福州市马尾地区第四纪地层划分及海相层分析

通过对该区钻孔剖面贡料,结合~(14)C、古地磁、孢粉及微体古生物等资料综合分析研究,对该区第四纪地层提出划分意见和自第四纪晚期以来,地层中存在着典型两期海侵所形成的海相层。     

南极中山站石榴石变粒岩的岩石学矿物学及其变质作用研究

本文报道了南极拉丝曼丘陵“中山站”石榴石变粒岩的岩石学和矿物化学特征;确定了其矿物组合及世代演化关系,利用电子探针分析了其特征变质矿物的化学组成,最后推断东南极拉丝曼丘陵地区曾发生过麻粒岩相变质作用和混合岩化作用。     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

A climatology of mesoscale model simulated low-level wind jets over Cook Inlet and Shelikof Strait, Alaska

Weather in the North Gulf of Alaska is characterized by a high frequency of deep synoptic-scale low-pressure systems, especially during the cold season. The strong pressure gradients of these storms interact with the extremely rugged terrain of the coastal mountains to produce a variety of channeled flows. These surface wind regimes are not well documented in the scientific community, due to the paucity of observations. Modeling of these phenomena in regions of complex terrain is of great interest to those working with hydrodynamic, wave, and pollutant transport models in coastal and shelf areas. Such models, when coupled with ocean and coastal-ecology counterparts, give a broad view of the role surface winds play in shaping local coastal marine ecosystem in this region. This paper presents a climatology of simulated low-level wind jets over the domain of Cook Inlet and Shelikof Strait along Alaska's south-central coast. Daily simulations using the RAMS model were conducted in a 36-h forecast mode for the cold-season period 10/1/03 to 3/31/04. Systematic analysis of the resulting simulated low-level wind field makes it possible to characterize these jets and gap flows in spatial and temporal detail. The comparison between the RAMS winds and the Synthetic Aperture Radar (SAR)-derived winds when available verifies the existence of these wind jets and the capability of the model to simulate these cases. Clearly, the results of a study in this region depend on the fidelity of the model at these scales (O[5 km]). The SAR comparisons attempt to help establish this. From the 6 months of simulations over Cook Inlet and Shelikof Strait, the low-level wind jets are classified into 10 different regimes by location and orientation. These regimes are categorized into four more general groups: cross-channel westerly, easterly, and up and down Inlet flows. The nature of a particular regime is largely a function of pressure gradient orientation and local topography. Jets in the same group have a similar occurrence distribution with time. Some form of jet occurred in the study region almost daily each month of the period, with December 2003 having the highest frequency of wind jets.     

Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.     

包头市近50年气候变化及对策

利用包头市1961—2010年的逐日气温、降水、风等气象要素资料,分析了近50年气候变化的时空特征。结果表明:包头市气候发生了明显的变暖过程,全市年平均气温升高了1.9～2.3℃,年平均最高气温升高1.3℃,年平均最低气温升高2.2～2.7℃,特别是20世纪80年代中期以后气温持续上升,冬季变暖尤为明显。而降水量没有趋势性的年际变化,呈现出箱体内的震荡。     

Approximate incremental dynamic analysis using the modal pushover analysis procedure

Incremental dynamic analysis (IDA)—a procedure developed for accurate estimation of seismic demand and capacity of structures—requires non‐linear response history analysis of the structure for an ensemble of ground motions, each scaled to many intensity levels, selected to cover the entire range of structural response—all the way from elastic behaviour to global dynamic instability. Recognizing that IDA of practical structures is computationally extremely demanding, an approximate procedure based on the modal pushover analysis procedure is developed. Presented are the IDA curves and limit state capacities for the SAC‐Los Angeles 3‐, 9‐, and 20‐storey buildings computed by the exact and approximate procedures for an ensemble of 20 ground motions. These results demonstrate that the MPA‐based approximate procedure reduces the computational effort by a factor of 30 (for the 9‐storey building), at the same time providing results to a useful degree of accuracy over the entire range of responses—all the way from elastic behaviour to global dynamic instability—provided a proper hysteretic model is selected for modal SDF systems. The accuracy of the approximate procedure does not deteriorate for 9‐ and 20‐storey buildings, although their dynamics is more complex, involving several ‘modes’ of vibration. For all three buildings, the accuracy of the MPA‐based approximate procedure is also satisfactory for estimating the structural capacities for the limit states of immediate occupancy, collapse prevention, and global dynamic instability. Copyright © 2006 John Wiley & Sons, Ltd.     

秦皇岛市洋河、戴河滨海平原海水入侵的控制与治理

秦皇岛市洋河,戴河冲洪积平原,近20年来抽取地下水量迅速增加,80年代初形成了低于海平面的降落漏斗,造成海水从海岸线向内陆和从河流下游河床向两侧同时侵入孔隙含水层。由于水质恶化,北戴河区水源地面临报废的危险。为了保护和开发淡水资源,控制海水入侵,必须对地下水的水质和水量进行综合评价。采用水动力弥散型地下水水质模型来描述滨海含水层中海水和淡水的运动,把氯离子作为水质模型的变量。在水量模型中采用孔隙压力代替水头作为变量。数学模型用有限单元法求解。模拟面积约180km²,剖分为321个单元,184个结点。作为水文地质实体的模型,它被用来模拟和预报不同降水量年份的地下水水位和水质。计算结果表明,如果保持目前的地下水开采量,海水入侵还会深入。为了控制和治理海水入侵,本文探讨了可行措施。根据数学模型模拟的结果,在洋河下游人海口修建防潮闸,同时加强滨海含水层的管理,具有较好的经济效益和环境效益。     

Measurement of aerosol effective density by single particle mass spectrometry

Single particle mass spectrometry has been widely used to determine the size and chemical compositions of atmospheric aerosols; however, it is still rarely used for the microphysical properties measurement. In this study, two methods were developed for determining aerosol effective density by a single particle aerosol mass spectrometer (SPAMS). Method I retrieved effective density through comparison between measured light scattering intensities and Mie theoretical modelled partial scattering cross section. Method II coupled a differential mobility analyzer (DMA) with SPAMS to simultaneously determine the electric mobility and vacuum aerodynamic diameter, and thus the effective density. Polystyrene latex spheres, ammonium sulfate and sodium nitrate were tested by these methods to help validate their effectiveness for determining the aerosol effective density. This study effectively extends SPAMS measurements to include particle size, chemical composition, light scattering, and effective density, and thus helps us better understand the environment and climate effects of aerosols.     

Input data selection for solar radiation estimation

Model input data selection is a complicated process, especially for non‐linear dynamic systems. The questions on which inputs should be used and how long the training data should be for model development have been hard to solve in practice. Despite the importance of this subject, there have been insufficient reports in the published literature about inter‐comparison between different model input data selection techniques. In this study, several methods (i.e. the Gamma test, entropy theory, AIC (Akaike's information criterion)/BIC (Bayesian information criterion) have been explored with the aid of non‐linear models of LLR (local linear regression) and ANN (artificial neural networks). The methodology is tested in estimation of solar radiation in the Brue Catchment of England. It has been found that the conventional model selection tools such as AIC/BIC failed to demonstrate their functionality. Although the entropy theory is quite powerful and efficient to compute, it failed to pick up the best input combinations. On the other hand, it is very encouraging to find that the new Gamma test was able to choose the best input selection. However, it is surprising to note that the Gamma test significantly underestimated the required training data while the entropy theory did a better job in this aspect. This is the first study to compare the performance of those techniques for model input selections and still there are many unsolved puzzles. Copyright © 2009 John Wiley & Sons, Ltd.