can be calculated. It gradually reduces with increase in the longitudinal distance from the pile tip. At the bottom of the soil plug, it tends to decrease with increase in the penetration depth and relative density, and to increase with the increase of ambient pressure. This may be attributed to (1) the decrease of friction angle as a result of increase in the effective vertical stress, (2) the difference in the dilation degree of the soil plug during driving with ambient pressures, and (3) the difference in compaction degree of soil plug during driving with relative densities. Based on the test results, an empirical equation was suggested to compute the earth pressure coefficient to be used in the calculation of plug capacity using one‐dimensional analysis, and it produces proper plug capacities for all soil conditions.     

Impacts of Seasonal Pumping on Stream‐Aquifer Interactions in Miryang,Korea

Large agricultural fields in South Korea are located mostly on alluvial plains, where a significant amount of groundwater is used for heating of water‐curtain insulated greenhouses. Such greenhouses are commonly used for crop cultivation during the winter dry season from November to March. After use the groundwater is discharged directly into streams, causing groundwater depletion. A hydrogeological study was carried out in a typical agricultural area of this type, located on an alluvial aquifer near the Nakdong River. Groundwater levels, chemical characteristics, and temperatures from 68 observation wells were analyzed to determine the impacts of seasonal groundwater pumping on the groundwater system and stream‐aquifer interactions. Our results show that the groundwater system has not yet reached a state of dynamic equilibrium. Decades of excessive seasonal pumping have caused a gradual decline of groundwater levels, leading to groundwater depletion, especially in areas further from the river. Seasonal pumping has also significantly affected groundwater quality in the aquifer near the river. Groundwater temperature is decreasing (in this case a disadvantage), and saline groundwater is being diluted by induced recharge. The results of this study provide a basic outline for effective integrated water management that is widely applicable in South Korea.     

Seismic isolation for low‐to‐medium‐rise buildings using granulated rubber–soil mixtures: numerical study

This paper presents the preliminary research works on a potential seismic isolation method that makes use of scrap rubber tires for the protection of low‐to‐medium‐rise buildings. The method involves mixing shredded rubber tire particles with soil materials and placing the mixtures around building foundations, which provides a function similar to that of a cushion. Meanwhile, the stockpiling of scrap tires is a significant threat to our environment, and the engineering community has been looking for long‐term viable solutions to the recycling and reuse of rubber. A finite element program has been developed for modeling the time‐domain dynamic responses of soil–foundation–structure system, by which the effectiveness and robustness of the proposed method have been evaluated. In general, the structural responses, in terms of acceleration and inter‐story drift, can be reduced by 40–60%. Copyright © 2012 John Wiley & Sons, Ltd.     

Composition and temperatures of the topside ionosphere over Arecibo

Results of analysis of about 150 autocorrelation functions are presented for the period from about 2300 hr on 5 October to about 1200 hr on 7 October 1967. A large percentage concentration of helium ions are observed. It reaches a value as high as 50 per cent with a maximum at around 800 km. Downward heat fluxes deduced from the temperature variations yield a value of about 2–2.5 × 10⁹ eV cm^?2 sec^?1 during the period 1200–1600 hr and a value of about 1.5 × 10⁸ eV cm^?2 sec^?1 during the period 0100–0400 hr at night. These agree well with other measurements. The O⁺ ions are found not to be in diffusive equilibrium, and from the O⁺ fluxes and the electron density profiles, the O⁺ drift velocity has been estimated. It is found that the speed can be as high as 1–5 × 10³ cm sec^?1 even at altitudes as high as 700 km.     

Holocene and Eemian climatic optima in the Korean Peninsula based on textural and carbon isotopic records from the stalagmite of the Daeya Cave,South Korea

Textural and stable isotopic records from the absolute-dated stalagmite of the Daeya Cave (DY-1) provide new insights into the climatic evolution of the Korean Peninsula during the Holocene and Eemian climatic optima. The stalagmite yielded ages of 8572 ± 227 to 5907 ± 158 and 1,23,456 ± 535 to 1,19,837 ± 1089 years, which coincide with the Holocene and Eemian climatic optima, respectively. The stalagmite’s δ¹³C record closely resembles previously reported Chinese speleothem δ¹⁸O data. Thus it can be suggested that textural and geochemical results of the DY-1 reflect East Asian monsoon intensity, which is forced by summer insolation patterns in the northern hemisphere. Lighter carbon isotopic compositions, well-developed fibrous calcite crystals, and their relatively faster growth rate in the stalagmite sample are interpreted to reflect the warmest and wettest climate conditions of the Holocene and Eemian interglacials. Both climatic optima took place when insolation was decreasing from its maximum level, temperature in Greenland was highest, and sea level approached its maximum level. These climatic optima also coincide with decreasing Antarctic temperatures. Compared the DY-1 data to other proxies, it is suggested that the Holocene and Eemian climatic optima developed through a balance among boreal insolation, monsoon intensity, and sea level (also continental ice volume), which are the main climatic forcing factors in the northern hemisphere. These trends also follow the bi-polar seesaw mechanism as previously described.     

Field survey of the 1994 Mindoro Island,Philippines tsunami

This is a report of the field survey of the November 15, 1994 Mindoro Island, Philippines, tsunami generated by an earthquake (M=7.0) with a strike-slip motion. We will report runup heights from 54 locations on Luzon, Mindoro and other smaller islands in the Cape Verde passage between Mindoro and Luzon. Most of the damage was concentrated along the northern coast of Mindoro. Runup height distribution ranged 3–4 m at the most severely damaged areas and 2–4 in neighboring areas. The tsunami-affected area was limited to within 10 km of the epicenter. The largest recorded runup value of 7.3 m was measured on the southwestern coast of Baco Island while a runup of 6.1 m was detected on its northern coastline. The earthquake and tsunami killed 62 people, injured 248 and destroyed 800 houses. As observed in other recent tsunami disasters, most of the casualties were children. Nearly all eyewitnesses interviewed described the first wave as a leading-depression wave. Eyewitnesses reported that the main direction of tsunami propagation was SW in Subaang Bay, SE in Wawa and Calapan, NE on Baco Island and N on Verde Island, suggesting that the tsunami source area was in the southern Pass of Verde Island and that the wave propagated rapidly in all directions. The fault plane extended offshore to the N of Mindoro Island, with its rupture originating S of Verde Island and propagating almost directly south to the inland of Mindoro, thereby accounting for the relatively limited damage area observed on the N of Mindoro.